2,8-phenanthroline | 19376-21-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,8-phenanthroline
• 英文别名: [3,7]phenanthroline；1,7-Diazaphenanthren；1,7-Phenanthrolin；3,7-Phenanthrolin；3,7-Phenanthroline
• CAS: 19376-21-7
• 化学式: C₁₂H₈N₂
• 分子量: 180.209
• InChiKey: HLTQJJLFTXOYSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,8-phenanthroline 在 氢氧化钾 、 potassium permanganate 作用下， 生成 5H-环戊烯并[2,1-c:3,4-c']二吡啶-5-酮
  参考文献：
  名称：

  Photochemistry of 9-diazo-3,6-diazafluorene: through-space or through-bond transmission of electronic effects

  摘要：

  DOI：

  10.1021/jo00227a006
• 作为产物：
  描述：

  1,2-二(4-吡啶基)乙烯 以 水 、 乙腈 为溶剂， 反应 4.0h， 以1.4 g的产率得到2,8-phenanthroline
  参考文献：
  名称：

  Photochemistry of 9-diazo-3,6-diazafluorene: through-space or through-bond transmission of electronic effects

  摘要：

  DOI：

  10.1021/jo00227a006

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011105700A1

  公开（公告）日：2011-09-01

  Provided are novel organic electroluminescent compounds, and organic electroluminescent devices comprising the same. Since the organic electroluminescent compounds exhibit high luminous efficiency in blue color, and excellent life property of the material, they may be used to manufacture OLEDs having very good operation life.

  提供了新颖的有机电致发光化合物，以及包含这些化合物的有机电致发光器件。由于这些有机电致发光化合物在蓝色方面表现出高发光效率，并且材料具有优秀的寿命特性，因此它们可以用于制造具有非常良好使用寿命的OLED。
• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。
• HETEROCYCLIC COMPOUND FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ITS APPLICATION
  申请人：TOSOH CORPORATION

  公开号：US20160056388A1

  公开（公告）日：2016-02-25

  A novel heterocyclic compound for an organic electroluminescent device excellent in long service life and light-emitting characteristics is provided. A cyclic azine compound has at least one substituent (substituent B) selected from a specific group.

  提供一种新的杂环化合物，用于有机电致发光器件，具有长寿命和发光特性优异。该环状腈化合物至少具有来自特定群组的一个取代基（取代基B）。
• ORGANIC EL MATERIAL AND ORGANIC EL ELEMENT EMPLOYING SAME
  申请人：Kaneka Corporation

  公开号：EP3316328A1

  公开（公告）日：2018-05-02

  An organic EL material according to the present invention includes a compound represented by the general formula (I). In the formula (I), R1 and R2 are each independently a hydrogen atom or any substituent, and are preferably each independently a substituent selected from the group consisting of a hydrogen atom, a cyano group, a halogen-substituted alkyl group, a halogen, a pyridyl group optionally having a substituent, and an electron-donating aromatic group. A is a substituent in which at least one heteroaryl group optionally having a substituent, or at least one aryl amino group optionally having a substituent is bonded to a carbon atom at the 4-position of the pyridine ring directly or through other aromatic group.

  根据本发明，有机 EL 材料包括通式 (I) 所代表的化合物。在式（I）中，R1 和 R2 各自独立地为氢原子或任何取代基，并且最好各自独立地为选自氢原子、氰基、卤素取代的烷基、卤素、任选具有取代基的吡啶基和电子供能的芳基的取代基。A 是一种取代基，其中至少一个任选具有取代基的杂芳基或至少一个任选具有取代基的芳基氨基直接或通过其他芳香基键合到吡啶环 4 位的碳原子上。
• Organic light emitting diode
  申请人：LG DISPLAY CO., LTD.

  公开号：US10033007B2

  公开（公告）日：2018-07-24

  The present invention relates to an organic light emitting device, and comprises a first cathode, a second cathode, and an anode provided between the first cathode and the second cathode, in which a first light emitting unit is provided between the first cathode and the anode, a second light emitting unit is provided between the second cathode and the anode, and the first light emitting unit and the second emitting unit are connected in parallel with each other, the first light emitting unit comprises a first light emitting layer, and an organic material layer comprising the compound represented by Formula 1 is provided between the first light emitting layer and the anode, and the second light emitting unit comprises a second light emitting layer, and an organic material layer comprising the compound represented by Formula 1 is provided between the second light emitting layer and the anode.

  本发明涉及一种有机发光器件，包括第一阴极、第二阴极以及设置在第一阴极和第二阴极之间的阳极，其中第一阴极和阳极之间设置有第一发光单元，第二阴极和阳极之间设置有第二发光单元，第一发光单元和第二发光单元相互并联、第一发光单元包括第一发光层，在第一发光层和阳极之间设有由式 1 所代表的化合物组成的有机材料层，第二发光单元包括第二发光层，在第二发光层和阳极之间设有由式 1 所代表的化合物组成的有机材料层。