[Zn(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)(1,10-phenathroline)]n | 1204325-56-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Zn(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)(1,10-phenathroline)]n
• 英文别名: [Zn(dpa)(1,10-phen)]n
• CAS: 1204325-56-3
• 化学式: C₂₆H₁₆N₂O₄Zn
• 分子量: 485.814
• InChiKey: YNCYDTQOVKPGSJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 2,2'-联苯二甲酸 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 生成 [Zn(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)(1,10-phenathroline)]n
  参考文献：
  名称：

  Synthesis, characterization and properties of series coordination polymers constructed from a biphenyl dicarboxylate and nitrogen-containing mixed ligands

  摘要：

  A series of coordination polymers have been prepared by the combination of flexible ligand 1,1'-biphenyl-2,2'-dicarboxylic acid (H(2)dpa) and different types of nitrogen-containing ligands, with various metal ions such as Co(II), Zn(II) and Cd(II). The single-crystal structure analyses reveal that the above complexes possess different structure features with the introduction of different nitrogen-containing ligands. When auxiliary linear ligand 4,4'-bipyridine (4,4'-bpy) is introduced, two-dimensional layered complex, [Co-2(dpa)(2)(4,4'-bpy)(2)(H2O)](n) (1) is formed. Whereas if chelating ligand, 1,10-phenanthroline (1,10'-phen) and 2,2'-bipyridine (2,2'-bpy) are introduced, one-dimensional complex [Zn(dpa)(1,10'-phen)](n) (2) and discrete complexes [Co-2(dpa)(2)(2,2'-bpy)(2)(H2O)(2)] (3), [Co-3(dpa)(3)(1,10'-phen)(6)(H2O)(2)] (4), [Cd(dpa)(1,10'-phen)(2)][(H(2)dpa)(2)(H2O)(2)] (5) are synthesized. To our interest, 1 and 2 crystallize in homochiral space-group. Furthermore, the magnetic property of complex 1 and the fluorescent properties of complexes 2 and 5 are studied. Crown Copyright (C) 2009 Published by Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.025