1,6-bis(2'-[1',10']phenanthrolinyl)pyrene | 646034-81-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,6-bis(2'-[1',10']phenanthrolinyl)pyrene
• 英文别名: 1,10-Phenanthroline, 2,2'-(1,6-pyrenediyl)bis-；2-[6-(1,10-phenanthrolin-2-yl)pyren-1-yl]-1,10-phenanthroline
• CAS: 646034-81-3
• 化学式: C₄₀H₂₂N₄
• 分子量: 558.641
• InChiKey: ZSOAJXAGZZKZFS-UHFFFAOYSA-N

物化性质

• 熔点：
  >280 °C(Solv: chloroform (67-66-3))
• 密度：
  1.389±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  44
• 可旋转键数：
  2
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  芘 、 alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 、 三氯化铝 作用下， 以 二硫化碳 、 乙醇 为溶剂， 生成 1,6-bis(2'-[1',10']phenanthrolinyl)pyrene
  参考文献：
  名称：

  芘桥联双(菲咯啉)配体及其双核钌(II)配合物

  摘要：

  8-氨基-7-喹啉甲醛与一系列四种异构二乙酰芘的弗里德兰德缩合提供相应的1,3-、1,6-、1,8-和2,7-双(2'-[1', 10']菲咯啉基)芘。这些配体，连同 2,7-芘桥连异构体的四氢类似物，已经用 [Ru([D8]bpy)2Cl2] 处理，其中 [D8]bpy = [D8]2,2'-联吡啶，为提供双核 RuII 配合物，其 1H NMR 和 X 射线晶体学分析表明，桥接芘分层在与每个金属原子配位的 [D8]bpy 辅助配体之间。尽管非常适合 π-π 相互作用，但对这些配合物的光物理和电化学性质几乎没有这种影响。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

  DOI：

  10.1002/ejic.200300031

文献信息

• LIGHT EMITTING ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2595208A1

  公开（公告）日：2013-05-22

  Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioethergroup, a halogen, a cyano group, a -P(=O)R24R25 group and a silyl group;R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)

  本发明提供了一种有机薄膜发光元件，它实现了发光效率的提高、驱动电压的提高和耐用寿命的提高。具体地说，本发明提供了一种发光元件，它包括位于正极和负极之间的空穴传输层和电子传输层，并通过电能发光。该发光元件的特征在于：发光元件的空穴传输层含有通式（1）表示的化合物；电子传输层含有供体化合物；供体化合物是碱金属、含碱金属的无机盐、碱金属和有机物的复合物、碱土金属、含碱土金属的无机盐或碱土金属和有机物的复合物。(式中，R1-R20 各代表一个选自氢、氘、烷基、环烷基、氨基、芳基、杂环基、杂芳基、烯基、环烯基、炔基、烷氧基、烷硫基、芳醚基、芳硫醚基、卤素、氰基、-P(=O)R24R25 基和硅烷基的基团；R24 和 R25 分别代表芳基或杂芳基；这些取代基可以进一步被取代，或者相邻的两个取代基可以结合在一起形成一个环。同时，R21-R23 可以相同或不同，各自代表一个选自烷基、环烷基、芳基和杂芳基的基团；这些取代基可能被进一步取代）。
• ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Sony Corporation

  公开号：EP2833429A1

  公开（公告）日：2015-02-04

  An organic electroluminescence device including: an anode; one or more organic thin film layers including an emitting layer; a donor-containing layer; an acceptor-containing layer; and a light-transmissive cathode in this order, wherein the donor-containing layer comprises a compound represented by the following formula (I) or (II):

  一种有机电致发光器件，包括：一个阳极；一个或多个有机薄膜层，其中包括一个发光层；一个含供体层；一个含受体层；以及一个透光阴极，其中含供体层依次包括下式（I）或（II）所代表的化合物：
• Organic electroluminescent device
  申请人：JOLED INC

  公开号：US10573823B2

  公开（公告）日：2020-02-25

  An organic electroluminescence device including: an anode; a cathode; two or more emitting units that are disposed between the anode and the cathode, each unit having an emitting layer; and a charge-generating layer that is disposed between the emitting units, wherein the charge-generating layer includes an N layer nearer to the anode and a P layer nearer to the cathode, and the N layer includes a compound represented by the following formula (I) or (II):

  一种有机电致发光器件，包括：一个阳极；一个阴极；两个或两个以上设置在阳极和阴极之间的发光单元，每个单元都有一个发光层；以及一个设置在发光单元之间的电荷发生层，其中电荷发生层包括一个靠近阳极的 N 层和一个靠近阴极的 P 层，N 层包括下式（I）或（II）所代表的化合物：
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Sony Corporation

  公开号：US20150069351A1

  公开（公告）日：2015-03-12

  An organic electroluminescence device including: an anode; one or more organic thin film layers including an emitting layer; a donor-containing layer; an acceptor-containing layer; and a light-transmissive cathode in this order, wherein the donor-containing layer comprises a compound represented by the following formula (I) or (II):
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Sony Corporation

  公开号：US20150303380A1

  公开（公告）日：2015-10-22

  An organic electroluminescence device including: an anode; a cathode; two or more emitting units that are disposed between the anode and the cathode, each unit having an emitting layer; and a charge-generating layer that is disposed between the emitting units, wherein the charge-generating layer includes an N layer nearer to the anode and a P layer nearer to the cathode, and the N layer includes a compound represented by the following formula (I) or (II):