1-(2,6-dimethoxy-4-fluorophenyl)-2-methylpropan-1-one | 263010-96-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2,6-dimethoxy-4-fluorophenyl)-2-methylpropan-1-one
• 英文别名: 1-(4-fluoro-2,6-dimethoxyphenyl)-2-methylpropan-1-one
• CAS: 263010-96-4
• 化学式: C₁₂H₁₅FO₃
• 分子量: 226.248
• InChiKey: SZOFBXUBUMPPBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(2,6-dimethoxy-4-fluorophenyl)-2-methylpropan-1-one 、 吗啉 、 potassium carbonate 在 氩 、 水 、 二氯甲烷 、 碳酸氢钠 作用下， 以 二甲基亚砜 为溶剂， 反应 16.0h， 以to yield the final product, 1-(2,6-dimethoxy-4-morpholinophenyl)-2-methylpropan-1-one的产率得到
  参考文献：
  名称：

  Photoinitiators and applications therefor

  摘要：

  本发明涉及具有以下一般式的新型高效能光引发剂：其中X1是共轭系统，例如一个或多个芳基或取代芳基；Z1是-O、-S、一个具有1至6个碳原子的烷基、酯基、酮基、胺基、亚胺基、醚基、芳基或取代芳基、金属或非金属，或者是一个含金属或非金属的基团，例如含锌基团或含硼基团的基团；M1是烷基、取代烷基或与Z1形成五元环。本发明还涉及一种产生反应物种的方法，其包括将一个或多个光引发剂暴露于辐射中以形成一个或多个反应物种。还描述了聚合可聚合材料的方法、固化不饱和低聚物/单体混合物的方法以及使用本发明的光引发剂进行层压的方法。此外，本发明还涉及油墨组合物、粘合剂组合物和树脂以及使用上述光引发剂进行印刷的方法。

  公开号：

  US06265458B1
• 作为产物：
  描述：

  1,3-二甲氧基-5-氟苯 、 异丁酰氯 在 AlCl₃ 作用下， 以 硝基苯 为溶剂， 生成 1-(2,6-dimethoxy-4-fluorophenyl)-2-methylpropan-1-one
  参考文献：
  名称：

  CHELATES COMPRISING CHINOID GROUPS AS PHOTOINITIATORS

  摘要：

  公开号：

  EP1117698B1

文献信息

• US6265458B1
  申请人：——

  公开号：US6265458B1

  公开（公告）日：2001-07-24
• [EN] NOVEL PHOTOINITIATORS AND APPLICATIONS THEREFOR<br/>[FR] NOUVEAUX PHOTOAMORCEURS ET LEURS UTILISATIONS
  申请人：KIMBERLY CLARK CO

  公开号：WO2000018750A2

  公开（公告）日：2000-04-06

  The present invention is directed to new, energy-efficient, photoinitiators having general formula (I) wherein X1 is a conjugated system such as one or more aryl groups or substituted aryl groups; Z1 is -O, -S, an alkyl group having from one to six carbon atoms, an ester moiety, a ketone moiety, an amine moiety, an imine moiety, an ether moiety, an aryl or substituted aryl group, a metal or non-metal, or a metal or non-metal containing group, such as a zinc-containing group or a boron-containing group, respectively; and M1 is an alkyl group, a substituted alkyl group, or forms a five member ring with Z1. The present invention is also directed to a method of generating a reactive species, which includes exposing one or more photoinitiators to radiation to form one or more reactive species. Also described are methods of polymerizing polymerizable materials, methods of curing an unsaturated oligomer/monomer mixture, and methods of laminating using the photoinitiators of the present invention. In addition, the present invention is directed to ink compositions, adhesive compositions and resins, and methods of printing using the above-described photoinitiators.
• [EN] CHELATES COMPRISING CHINOID GROUPS AS PHOTOINITIATORS<br/>[FR] NOUVEAUX PHOTOAMORCEURS ET LEURS UTILISATIONS
  申请人：——

  公开号：WO2000018750A9

  公开（公告）日：2001-07-26

  [EN] The present invention is directed to new, energy-efficient, photoinitiators having general formula (I) wherein X1 is a conjugated system such as one or more aryl groups or substituted aryl groups; Z1 is -O, -S, an alkyl group having from one to six carbon atoms, an ester moiety, a ketone moiety, an amine moiety, an imine moiety, an ether moiety, an aryl or substituted aryl group, a metal or non-metal, or a metal or non-metal containing group, such as a zinc-containing group or a boron-containing group, respectively; and M1 is an alkyl group, a substituted alkyl group, or forms a five member ring with Z1. The present invention is also directed to a method of generating a reactive species, which includes exposing one or more photoinitiators to radiation to form one or more reactive species. Also described are methods of polymerizing polymerizable materials, methods of curing an unsaturated oligomer/monomer mixture, and methods of laminating using the photoinitiators of the present invention. In addition, the present invention is directed to ink compositions, adhesive compositions and resins, and methods of printing using the above-described photoinitiators.
  [FR] La présente invention concerne de nouveaux photoamorceurs, à haut rendement énergétique, représentés par la formule générale (I). Dans cette formule, X1 est un système conjugué tel que un ou plusieurs groupes aryle ou substitués aryle; Z1 est -O, -S, un groupe alkyle possédant de un à six atomes de carbone, une fraction ester, une fraction cétone, une fraction amine, une fraction imine, une fraction éther, un groupe aryle ou substitué aryle, un métal ou un non-métal, ou bien un groupe renfermant un métal ou un non-métal, par exemple un groupe renfermant du zinc ou un groupe renfermant du bore, respectivement; et M<1> est un groupe alkyle, un groupe substitué alkyle, ou forme un noyau à cinq éléments avec Z<1>. Cette invention concerne également un procédé permettant d'obtenir une espèce réactive par exposition d'un ou de plusieurs photamorceurs à un rayonnement pour former une ou plusieurs espèces actives. De plus, l'invention concerne des procédés de polymérisation de matières polymérisables, de traitement d'un mélange oligomère/monomère insaturé et de stratification au moyen des photoamorceurs couverts par la présente invention. Enfin, cette invention concerne des compostions d'encres, des compositions adhésives et des résines, ainsi que des procédés d'impression au moyen des photoamorceurs décrits ci-dessus.
• CHELATES COMPRISING CHINOID GROUPS AS PHOTOINITIATORS
  申请人：KIMBERLY-CLARK WORLDWIDE, INC.

  公开号：EP1117698B1

  公开（公告）日：2006-04-19
• Photoinitiators and applications therefor
  申请人：Kimberly-Clark Worldwide, Inc.

  公开号：US06265458B1

  公开（公告）日：2001-07-24

  The present invention is directed to new, energy-efficient, photoinitiators having the following general formula: wherein of X1 is a conjugated system such as one or more aryl groups or substituted aryl groups; Z1 is —O, —S, an alkyl group having from one to six carbon atoms, an ester moiety, a ketone moiety, an amine moiety, an imine moiety, an ether moiety, an aryl or substituted aryl group, a metal or non-metal, or a metal or non-metal containing group, such as a zinc-containing group or a boron-containing group, respectively; and M1 is an alkyl group, a substituted alkyl group, or forms a five-member ring with Z1. The present invention is also directed to a method of generating a reactive species, which includes exposing one or more photoinitiators to radiation to form one or more reactive species. Also described are methods of polymerizing polymerizable materials, methods of curing an unsaturated oligomer/monomer mixture, and methods of laminating using the photoinitiators of the present invention. In addition, the present invention is directed to ink compositions, adhesive compositions and resins, and methods of printing using the above-described photoinitiators.

  本发明涉及具有以下一般式的新型高效能光引发剂：其中X1是共轭系统，例如一个或多个芳基或取代芳基；Z1是-O、-S、一个具有1至6个碳原子的烷基、酯基、酮基、胺基、亚胺基、醚基、芳基或取代芳基、金属或非金属，或者是一个含金属或非金属的基团，例如含锌基团或含硼基团的基团；M1是烷基、取代烷基或与Z1形成五元环。本发明还涉及一种产生反应物种的方法，其包括将一个或多个光引发剂暴露于辐射中以形成一个或多个反应物种。还描述了聚合可聚合材料的方法、固化不饱和低聚物/单体混合物的方法以及使用本发明的光引发剂进行层压的方法。此外，本发明还涉及油墨组合物、粘合剂组合物和树脂以及使用上述光引发剂进行印刷的方法。