trimethylene glycol mono-2-methylallyl ether | 111718-99-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trimethylene glycol mono-2-methylallyl ether
• 英文别名: 3-(2-Methylprop-2-enoxy)propan-1-ol
• CAS: 111718-99-1
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: QTZQWDQHGJHHON-UHFFFAOYSA-N

物化性质

• 沸点：
  205.7±15.0 °C(Predicted)
• 密度：
  0.911±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trimethylene glycol mono-2-methylallyl ether 在 sodium hydroxide 、 N-溴代丁二酰亚胺(NBS) 、 sodium 、 苯磺酰氯 作用下， 以 1,4-二氧六环 、 乙醇 为溶剂， 反应 92.0h， 生成 3-methyl-3-<(8-quinolinyloxy)methyl>-16-crown-5
  参考文献：
  名称：

  套索醚给电子侧臂的分子设计：喹啉部分与碱金属阳离子络合的有效配位

  摘要：

  La propriete de Coordination specifique du reste quinoleine (braslateral du lariat) est etudiee en mesurant l'aptitude complexante dans le甲醇 a 25°C

  DOI：

  10.1021/ja00210a037
• 作为产物：
  描述：

  3-(3-Allyloxy-propoxy)-2-methyl-propene 在 titanium(IV) isopropylate 、 环己氯化镁 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到trimethylene glycol mono-2-methylallyl ether
  参考文献：
  名称：

  烯丙基醚的选择性裂解

  摘要：

  通过使用Ti（Oi - Pr）4和可商购的格氏试剂，开发了一种用于烯丙基醚选择性裂解为醇的简单的一步法。

  DOI：

  10.1016/0040-4039(96)00657-0

文献信息

• EFFECT OF POSITION OF ELECTRON-DONATING SIDEARM OF 16-CROWN-5 ON COMPLEXATION TOWARD Na⁺AND K⁺
  作者：Yohji Nakatsuji、Masayuki Yonetani、Mitsuo Okahara

  DOI：10.1246/cl.1984.2143

  日期：1984.12.5

  Several 16-crown-5 derivatives having an electron-donating sidearm were newly prepared and their stability constants toward Na+ and K+ were measured. The difference in the position of the sidearm was disclosed to change remarkably the complexation property of such type of compounds.

  新制备了数种具有电子供体侧臂的16-冠-5衍生物，并测定了它们对Na+和K+的稳定常数。发现侧臂位置的差异显著改变了此类化合物的配位性质。
• Siloxy-[2,3]Wittig rearrangement: A new method for diastereoselective preparations of 1,2-diol systems
  作者：Ei-ichi Nakai、Takeshi Nakai

  DOI：10.1016/s0040-4039(00)82881-6

  日期：——

  A novel [2,3]Wittig variant, termed “siloxy-[2,3]Wittig rearrangement”, has been developed which provides the half-silylated 1,2-diol systems with a high anti-diastereoselectivity. The unusual anti-selectivity is discussed on mechanistic grounds.

  已经开发了被称为“甲硅烷氧基-[2,3] Wittig重排”的新颖的[2,3] Wittig变体，其为半甲硅烷基化的1,2-二醇系统提供了高的非对映选择性。基于机械原理讨论了异常的抗选择性。
• Radiation-curable protective coating composition
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0327258A2

  公开（公告）日：1989-08-09

  Normally solid, organic solvent-soluble, thermoplastic, polyethylenically-unsaturated, cellulosic polyurethane polymers are provided. These cellulosic polyurethane polymers comprise one or more cellulose ether or ester segments, one or more alkylene moieties having at least two carbon atoms and which can be substituted or interrupted by ether oxygen atoms, ester groups, or phenylene groups, two or more residues of diisocyanates, the segments, moieties, and residues being linked together by linking groups with the proviso that said alkylene moieties contain sufficient ethylenic unsaturation that said polymer can be crosslinked to a solvent-insoluble state. The cellulosic polyurethane polymers can be obtained by the polymerization of a reaction mixture comprising (a) aliphatic or cycloaliphatic diol comprising sufficient ethylenically-unsaturated diol to permit crosslinking of the polymerization product to a solvent-insoluble state; (b) organic solvent-soluble cellulose ether or ester having residual unreacted cellulosic hydroxyl groups; and (c) organic diisocyanate. The reaction product may optionally also contain primary or secondary aliphatic or aromatic diamines or dithiols. Also provided are coating compositions and shaped articles and methods for preparing same.

  提供了通常为固体、有机溶剂可溶、热塑性、聚乙烯不饱和的纤维素聚氨酯聚合物。这些纤维素聚氨酯聚合物包括一个或多个纤维素醚或酯段，一个或多个至少具有两个碳原子且可被醚氧原子、酯基或亚苯基取代或中断的亚烷基，两个或多个二异氰酸酯残基，这些段、基和残基通过连接基连接在一起，但条件是所述亚烷基含有足够的乙烯不饱和度，使所述聚合物可以交联成溶剂不溶状态。纤维素聚氨酯聚合物可通过聚合反应混合物获得，该反应混合物包括：(a) 脂肪族或环脂族二元醇，其中含有足够的乙烯不饱和二元醇，使聚合产物可以交联成不溶于溶剂的状态；(b) 有机溶剂可溶性纤维素醚或酯，具有残留的未反应的纤维素羟基；(c) 有机二异氰酸酯。反应产物还可选择含有伯或仲脂肪族或芳香族二胺或二硫醇。此外，还提供了涂层组合物和成型制品以及制备方法。
• AQUEOUS EMULSION CONTAINING FINE PARTICLES OF CROSS-LINKED ALLYLIC COPOLYMER
  申请人：DAISO CO., LTD.

  公开号：EP0953601A1

  公开（公告）日：1999-11-03

  A crosslinked allyl copolymer fine particle-containing aqueous emulsion having a polymerization degree of diallyl phthalate of at least 85 % and an average particle diameter of 200 nm or less, which is obtained by emulsion-copolymerizing (a) 10 to 40 % by weight of diallyl phthalate, (b) 0.1 to 15 % by weight of a hydroxyl group-containing vinyl monomer and (c) the balance of an acrylate ester of a monohydric alcohol having 1 to 8 carbon atoms, has good film formation properties.

  一种交联烯丙基共聚物细颗粒含水乳液，其邻苯二甲酸二烯丙酯的聚合度至少为 85%，平均颗粒直径为 200 纳米或更小，它是通过乳液聚合 (a) 10% 至 40% （重量百分比）的邻苯二甲酸二烯丙酯、(b) 0.1% 至 15% （重量百分比）的含羟基的乙烯基单体和 (c) 其余的具有 1 至 8 个碳原子的一元醇的丙烯酸酯而得到的，具有良好的成膜性能。
• C-pivot lariat ethers bearing an electron-donating side arm as lithium cation selective extractants
  作者：Ryuhei Wakita、Masayuki Yonetani、Yohji Nakatsuji、Mitsuo Okahara

  DOI：10.1021/jo00296a036

  日期：1990.4