(Z)-pentyl 3-phenylacrylate | 683774-98-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: (Z)-pentyl 3-phenylacrylate
• 英文别名: cis-Amyl cinnamate；pentyl (Z)-3-phenylprop-2-enoate
• CAS: 683774-98-3
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: QDRJCWZGTMRXCL-KHPPLWFESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  戊醇 、 一氧化碳 、 Phenylacetaldehyd-enoltosylat 在 potassium phosphate 、 palladium diacetate 作用下， 以 甲苯 为溶剂， 100.0 ℃ 、689.49 kPa 条件下， 反应 14.0h， 生成 pentyl cinnamate 、 (Z)-pentyl 3-phenylacrylate
  参考文献：
  名称：

  钯催化乙烯基甲苯磺酸酯的烷氧基和氨基羰基化

  摘要：

  描述了甲苯磺酸乙烯基酯的钯催化的烷氧基羰基化和氨基羰基化。在伯，仲和叔醇，或伯和仲胺的存在下，各种酮和醛衍生的乙烯基甲苯磺酸酯可以被羰基化，以高收率提供相应的酯和酰胺。将烷氧羰基化用于异古瓦汀的短合成。

  DOI：

  10.1021/ol200744s

文献信息

• ANTIPERSPIRANT AND DEODORANT COMPOSITIONS COMPRISING MALODOR REDUCTION COMPOSITIONS
  申请人：The Procter & Gamble Company

  公开号：US20160089317A1

  公开（公告）日：2016-03-31

  The present invention relates to antiperspirant and deodorant compositions comprising malodor reduction compositions and methods of making and using such antiperspirant and deodorant compositions. Such antiperspirant and deodorant compositions comprising the malodor control technologies disclosed herein provide malodor control without leaving an undesirable scent and when perfume is used to scent such compositions, such scent is not unduely altered by the malodor control technology.
• CLEANING AND/OR TREATMENT COMPOSITIONS COMPRISING MALODOR REDUCTION COMPOSITIONS
  申请人：The Procter & Gamble Company

  公开号：US20160090555A1

  公开（公告）日：2016-03-31

  The present invention relates to cleaning and/or treatment compositions comprising malodor reduction compositions and methods of making and using such cleaning and/or treatment compositions and malodor reduction compositions. As a result, such malodor reduction compositions do not unduely interfere with the scent of the perfumed or unperfumed cleaning and/or treatment compositions that comprise such compositions and the perfumed or unperfumed situs that is treated with such cleaning and/or treatment compositions.
• Palladium Catalyzed Alkoxy- and Aminocarbonylation of Vinyl Tosylates
  作者：Diana C. Reeves、Sonia Rodriguez、Heewon Lee、Nizar Haddad、Dhileepkumar Krishnamurthy、Chris H. Senanayake

  DOI：10.1021/ol200744s

  日期：2011.5.6

  The palladium catalyzed alkoxycarbonylation and aminocarbonylation of vinyl tosylates are described. A variety of ketone and aldehyde derived vinyl tosylates may be carbonylated in the presence of primary, secondary, and tertiary alcohols, or primary and secondary amines, to provide the corresponding esters and amides in good yields. The alkoxycarbonylation was applied to a short synthesis of isoguvacine

  描述了甲苯磺酸乙烯基酯的钯催化的烷氧基羰基化和氨基羰基化。在伯，仲和叔醇，或伯和仲胺的存在下，各种酮和醛衍生的乙烯基甲苯磺酸酯可以被羰基化，以高收率提供相应的酯和酰胺。将烷氧羰基化用于异古瓦汀的短合成。