(S,E)-6-Methyl-3-hepten-4-ol | 153665-39-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (S,E)-6-Methyl-3-hepten-4-ol
• 英文别名: (S)-rhynchophorol；(S)-6-methyl-hept-2t-en-4-ol；(S)-(-)-(E)-6-Methyl-2-hepten-4-ol；S-Rhynchophorol；(E,4S)-6-methylhept-2-en-4-ol
• CAS: 153665-39-5
• 化学式: C₈H₁₆O
• 分子量: 128.214
• InChiKey: RQAFKZOPSRTJDU-WTSVBCDHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (S,E)-6-Methyl-3-hepten-4-ol 在 palladium on activated charcoal 氢气 、 丙酸 作用下， 以 乙醇 为溶剂， 反应 2.0h， 生成 (+)-(R)-3,7-Dimethyl-octansaeure-aethylester
  参考文献：
  名称：

  （2R，4'R，8'R）-α-生育酚的合成研究。通过立体有规[3,3] sigmatropic重排可轻松合成旋光，饱和，无环类异戊二烯。

  摘要：

  DOI：

  10.1021/jo00884a001
• 作为产物：
  描述：

  (+/-)-6-methyl-2-heptyn-4-ol 在 吡啶 、 sodium hydroxide 、 氨 、 sodium 作用下， 生成 (S,E)-6-Methyl-3-hepten-4-ol
  参考文献：
  名称：

  （2R，4'R，8'R）-α-生育酚的合成研究。通过立体有规[3,3] sigmatropic重排可轻松合成旋光，饱和，无环类异戊二烯。

  摘要：

  DOI：

  10.1021/jo00884a001

文献信息

• Asymmetric Hydrogenation of Alkenyl, Cyclopropyl, and Aryl Ketones. RuCl₂(xylbinap)(1,2-diamine) as a Precatalyst Exhibiting a Wide Scope
  作者：Takeshi Ohkuma、Masatoshi Koizumi、Henri Doucet、Trang Pham、Masami Kozawa、Kunihiko Murata、Eiji Katayama、Tohru Yokozawa、Takao Ikariya、Ryoji Noyori

  DOI：10.1021/ja983257u

  日期：1998.12.1
• Aggregation Pheromones and Host Kairomones of West Indian Sugarcane Weevil, Metamasius hemipterus sericeus
  作者：A. L. Perez、Y. Campos、C. M. Chinchilla、A. C. Oehlschlager、G. Gries、R. Gries、R. M. Giblin-Davis、G. Castrillo、J. E. Peña、R. E. Duncan、L. M. Gonzalez、H. D. Pierce, Jr.、R. McDonald、R. Andrade

  DOI：10.1023/b:joec.0000006377.13235.4b

  日期：1997.4

  Coupled gas chromatagraphic-electroantennographic detection (GC-EAD) analyses and coupled CC-mass spectrometry (MS) of volatiles produced by male and female West Indian sugarcane weevils (WISW), Metamasius hemipterus sericeus (Oliv.), revealed eight male specific, EAD-active compounds: 3-pentanol (1), 2-methyl-4-heptanol (2), 2-methyl-4-octanol (3), 4-methyl-5-nonanol (4), and the corresponding ketones. In field experiments in Florida, alcohols 1-4 in combination with sugarcane were most attractive, whereas addition of the ketones or replacement of alcohols with ketones significantly reduced attraction. In Costa Rica field experiments testing alcohols 1-4 singly and in all binary, ternary, and quaternary combinations revealed 4 in combination with 2 was the major aggregation pheromone, equally attracting male and female WISW. Stereoisomeric 4 and (4S,5S)-4, the only isomer produced by WISW, were equally attractive. Addition of 4S-, 4R- or (+/-)-2 to (4S,5S)-4 significantly enhanced attraction. Sugarcane stalks in combination with 2 plus 4 (ratio of 1:8) were highly synergistic, whereas EAD-active sugarcane volatiles ethyl acetate, ethyl propionate, or ethyl butyrate only moderately increased attractiveness of the pheromone lure.
• Hoppe, Dieter; Kraemer, Thomas, Angewandte Chemie, 1986, vol. 98, # 2, p. 171 - 173
  作者：Hoppe, Dieter、Kraemer, Thomas

  DOI：——

  日期：——
• COMPOSITIONS AND METHODS COMPRISING YEAST ORGANISMS AND LIPID EXTRACTS THEREOF
  申请人：R.F. Technology Consultants, Inc.

  公开号：US20160375071A1

  公开（公告）日：2016-12-29

  The invention provides compositions comprising whole yeast organisms and/or lipid yeast extract. Such compositions may be medical or cosmetic compositions, comprising one or more cosmetic or medical, pharmaceutical ingredients. The invention comprises methods of making such compositions. The yeast components of the compositions may be derived from yeast cultures which comprise at least 0.1% oil by dry weight.
• US4000169A
  申请人：——

  公开号：US4000169A

  公开（公告）日：1976-12-28