Lithium-Tetracyanchinodimethan | 39526-52-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Lithium-Tetracyanchinodimethan
• CAS: 39526-52-8；104363-93-1
• 化学式: C₁₂H₅N₄*Li
• 分子量: 212.14
• InChiKey: RMHUKAWRLCPAKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.21
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  95.16
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  Lithium-Tetracyanchinodimethan 、 1-(n-octyl)-4-methylpyridinium bromide 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 乙腈 为溶剂， 反应 14.0h， 以97%的产率得到
  参考文献：
  名称：

  Effecient synthesis and decomposition study of optically nonlinear adducts of tetracyanoquinodimethane

  摘要：

  Described are the synthetic conditions resulting in a significant improvement in both yield and reaction time of Z-beta-(1-substituted-4-pyridinium)-alpha-cyano-4-styryldicyanomethanide chromophores. A decomposition study of the zwitterionic chromophores in solution is also described. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)01054-2

文献信息

• Rectifying characteristics of Mg|(C16H33-Q3CNQ LB film)|Pt structures
  作者：Geoffrey J. Ashwell、J. Roy Sambles、A. Scott Martin、William G. Parker、Marek Szablewski

  DOI：10.1039/c39900001374

  日期：——

  The Mg|(LB monolayer)|Pt structures of Z-β-(1-hexadecyl-4-quinolinium)-α-cyano-4-styryldicyanomethanide (C16H33–Q3CNQ) show asymmetric current–voltage characteristics; the behaviour is attributed to the organic monolayer although whether it is due to the presence of the permanent dipole moment or molecular rectification is unclear.

  Z -β-（1-十六烷基-4-喹啉鎓）-α-氰基-4-苯乙烯基二氰基甲烷（C 16 H 33 –Q3CNQ）的Mg |（LB单层）| Pt结构表现出不对称的电流-电压特性。该行为归因于有机单分子层，尽管尚不清楚是由于永久偶极矩的存在还是由于分子整流。
• Solvent-directed lanthanide 7,7,8,8-tetracyano-p-quinodimethane complexes: Syntheses, structures, magnetic and electrochemical properties
  作者：Ju-Wen Zhang、Yan Wang、Peng-Fei Yan、Guang-Feng Hou、Guang-Ming Li

  DOI：10.1016/j.ica.2014.03.012

  日期：2014.5

  Reactions between trivalent lanthanide ions and the radical anion of 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) produce four mononuclear complexes [Ln(TCNQ)(2)(H2O)(7)](TCNQ)center dot 5H(2)O center dot EtOH [Ln = Nd (1), Sm (2), Eu (3) and Gd (4)] and three dinuclear complexes [Ln(2)(TCNQ)(2)(H2O)(15)](TCNQ)(4)center dot x(p-dioxane)center dot 7H(2)O [Ln = Ce (5, x = 2.5), Pr (6, x = 2.5) and Nd (7, x = 2)]. One of the coordinated TCNQ. radical anions is involved in pi-pi stacking interactions with the uncoordinated TCNQ. radical anions, and the other coordinated TCNQ. radical anion is not involved in such pi-pi interactions in 1-4. All the TCNQ. radical anions are involved in pi-pi interactions in 5-7. The effect of reaction solvent on the structures of 1-7 was revealed. The magnetic properties of 4 and the electrochemical properties of 1-7 were investigated. (C) 2014 Elsevier B. V. All rights reserved.
• Ehmann, Agnes; Gompper, Rudolf; Hartmann, Horst, Angewandte Chemie, 1994, vol. 106, # 5, p. 581 - 584
  作者：Ehmann, Agnes、Gompper, Rudolf、Hartmann, Horst、Mueller, Thomas J. J.、Polborn, Kurt、Schuetz, Reiner

  DOI：——

  日期：——