1'-O-monobutyrylsucrose | 111933-83-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1'-O-monobutyrylsucrose
• 英文别名: sucrose 1'-O-butyrate；1'-O-butyryl-sucrose；6-O-butanoyl-sucrose；1'-O-butyrylsucrose；butanoyl(-1)Fruf(b2-1a)Glc；[(2S,3S,4S,5R)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl butanoate
• CAS: 111933-83-6
• 化学式: C₁₆H₂₈O₁₂
• 分子量: 412.391
• InChiKey: NXWOTQDZISYBPL-KGHFDYDHSA-N

物化性质

• 沸点：
  678.0±55.0 °C(predicted)
• 密度：
  1.56±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2.8
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  196
• 氢给体数：
  7
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1'-O-monobutyrylsucrose 在 phosphate buffer 、 yeast α-glucosidase 作用下， 反应 48.0h， 生成 1-O-butanoyl-D-fructose
  参考文献：
  名称：

  Carrea, Giacomo; Riva, Sergio; Secundo, Francesco, Journal of the Chemical Society. Perkin transactions I, 1989, p. 1057 - 1061

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2,2-三氯丁酸乙酯 、 蔗糖 以 N,N-二甲基甲酰胺 为溶剂， 反应 60.0h， 以57%的产率得到1'-O-monobutyrylsucrose
  参考文献：
  名称：

  Protease-catalyzed regioselective esterification of sugars and related compounds in anhydrous dimethylformamide

  摘要：

  DOI：

  10.1021/ja00210a045

文献信息

• Effect of fatty acid chain length on initial reaction rates and regioselectivity of lipase-catalysed esterification of disaccharides
  作者：Ninfa R Pedersen、Reinhard Wimmer、Jeppe Emmersen、Peter Degn、Lars H Pedersen

  DOI：10.1016/s0008-6215(02)00112-x

  日期：2002.7

  t-BuOH and pyridine (v/v) the effect of fatty acid chain length (C-4-C-12) on C. antarctica lipase B (Novozym 435, EC 3.1.1.3) catalysed esterification was studied. alpha and beta maltose 6'-O-acyl esters in an anomeric molar ratio of 1.0:1.1 were synthesised independently of the chain length, but the initial specific reaction rate increased with decreasing chain length of the acyl donor. The product

  在9:11 t-BuOH和吡啶（v / v）的反应介质混合物中，脂肪酸链长（C-4-C-12）对南极洲C.脂肪酶B的影响（Novozym 435，EC 3.1.1.3）研究了催化酯化反应。异头摩尔比为1.0：1.1的α和β麦芽糖6'-O-酰基酯的合成与链长无关，但初始比反应速率随酰基供体链长的减小而增加。反应24小时后，产物产率遵循相同的趋势，月桂酸酯产率为1.1％（mol / mol），丁酯产率为27.6％（mol / mol）。以蔗糖为酰基受体时，链长为C-4和C-10的脂肪酸形成6'-O-酰基和6-O-酰基单酯，而6'，6-O-酰基二酯仅与丁酸（C-4：0）作为酰基供体。6' -O-酰基和6-O-酰基单酯和丁酸的6'，6-O-酰基二酯的摩尔比为1.0：0.5：0.2，癸酸（C-10：0）生成6 -O-酰基和6-O-酰基单酯以1.0∶0.3的比例形成。在酰基供体的链长度最短的情况下，可
• Low-dusting investment composition material
  申请人：Bettman Marijke

  公开号：US20060086286A1

  公开（公告）日：2006-04-27

  The invention relates to a method for manufacturing a heat-resistant mold wherein heat-resistant investment material is inserted in a wax model manufactured in a conventional manner. The invention further relates to a low-dusting investment material, which low-dusting material is in particular heat-resistant. The investment material is applicable in dentistry, particularly for manufacturing molds.

  本发明涉及一种制造耐热模具的方法，其中将耐热投资材料插入以传统方式制造的蜡模中。本发明还涉及一种低除尘投资材料，这种低除尘材料尤其具有耐热性。这种投资材料适用于牙科，特别是用于制造模具。
• Proteinase N-catalysed regioselective esterification of sucrose and other mono- and disaccharides
  作者：Pierre Potier、Alain Bouchu、Juliette Gagnaire、Yves Queneau

  DOI：10.1016/s0957-4166(01)00424-4

  日期：2001.9

  Crude Proteinase N was used as catalyst for the synthesis of carbohydrate (in particular sucrose) esters by transesterification of activated esters in organic solvents. Polymerisable or amphiphilic sucrose esters (methacrylates and laurates) were obtained regioselectively in good yields. The influence of the reaction parameters (temperature, pH, solvent, chain length, solid support) on the reaction rate, yield and selectivity was studied. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Proteinase N-catalysed transesterifications in DMSO–water and DMF–water: preparation of sucrose monomethacrylate
  作者：Pierre Potier、Alain Bouchu、Gérard Descotes、Yves Queneau

  DOI：10.1016/s0040-4039(00)00452-4

  日期：2000.5

  The selective acylation of sucrose was catalysed by proteinase N (from Bacillus subtilis) in DMF suspensions, providing 1'-monoesters, and notably, methacryloyl esters. Presence of water up to 7% (vol.) led to faster reactions. Alternatively, a slurry of the enzyme with a minimum volume of DMSO could also be used, despite its ability to denature enzymes. (C) 2000 Elsevier Science Ltd. All rights reserved.
• NON-DUSTING AND FAST-WETTING IMPRESSION MATERIAL AND METHOD OF PREPARING SAME
  申请人：DENTSPLY INTERNATIONAL, INC.

  公开号：EP0058203B2

  公开（公告）日：1994-08-10