Taming elemental fluorine: Indirect use of fluorine for the synthesis of α-fluoroketones[1]
作者:Shlomo Rozen、Ynon Menahem
DOI:10.1016/s0022-1139(00)85146-5
日期:1980.7
Fluorine and sodium trifluoroacetate react at −75° to produce a variety of fluoroxy-compounds. Although it is possible to direct the reaction towards the formation of CF3COOF or CF3CF2OF, mixtures may be used when only the electrophilicfluorine has to be attached to the molecule of interest. Such is the case of the reaction of enol-acetates with the mixture of the fluoroxy reagents. A wide variety