1,4-bis(trichlorostannyl)pentane | 351387-98-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: 1,4-bis(trichlorostannyl)pentane
• 英文别名: 1,5-bis(trichlorostannyl)pentane；Stannane, 1,5-pentanediylbis[trichloro-；trichloro(5-trichlorostannylpentyl)stannane
• CAS: 351387-98-9
• 化学式: C₅H₁₀Cl₆Sn₂
• 分子量: 520.272
• InChiKey: MJDVFRREUJKLKP-UHFFFAOYSA-H

物化性质

• 沸点：
  405.9±28.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.47
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,4-bis(trichlorostannyl)pentane 、 苯乙炔 在 n-butyl lithium 作用下， 以 甲苯 为溶剂， 以79%的产率得到1,4-bis(tris(phenylethynyl)stannyl)pentane
  参考文献：
  名称：

  A General Route to Alkylene-, Arylene-, or Benzylene-Bridged Ditin Hexachlorides and Hexaalkynides

  摘要：

  The preparation of alkylene-, arylene-, or benzylene-bridged ditin hexachlorides in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride is described. The tetragonal geometry of the tin atom of 1,4-bis(trichlorostannyl)-butane in the solid state indicates that no intramolecular or intermolecular interaction involving either end of the molecule exists in this compound. The ditin hexachlorides were successfully transformed in the corresponding hexaalkynides, precursors of hybrid materials.

  DOI：

  10.1021/om0202468
• 作为产物：
  描述：

  1,5-二溴戊烷 在 Mg 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 1,4-bis(trichlorostannyl)pentane
  参考文献：
  名称：

  A General Route to Alkylene-, Arylene-, or Benzylene-Bridged Ditin Hexachlorides and Hexaalkynides

  摘要：

  The preparation of alkylene-, arylene-, or benzylene-bridged ditin hexachlorides in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride is described. The tetragonal geometry of the tin atom of 1,4-bis(trichlorostannyl)-butane in the solid state indicates that no intramolecular or intermolecular interaction involving either end of the molecule exists in this compound. The ditin hexachlorides were successfully transformed in the corresponding hexaalkynides, precursors of hybrid materials.

  DOI：

  10.1021/om0202468

文献信息

• α,ω-Bis(trichlorostannyl)alkanes:  Unravelling the Hydrolysis Pathway to Organotin-oxo Oligomers
  作者：Bernhard Zobel、Andrew Duthie、Dainis Dakternieks、Edward R. T. Tiekink

  DOI：10.1021/om010202j

  日期：2001.6.1

  New alpha,omega -bis(trichlorostannyl)alkanes, Cl3Sn(CH2)(n)SnCl3 [n = 3-5, 8], have been synthesized via tin-phenyl bond cleavage reactions on alpha,omega -bis(triphenylstannyl)alkanes, Ph3Sn(CH2)(n)SnPh3 [n = 3-5, 8], using either SnCl4 or concentrated hydrochloric acid. Some key missing links, (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6), in the hydrolysis pathway of organotin trichlorides were identified. Crystal structures of the nonassociated di-tin compounds (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6, isolated as the 18-crown-6 cocrystal acetonitrile solvate) as well as the polymeric hydrolysis product [H2O(OH)Cl2Sn(CH2)(3)SnCl2(OH)H2O . 2H(2)O](n) (7 . 2H(2)O) are reported.
• A General Route to Alkylene-, Arylene-, or Benzylene-Bridged Ditin Hexachlorides and Hexaalkynides
  作者：Bernard Jousseaume、Hocine Riague、Thierry Toupance、Mohamed Lahcini、Philip Mountford、Ben R. Tyrrell

  DOI：10.1021/om0202468

  日期：2002.10.1

  The preparation of alkylene-, arylene-, or benzylene-bridged ditin hexachlorides in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride is described. The tetragonal geometry of the tin atom of 1,4-bis(trichlorostannyl)-butane in the solid state indicates that no intramolecular or intermolecular interaction involving either end of the molecule exists in this compound. The ditin hexachlorides were successfully transformed in the corresponding hexaalkynides, precursors of hybrid materials.