[1-(Prop-2-enoxymethyl)cyclohexyl]methanol | 1276693-09-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [1-(Prop-2-enoxymethyl)cyclohexyl]methanol
• CAS: 1276693-09-4
• 化学式: C₁₁H₂₀O₂
• 分子量: 184.279
• InChiKey: URAPUYSDQSSQGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [1-(Prop-2-enoxymethyl)cyclohexyl]methanol 在 正丁基锂 、 pyridinium chlorochromate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 1-(1-(allyloxymethyl)cyclohexyl)-1-(4-(trifluoromethyl)phenyl)prop-2-yn-1-ol
  参考文献：
  名称：

  铂催化的5-烷氧基戊-1-yn-3-ol衍生物的1,2-碳烷氧基化反应中的不同化学选择性

  摘要：

  报道了炔烃的两种不同的Pt催化的碳烷氧基化。5-烷氧基戊-1-yn-3-ol衍生物5的环异构化产生2，6-二氧杂双环[3.1.0]己烷6。推测该机理涉及羟基触发的[3.3]-σ烯丙基重排。由于相同的催化作用可扩展至它们的叔醇类似物7，因此通过[3.3]烯丙基重排获得了独特的二氢呋喃醇8，该羟基不受羟基的辅助。

  DOI：

  10.1021/ol2002144
• 作为产物：
  描述：

  [1-(羟基甲基)环己基]甲醇 、 3-氯丙烯 在 sodium hydroxide 作用下， 反应 4.5h， 以80.4%的产率得到[1-(Prop-2-enoxymethyl)cyclohexyl]methanol
  参考文献：
  名称：

  モノグリシジルエーテル化合物、及びモノアリルエーテル化合物

  摘要：

  提供作为环氧树脂稀释剂有用的单甘油醚化合物。此外，提供作为单甘油醚化合物合成中间体有用的化合物，还有作为活性能线固化型或热固化型油墨、涂料和涂层剂等原料有用的单丙烯醚化合物。所述化合物由以下通式（1）表示。（在通式（1）中，R1至R3分别独立表示氢原子或碳数为1至3的烃基，X1和X2分别独立表示具有1至3个支链的烃基，Y表示丙烯基或甘油基。n和m分别独立表示0至10。）【选择图】无

  公开号：

  JP2015209410A

文献信息

• Fumarate derivative, method for producing the same
  申请人：——

  公开号：US20030060563A1

  公开（公告）日：2003-03-27

  This invention is to provide a polymerizable composition having excellent curability and surface hardness, and a cured product thereof. A novel fumarate derivative having two or more fumarate groups within one molecule and ensuring high copolymerizability with the terminal alkenyloxy group, a method for producing the derivative, a polymerizable composition containing the derivative, and a cured product thereof are provided.

  本发明旨在提供一种具有优异固化性和表面硬度的可聚合组合物及其固化产物。提供了一种新型富马酸酯衍生物，其分子内具有两个或更多的富马酸基团，并确保与末端烯氧基团高度共聚性，一种制备该衍生物的方法，含有该衍生物的可聚合组合物以及其固化产物。
• Fluorine-containing copolymer useful as paint vehicle
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP0544233A1

  公开（公告）日：1993-06-02

  The invention provides a copolymer suitable for use as a paint vehicle, which includes, as essential components, 10 to 80 mol% of a fluoroolefin, 0 to 80 mol% of a hydroxyl-containing polymerizable unsaturated monomer, 3 to 80 mol % of an allyloxy group-containing compound, and 2 to 70 mol% of an organosilicon compound having a polymerizable unsaturated bond and a group hydrolyzable to a hydroxyl. The copolymer is soluble in various organic solvents and sufficiently low in molecular weight so as to substantially reduce the amount of solvent. The cured copolymer is excellent in weatherability, water resistance, chemical resistance and abrasion resistance.

  本发明提供了一种适合用作涂料载体的共聚物，其基本成分包括 10 至 80 摩尔%的氟烯烃、0 至 80 摩尔%的含羟基的可聚合不饱和单体、3 至 80 摩尔%的含烯丙氧基化合物，以及 2 至 70 摩尔%的有机硅化合物，该有机硅化合物具有可聚合的不饱和键和可水解为羟基的基团。该共聚物可溶于各种有机溶剂，且分子量足够低，可大大减少溶剂用量。固化后的共聚物具有优异的耐候性、耐水性、耐化学性和耐磨性。
• FLUORINE COATING COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2075294A1

  公开（公告）日：2009-07-01

  Disclosed is a two-pack fluorine coating composition which comprises a combination of: a base component comprising a fluorinated copolymer having a hydroxyl group which can be dissolved in a low-polar weak solvent even at a low temperature and; a curing agent comprising a polyisocyanate compound. Specifically disclosed is a fluorine coating composition comprising:; (A) a base component which comprises a fluorinated copolymer of a fluoroolefin and a monomer having a double bond copolymerizable with the fluoroolefin and which has a fluorine content of 10 mass% or more, wherein 5 to 30 mol% of the monomer has a hydroxyl group and 10 to 50 mol% of the monomer has a branched alkyl group having 3 or more carbon atoms; and (B) a curing agent comprising a polyisocyanate compound which is produced by the reaction between at least one diisocyanate selected from an aliphatic diisocyanate and a alicyclic diisocyanate and a monoalcohol having 1 to 20 carbon atoms and which has an [(allophanate group)/(isocyanurate group)] ratio of 90/10 to 81/19 by mole.

  本发明公开了一种双组分氟涂料组合物，该组合物由以下成分组合而成：基础成分，包括具有羟基的氟化共聚物，该共聚物在低温下也能溶解在低极性弱溶剂中；固化剂，包括多异氰酸酯化合物。具体公开了一种含氟涂料组合物，包括(A) 基础组分，包括氟烯烃和具有可与氟烯烃共聚的双键的单体的氟化共聚物，其氟含量为 10 质量％或以上，其中 5 至 30 摩尔％的单体具有羟基，10 至 50 摩尔％的单体具有 3 个或更多碳原子的支链烷基；(B) 包含多异氰酸酯化合物的固化剂，该化合物由至少一种选自脂肪族二异氰酸酯和脂环族二异氰酸酯的二异氰酸酯与具有 1 至 20 个碳原子的一元醇反应生成，其[（异丙酸酯基）/（异氰尿酸酯基）]比率为 90/10 至 81/19（以摩尔计）。
• PHOTOCURABLE FLUORINATED POLYMER COMPOSITION
  申请人：Asahi Glass Company, Limited

  公开号：EP2468816A1

  公开（公告）日：2012-06-27

  To provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance. According to the photocurable fluorinated polymer composition comprising a fluorinated polymer (A) containing polymerized units derived from a fluoroolefin and polymerized units derived from an unsaturated monomer having an oxetanyl group or a substituted oxetanyl group, and a photoreaction initiator (B), of the present invention, it is possible to provide a photocurable fluorinated polymer composition which has a high curing rate, shows little shrinkage before and after photocuring and requires no post treatment such as heat treatment after photocuring and whereby it is possible to obtain a cured resin excellent in heat resistance and weather resistance.

  提供一种光固化型含氟聚合物组合物，该组合物固化速率高，在光固化前后收缩率小，光固化后无需进行热处理等后处理，可获得耐热性和耐候性优异的固化树脂。本发明的光固化含氟聚合物组合物由含氟聚合物（A）和光引发剂（B）组成，前者含有由氟烯烃衍生的聚合单元，后者含有由具有氧杂环丁烷基团或取代氧杂环丁烷基团的不饱和单体衍生的聚合单元、可以提供一种光固化型含氟聚合物组合物，该组合物固化速率高，在光固化前后收缩率小，光固化后无需进行热处理等后处理，从而可以获得耐热性和耐候性极佳的固化树脂。
• PROCESS FOR PRODUCTION OF FLUOROPOLYMER THAT CONTAINS HYDROLYZABLE SILYL GROUPS, AND COMPOSITION CONTAINING FLUOROPOLYMER THAT CONTAINS HYDROLYZABLE SILYL GROUPS
  申请人：Asahi Glass Company, Limited

  公开号：EP2524931A1

  公开（公告）日：2012-11-21

  The present invention has an object to provide a process for producing a hydrolyzable silyl group-containing fluoropolymer which is excellent in storage stability and has a sufficient pot life. At the time of producing a hydrolyzable silyl group-containing fluoropolymer by reacting an isocyanate group of an isocyanate group-containing alkoxysilane to a hydroxy group of a hydroxy group-containing fluoropolymer, the reaction is carried out in the presence a compound containing a specific metal atom at a certain concentration.

  本发明的目的是提供一种生产可水解含硅烷基含氟聚合物的工艺，该聚合物具有优异的储存稳定性和足够的罐装寿命。在通过将含异氰酸酯基团的烷氧基硅烷的异氰酸酯基团与含羟基基团的含氟聚合物的羟基基团反应来生产可水解的含硅基的含氟聚合物时，该反应是在含有一定浓度的特定金属原子的化合物存在下进行的。