2,2’-(3,5,5-三甲基亚己基)双[4,6-二甲基苯酚] | 7292-14-0

• 物质功能分类: 有机原料 - 醇、酚、酚醇类化合物及衍生物 - 酚及其卤化、磺化、硝化或亚硝化衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2’-(3,5,5-三甲基亚己基)双[4,6-二甲基苯酚]
• 中文别名: 2,2'-(3,5,5-三甲基亚己基)双[4,6-二甲基苯酚]
• 英文名称: 1,1-bis(2-hydroxy-3,5-dimethylphenyl)-3,5,5-trimethylhexane
• 英文别名: 2,2'-(3,5,5-trimethylhexylidene)bis[4,6-dimethylphenol]；2-[1-(2-hydroxy-3,5-dimethylphenyl)-3,5,5-trimethylhexyl]-4,6-dimethylphenol
• CAS: 7292-14-0
• 化学式: C₂₅H₃₆O₂
• 分子量: 368.56
• InChiKey: RPWDFMGIRPZGTI-UHFFFAOYSA-N

物化性质

• 熔点：
  169-170 °C
• 沸点：
  482.9±40.0 °C(Predicted)
• 密度：
  1.012±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2’-(3,5,5-三甲基亚己基)双[4,6-二甲基苯酚] 在 4-二甲氨基吡啶 、 三乙胺 、 三氯氧磷 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以30%的产率得到6-hydroxy-2,4,8,10-tetramethyl-12-(2,2,4-trimethylpentyl)-12H-dibenzo<1,3,2>dioxaphosphocin 6-oxide
  参考文献：
  名称：

  Goddard, John D.; Payne, Alan W.; Cook, Nick, Journal of Heterocyclic Chemistry, 1988, vol. 25, p. 575 - 588

  摘要：

  DOI：

文献信息

• Method for treating allergies using substituted pyrazoles
  申请人：Butler R. Christopher

  公开号：US20050101587A9

  公开（公告）日：2005-05-12

  A method for treating an allergic condition, including an atopic allergic condition, using substituted pyrazoles.

  使用取代吡唑烷治疗过敏症状的方法，包括特应性过敏症状。
• Method for producing grains of aliphatic acid silver salt and thermally processed image recording material
  申请人：——

  公开号：US20010018170A1

  公开（公告）日：2001-08-30

  A method for producing grains of aliphatic acid silver salt by mixing a solution containing silver ions and a solution of aliphatic acid alkali metal salt to attain reaction of them, wherein (1) 95-100% of the total molar number to be added of the aliphatic acid alkali metal salt is added under a condition that dilution factor of the solution of aliphatic acid alkali metal salt becomes 10-fold or higher at 1 second after the addition, (2) 95-100% of the total amount to be added of silver in the solution containing silver ions is added under a condition that dilution factor of the solution containing silver ions becomes 20-fold or higher at 1 second after the addition, and (3) 50-100% of the total amount to be added of the solution of aliphatic acid alkali metal salt is added simultaneously with the solution containing silver ions. According to the present invention, there is provided a method for producing grains of aliphatic acid silver salt, which show excellent fog prevention ability, in addition, excellent fog prevention ability even after time lapse, when used in a thermally processed image recording material.

  本发明提供了一种制备脂肪族酸银盐颗粒的方法，包括将含有银离子的溶液和脂肪族酸碱金属盐的溶液混合以使它们反应，其中（1）脂肪族酸碱金属盐的总摩尔数的95-100％在加入后1秒钟时，脂肪族酸碱金属盐的稀释因子变为10倍或更高，（2）所含银离子的溶液中总添加量的95-100％在加入后1秒钟时，银离子溶液的稀释因子变为20倍或更高，（3）脂肪族酸碱金属盐溶液的总添加量的50-100％同时与含银离子的溶液一起加入。该发明提供了一种制备脂肪族酸银盐颗粒的方法，该颗粒具有出色的防雾能力，并且即使在时间流逝后，当用于热处理的图像记录材料时，仍具有出色的防雾能力。
• Method for preparing non-photosensitive fatty acid silver salt grains and an apparatus for preparing the same
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030023103A1

  公开（公告）日：2003-01-30

  A method for preparing non-photosensitive fatty acid silver salt grains was disclosed. The method has the step of reacting a silver ion-containing solution, the solvent of which being water or a mixture of water and an organic solvent, with a solution of a fatty acid alkali metal salt, the solvent of which being water, an organic solvent, or a mixture of water and an organic solvent, to obtain fatty acid silver salt grains; in which the reaction is proceeded by mixing the silver ion-containing solution and the solution of the fatty acid alkali metal salt within a closed mixing means. The dispersion of the non-photosensitive fatty acid silver salt grains prepared according to such method is excellent in dispersion stability and coating property.

  本发明公开了一种制备非感光脂肪酸银盐颗粒的方法。该方法包括以下步骤：将含有银离子的溶液与一种脂肪酸碱金属盐的溶液反应，其中溶剂为水或水和有机溶剂的混合物，而脂肪酸碱金属盐的溶剂为水、有机溶剂或水和有机溶剂的混合物，以获得脂肪酸银盐颗粒；在封闭的混合装置中混合含银离子的溶液和脂肪酸碱金属盐的溶液进行反应。根据这种方法制备的非感光脂肪酸银盐颗粒的分散性和涂层性能都非常优秀。
• Bisphenol-phosphorous compound complex and thermally processed image recording material utilizing the same
  申请人：——

  公开号：US20020009683A1

  公开（公告）日：2002-01-24

  Bisphenol-phosphorus compound complexes represented by the following general formula (1) are disclosed (R 1 to R 4 represent hydrogen atom or a group that can be a substituent on a benzene ring; L represents —S— group or a —CHR 5 — group where R 5 represents hydrogen atom or an alkyl group; and R 6 to R 8 represent an alkyl group, an aryl group, a heterocyclic group etc.). The present invention provides reducing agents that can realize thermally processed image recording materials that can provide sufficient image density at a practical reaction temperature (specifically 100-140° C.) and within a practical reaction time (specifically 1-30 seconds), and can sufficiently suppress the coloration of white portions when the materials are stored in a dark place after the development.

  本发明揭示了以下一般式（1）所代表的双酚-磷化合物配合物（其中R1至R4代表氢原子或苯环上可取代基团；L代表—S—基团或—CHR5—基团，其中R5代表氢原子或烷基；R6至R8代表烷基、芳基、杂环基等）。本发明提供了还原剂，可以实现在实际反应温度（具体为100-140℃）和实际反应时间（具体为1-30秒）内提供足够的图像密度的热处理图像记录材料，并且在开发后在暗处存储材料时可以充分抑制白色部分的着色。
• Polyhalogenomethylsulfonyl compound
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US20020018955A1

  公开（公告）日：2002-02-14

  ? The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: 1 wherein Z 1 and Z 2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R 1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.

  本发明的目的是提供一种新型的聚卤代甲基磺酰化合物，可用于提供具有高灵敏度、较少雾化、良好的库存稳定性和良好的暗高温或光存储稳定性的热处理图像记录材料。根据本发明，提供了由以下式（1）表示的聚卤代甲基磺酰化合物，或其盐，或其水合物或溶剂化物：其中Z1和Z2各自独立地表示卤素原子；A表示氢原子或卤素原子；R1表示具有2至12个碳原子的烷基基团，可以具有一个或多个取代基，具有2至12个碳原子的烯基基团，可以具有一个或多个取代基，或具有2至12个碳原子的炔基基团，可以具有一个或多个取代基。