3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol | 114834-29-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol
• 英文别名: 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-Henicosafluorotridecane-1,2-diol
• CAS: 114834-29-6
• 化学式: C₁₃H₇F₂₁O₂
• 分子量: 594.164
• InChiKey: JRJPHUAHPMPZNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  36
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  23

反应信息

• 作为反应物：
  描述：

  3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol 、 3-氨基苯硼酸 以 various solvent(s) 为溶剂， 反应 15.0h， 以94%的产率得到2-(3-aminophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane
  参考文献：
  名称：

  The synthesis and application of fluorous boronates without perfluorinated solvents

  摘要：

  The synthesis of a fluorous diol 4 bearing a perfluorodecyl chain was described. A series of boronic acid were attached to 4 by esterification. The purification of the products was fulfilled by facile filtration instead of expensive and environmental troublesome fluorous liquid-liquid extraction. The Suzuki cross-coupling reactions of the formed fluorous boronates 5 underwent smoothly and the fluorous diol 4 was recycled in good yields. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2004.12.014
• 作为产物：
  描述：

  1-碘全氟癸烷 在 吡啶 、 四氧化锇 、 溶剂黄146 、 N-甲基吗啉氧化物 、 锌 、 过氧化苯甲酰 作用下， 以 异丙醇 、 丙酮 为溶剂， 反应 36.0h， 生成 3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol
  参考文献：
  名称：

  The synthesis and application of fluorous boronates without perfluorinated solvents

  摘要：

  The synthesis of a fluorous diol 4 bearing a perfluorodecyl chain was described. A series of boronic acid were attached to 4 by esterification. The purification of the products was fulfilled by facile filtration instead of expensive and environmental troublesome fluorous liquid-liquid extraction. The Suzuki cross-coupling reactions of the formed fluorous boronates 5 underwent smoothly and the fluorous diol 4 was recycled in good yields. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2004.12.014

文献信息

• Die Verwendung von Polyisocyanatlösungen zur Imprägnierung von mineralischen Substraten
  申请人：BAYER AG

  公开号：EP0540976A1

  公开（公告）日：1993-05-12

  Die Verwendung von Lösungen von a) Harnstoffgruppenfreien, fluorenthaltenden Polyisocyanaten in b) gegenüber Isocyanatgruppen inerten Lösungsmitteln zur Imprägnierung von mineralischen Substraten, ausgewählte, hierzu geeignete, fluorenthaltende Polyisocyanate mit einem Fluorgehalt in Form von perfluorierten Alkylgruppen von 15 bis 60 Gew.-% und einem Isocyanatgehalt von 0,5 bis 15 Gew.-%, welche durch Umsetzung von (cyclo)aliphatischen Isocyanaten mit fluoraufweisenden ein- und mehrwertigen Alkoholen hergestellt worden sind, sowie ausgewählte, zur Herstellung derartiger Polyisocyanate geeignete, fluorenthaltende Alkohole.

  a) 不含脲基的含氟多异氰酸酯在 b) 对异氰酸酯基团惰性的溶剂中的溶液用于矿物基材的浸渍，适用于这一目的的精选含氟多异氰酸酯，其全氟烷基形式的氟含量为 15 至 60 重量百分比，异氰酸酯含量为 0.5 至 15 重量百分比，是通过(环)脂肪族异氰酸酯与释放氟的一元醇和多元醇反应制得的。此外，还可以通过(环)脂肪族异氰酸酯与释放氟的一元醇和多元醇以及适于制备此类多 异氰酸酯的精选含氟醇反应制备异氰酸酯，其异氰酸酯含量为 0.5%至 15%(重量百分比)。
• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• US5254660A
  申请人：——

  公开号：US5254660A

  公开（公告）日：1993-10-19
• The synthesis and application of fluorous boronates without perfluorinated solvents
  作者：Chun-Yan Wang、Wei-Dong Meng、Yan-Gen Huang、Feng-Ling Qing

  DOI：10.1016/j.jfluchem.2004.12.014

  日期：2005.7

  The synthesis of a fluorous diol 4 bearing a perfluorodecyl chain was described. A series of boronic acid were attached to 4 by esterification. The purification of the products was fulfilled by facile filtration instead of expensive and environmental troublesome fluorous liquid-liquid extraction. The Suzuki cross-coupling reactions of the formed fluorous boronates 5 underwent smoothly and the fluorous diol 4 was recycled in good yields. (c) 2005 Elsevier B.V. All rights reserved.