1,2-bis[5-(4-phenylquinolinyl)-2-methyl-3-thienyl]perfluorocyclopentene | 869104-59-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,2-bis[5-(4-phenylquinolinyl)-2-methyl-3-thienyl]perfluorocyclopentene
• 英文别名: 2-[4-[3,3,4,4,5,5-Hexafluoro-2-[2-methyl-5-(4-phenylquinolin-2-yl)thiophen-3-yl]cyclopenten-1-yl]-5-methylthiophen-2-yl]-4-phenylquinoline
• CAS: 869104-59-6
• 化学式: C₄₅H₂₈F₆N₂S₂
• 分子量: 774.853
• InChiKey: BQZOVPXCPDDQLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  55
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  82.3
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,2-bis[5-(4-phenylquinolinyl)-2-methyl-3-thienyl]perfluorocyclopentene 以 二氯甲烷 为溶剂， 生成 C₄₅H₂₈F₆N₂S₂
  参考文献：
  名称：

  Photochromism and Electrical Transport Characteristics of a Dyad and a Polymer with Diarylethene and Quinoline Units

  摘要：

  The synthesis of a series of photochromic compounds incorporating a phenylquinoline unit and the photophysical and electric transport properties are described. The dyad and polymer with a quinoline unit show a high quantum yield due to the enforced antiparallel conformation of the dithienylethene moieties. High carrier conductivity was observed in the closed form of the diarylethene with a phenylquinoline unit.

  DOI：

  10.1021/jo050710t
• 作为产物：
  描述：

  1,2-bis(2-methyl-3-thienyl)perfluorocyclopentene 在 磷酸二苯酯 、 四氯化锡 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 生成 1,2-bis[5-(4-phenylquinolinyl)-2-methyl-3-thienyl]perfluorocyclopentene
  参考文献：
  名称：

  Photochromism and Electrical Transport Characteristics of a Dyad and a Polymer with Diarylethene and Quinoline Units

  摘要：

  The synthesis of a series of photochromic compounds incorporating a phenylquinoline unit and the photophysical and electric transport properties are described. The dyad and polymer with a quinoline unit show a high quantum yield due to the enforced antiparallel conformation of the dithienylethene moieties. High carrier conductivity was observed in the closed form of the diarylethene with a phenylquinoline unit.

  DOI：

  10.1021/jo050710t

文献信息

• Photochromism and Electrical Transport Characteristics of a Dyad and a Polymer with Diarylethene and Quinoline Units
  作者：Hyunbong Choi、Hyowon Lee、Youngjin Kang、Eunkyoung Kim、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/jo050710t

  日期：2005.10.1

  The synthesis of a series of photochromic compounds incorporating a phenylquinoline unit and the photophysical and electric transport properties are described. The dyad and polymer with a quinoline unit show a high quantum yield due to the enforced antiparallel conformation of the dithienylethene moieties. High carrier conductivity was observed in the closed form of the diarylethene with a phenylquinoline unit.