4-(6-Acryloyloxyhexyloxy)benzaldehyde | 140918-55-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-(6-Acryloyloxyhexyloxy)benzaldehyde
• 英文别名: 6-(4-formylphenoxy)hexyl prop-2-enoate
• CAS: 140918-55-4
• 化学式: C₁₆H₂₀O₄
• 分子量: 276.332
• InChiKey: HMTODOFZQFNLST-UHFFFAOYSA-N

物化性质

• 沸点：
  413.6±25.0 °C(Predicted)
• 密度：
  1.080±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(6-Acryloyloxyhexyloxy)benzaldehyde 在 sodium chlorite 、 sodium dihydrogenphosphate 、 双氧水 、 盐酸 作用下， 以 水 、 乙酸乙酯 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 14.0h， 以13.40 g的产率得到4-(6-(丙烯酰氧基)己氧基)苯甲酸
  参考文献：
  名称：

  Process for the preparation of aromatic carboxylic acid

  摘要：

  公开号：

  EP1174411B1
• 作为产物：
  描述：

  对羟基苯甲醛 在 2,6-二叔丁基-4-甲基苯酚 、 potassium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 反应 27.75h， 生成 4-(6-Acryloyloxyhexyloxy)benzaldehyde
  参考文献：
  名称：

  TWI520948

  摘要：

  公开号：

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC SUBSTANCE
  申请人：ZEON CORPORATION

  公开号：US20150274647A1

  公开（公告）日：2015-10-01

  The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y 1 to Y 8 are a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—, or the like; G 1 and G 2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z 1 and Z 2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A 1 is a tetravalent aromatic group, or the like; A 2 and A 3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A 4 and A 5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; A x1 and A x2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; A y1 and A y2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q 1 and Q 2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; and m and n are 0 or 1]. According to the present invention, a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.

  本发明涉及：由式(I)表示的可聚合化合物；包括所述可聚合化合物和引发剂的可聚合组合物；通过聚合所述可聚合化合物或可聚合组合物得到的聚合物；以及包括所述聚合物的光学各向异性物品[在该式中，Y1至Y8为化学单键，—O—，—O—C(═O)—，—C(═O)—O—等；G1和G2为具有1至20个碳原子的二价脂肪族基等；Z1和Z2为具有2至10个碳原子的烯基基团等；A1为四价芳香族基等；A2和A3为具有3至30个碳原子的二价脂环烃基等；A4和A5为具有4至30个碳原子的二价芳香族基等；Ax1和Ax2为包括芳香环的具有2至30个碳原子的有机基团等；Ay1和Ay2为氢原子、具有1至6个碳原子的烷基基团等；Q1和Q2为氢原子、具有1至6个碳原子的烷基基团等；m和n为0或1]。根据本发明，可以制备具有实用低熔点、在通用溶剂中具有优异溶解性、成本低廉的可聚合化合物、可聚合组合物和聚合物，并且可以生产出在宽波长范围内实现偏振光均匀转换的光学薄膜，同时提供光学各向异性物品。
• High polymer-nonlinear optical material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US05408009A1

  公开（公告）日：1995-04-18

  A high polymer which is a precursor capable of forming a hydrogen bond at a temperature of 40.degree. C. or more and a high polymer capable of forming a hydrogen bond, and a nonlinear optical material comprising a thin polymer film containing the high polymer and a method for forming the nonlinear optical material are disclosed. The thin polymer film containing the high polymer may be oriented in the electric field at a low temperature to give a nonlinear optical material.

  本发明公开了一种高分子前体，能够在40摄氏度或更高温度下形成氢键，以及一种能够形成氢键的高分子和包含该高分子的薄聚合物膜的非线性光学材料以及形成该非线性光学材料的方法。含有该高分子的薄聚合物膜可以在低温下在电场中定向，从而形成非线性光学材料。
• Fluorine-containing acrylate and methacrylate side-chain liquid crystal
  申请人：Minnesota Mining and Manufacturing Company

  公开号：US05087672A1

  公开（公告）日：1992-02-11

  The present invention relates to novel fluorinated acrylate and methacrylate ester monomers and homopolymers and copolymers thereof. In another aspect, it relates to a process for preparing monomers of the invention. Homopolymers and copolymers of the invention have units which correspond to the following general chemical formula: ##STR1## wherein R is hydrogen, halo, a C.sub.1 to C.sub.4 alkyl or haloalkyl group, or a C.sub.6 to C.sub.10 aryl group, W is --O-- or --NR.sup.1 --, wherein R.sup.1 is hydrogen or a C.sub.1 to C.sub.4 alkyl group, X is a carbon-to-carbon single bond or a spacer group, Y is a mesogenic group, and Z is a fluorinated alkyl group. The novel monomers and polymers can be liquid crystals.

  本发明涉及新型氟丙烯酸酯和甲基丙烯酸酯单体及其同聚物和共聚物。另一方面，它涉及一种制备本发明单体的方法。本发明的同聚物和共聚物具有与以下一般化学式相对应的单元：##STR1##其中R为氢、卤素、C.sub.1至C.sub.4烷基或卤代烷基，或C.sub.6至C.sub.10芳基；W为--O--或--NR.sup.1--，其中R.sup.1为氢或C.sub.1至C.sub.4烷基；X为碳-碳单键或空间基团；Y为介质基团；Z为氟化烷基。新型单体和聚合物可以是液晶。
• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Kubota Yusuke

  公开号：US20130334461A1

  公开（公告）日：2013-12-19

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).

  提供了一种可聚合的液晶组合物、涂料材料、介质和极化装置，每种都使用了聚合液晶化合物和颜料，并且能够产生适合于极化装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗红衍生物和一种新型蒽衍生物，每种都适用于用作颜料。具体提供了一种聚合液晶组合物，包含（A）至少一种具有聚合功能基团的液晶化合物，（B）至少一种颜料，和（C）聚合引发剂，以及一种适用于用作颜料（B）的新型萘内酰胺衍生物（IV′）, 一种新型香豆素衍生物（VI′）, 一种新型尼罗红衍生物（VII′）和一种新型蒽衍生物（VIII′）。