1,2-bis(5-acetyl-2-methyl-3-thienyl)perfluorocyclopentene | 869104-58-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-bis(5-acetyl-2-methyl-3-thienyl)perfluorocyclopentene
• 英文别名: 1-[4-[2-(5-Acetyl-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophen-2-yl]ethanone
• CAS: 869104-58-5
• 化学式: C₁₉H₁₄F₆O₂S₂
• 分子量: 452.441
• InChiKey: WXPRWPCWBZHJBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  90.6
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,2-bis(5-acetyl-2-methyl-3-thienyl)perfluorocyclopentene 以 甲苯 为溶剂， 生成 1-(8-acetyl-4,4,5,5,6,6-hexafluoro-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trinden-2-yl)-ethanone
  参考文献：
  名称：

  Photochromism of Thienyl-Containing Dihetarylethenes with Five-Membered Cyclic Bridges

  摘要：

  Spectral-kinetic characteristics of a number of new photochromic dihetaryethenes with different five-membered cyclic bridges are measured and discussed. It was shown that these characteristics depend on a bridge structure as well as a nature of substituents in the thienyl fragments.

  DOI：

  10.1080/15421400590946352
• 作为产物：
  描述：

  1-(8-acetyl-4,4,5,5,6,6-hexafluoro-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trinden-2-yl)-ethanone 以 甲苯 为溶剂， 生成 1,2-bis(5-acetyl-2-methyl-3-thienyl)perfluorocyclopentene
  参考文献：
  名称：

  Photochromism of Thienyl-Containing Dihetarylethenes with Five-Membered Cyclic Bridges

  摘要：

  Spectral-kinetic characteristics of a number of new photochromic dihetaryethenes with different five-membered cyclic bridges are measured and discussed. It was shown that these characteristics depend on a bridge structure as well as a nature of substituents in the thienyl fragments.

  DOI：

  10.1080/15421400590946352

文献信息

• Photochromism and Electrical Transport Characteristics of a Dyad and a Polymer with Diarylethene and Quinoline Units
  作者：Hyunbong Choi、Hyowon Lee、Youngjin Kang、Eunkyoung Kim、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/jo050710t

  日期：2005.10.1

  The synthesis of a series of photochromic compounds incorporating a phenylquinoline unit and the photophysical and electric transport properties are described. The dyad and polymer with a quinoline unit show a high quantum yield due to the enforced antiparallel conformation of the dithienylethene moieties. High carrier conductivity was observed in the closed form of the diarylethene with a phenylquinoline unit.
• Photochromism of Thienyl-Containing Dihetarylethenes with Five-Membered Cyclic Bridges
  作者：V. A. Barachevsky、Yu. P. Strokach、M. M. Krayushkin

  DOI：10.1080/15421400590946352

  日期：2005.5.1

  Spectral-kinetic characteristics of a number of new photochromic dihetaryethenes with different five-membered cyclic bridges are measured and discussed. It was shown that these characteristics depend on a bridge structure as well as a nature of substituents in the thienyl fragments.