RuH2(P(OMe)3)4 | 38784-31-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: RuH2(P(OMe)3)4
• 英文别名: ruthenium dihydride;trimethyl phosphite
• CAS: 38784-31-5
• 化学式: C₁₂H₃₈O₁₂P₄Ru
• 分子量: 599.392
• InChiKey: IDXRKAJHVOBPSN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.07
• 重原子数：
  29.0
• 可旋转键数：
  16.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  110.76
• 氢给体数：
  0.0
• 氢受体数：
  12.0

反应信息

• 作为反应物：
  描述：

  RuH2(P(OMe)3)4 、 sulfur 以 苯 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Pentasulfide S₅^2- as the First Tridentate Chelating Ligand in Ru(P(OE)₃)₃S₅(E = Me and Et)

  摘要：

  Room temperature stirring of H2Ru(P(OE)(3))(4) (E = Me and Et) and elemental sulfur in benzene afforded the optically active compounds Ru(P(OMe)(3))(3)S-5 (1) and Ru(P(OEt)(3))(3)S-5 (2). Compounds I-and 2 are crystallized in the trigonal space group P3(1) with a = 14.231(10) Angstrom, c = 10.24(1) Angstrom, V = 1794(2) Angstrom(3), and Z = 3, and orthorhombic space group P2(1)2(1)2(1) With a 15.393(5) Angstrom, b = 18.126(6) Angstrom, c = 12.421(4) Angstrom, V = 3465(1) Angstrom(3), and Z = 4, respectively. Solutions of 1 and 2 did not show any optical activity since the bulk materials are racemic mixtures. The X-ray analyses also reveal that in both compounds polysulfide S-5(2-) ion acts as a novel tridentate ligand, resulting in an asymmetric bicyclic RuS5 unit having three- and five-membered rings around the ruthenium atom. Fragmentation of the S-5(2-) ring to S2- ion was observed in the presence of sulfur-abstracting reagents such as PR3 (R = Ph, OMe, and Oft) and also to S-2(2-) ion when the compounds were reacted with RuCl2(P(OE)(3))(4) (E = Me and Et).

  DOI：

  10.1021/ic990764j
• 作为产物：
  描述：

  (η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 三甲氧基磷 在 H₂ 作用下， 以 四氢呋喃 为溶剂， 生成 RuH2(P(OMe)3)4
  参考文献：
  名称：

  New synthetic route to organophosphorous ruthenium dihydride complexes. X-ray crystal structure of cis-H2Ru(Ph2PCH2CH2PPh2)2·C6H6

  摘要：

  DOI：

  10.1016/s0020-1693(00)95493-8

文献信息

• Synthesis and Characterization of Triazenide and Triazene Complexes of Ruthenium and Osmium
  作者：Gabriele Albertin、Stefano Antoniutti、Marco Bedin、Jesús Castro、Soledad Garcia-Fontán

  DOI：10.1021/ic052063u

  日期：2006.5.1

  triazene complexes prepared from the 1,3-Ph15N=N15N(H)Ph ligand. Osmium dihydrogen [OsH(eta2-H2)P4]BPh4 complexes [P = P(OEt)3, PPh(OEt)2] react with 1,3-ArN=NN(H)Ar triazene to give the hydride-diazene [OsH(ArN=NH)P4]BPh4 derivatives. The X-ray crystal structure determination of the [OsH(PhN=NH)PPh(OEt)2}4]BPh4 complex is reported. A reaction path to explain the formation of the diazene complexes is also

  Triazenide [M（eta2-1,3-ArNNNAr）P4] BPh4 [M = Ru，Os; Ar = Ph，对甲苯基; P = P（OMe）3，P（OEt）3，PPh（OEt）2]配合物的制备是通过使三氟甲磺酸酯[M（kappa2-OTf）P4] OTf物种首先与1,3-ArN = NN（H ）Ar三氮烯，然后加入过量的三乙胺。另外，三氢化钌[Ru（eta2-1,3-ArNNNAr）P4] BPh4衍生物是通过使氢化物[RuH（eta2-H2）P4] +和RuH（kappa1-OTf）P4化合物与1,3-二芳基三氮烯反应而获得的。通过[Ru（eta2-1,3-PhNNNPh）P（OEt）3} 4] BPh4衍生物的光谱学和X射线晶体学表征该配合物。氢化三氮烯[OsH（eta1-1,3-ArN = NN（H）Ar）P4] BPh4 [P = P（OEt）3，PPh（OEt）2;
• Preparation of mono- and bis-(hydrazine) complexes of ruthenium(II) †
  作者：Gabriele Albertin、Stefano Antoniutti、Alessia Bacchi、Emilio Bordignon、Piero Matteo Dolcetti

  DOI：10.1039/a702712e

  日期：——

  Hydrazine complexes [RuH(R1NHNH2)L4]BPh4 1–3, [Ru(R1NHNH2)2L4][BPh4]2 4–6 [R1 = H, Me, Ph, 4-MeC6H4 or 4-O2NC6H4; L = P(OEt)3, PPh(OEt)2 or P(OMe)3] were prepared by allowing the hydride species [RuH2L4] to react, first with triflic acid (CF3SO3H) and then with an excess of the appropriate hydrazine. The derivatives [RuH(Me2NNH2)P(OEt)3}4]BPh4 1f, [Ru(η1-OSO2CF3)(Me2NNH2)P(OEt)3}4]BPh4 9 and [Ru(η2-P

  肼复合物[期RuH（R 1 NHNH 2）L- 4 ] BPH 4 1-3的[Ru（R 1 NHNH 2）2大号4 ] [BPH 4 ] 2 4-6 - [R 1  = H，Me中的pH值，4 -MeC 6 H 4或4-O 2 NC 6 H 4；L = P（OEt）3，PPh（OEt）2或P（OMe）3 ]通过首先使氢化物[RuH 2 L 4 ]与三氟甲磺酸（CF 3 SO 3）反应来制备H），然后加入过量的适当肼。衍生物[期RuH（ME 2 NNH 2）P（OET）3 } 4 ] BPH 4 1F，的[Ru（η 1 -OSO 2 CF 3）（ME 2 NNH 2）P（OET）3 } 4 ] BPH 4 9和的[Ru（η 2 -Ph-CONHNH 2）L- 4 ] [BPH 4 ] 2 7,8- [L = P（OET）3或PPH（OET）2 ]也被获得。通过红外光谱和红外光谱确定化合物溶液的配方和几何形状。1
• Amendola, Paola; Antoniutti, Stefano; Albertin, Gabriele, Inorganic Chemistry, 1990, vol. 29, # 2, p. 318 - 324
  作者：Amendola, Paola、Antoniutti, Stefano、Albertin, Gabriele、Bordignon, Emilio

  DOI：——

  日期：——
• Albertin, Gabriele; Antoniutti, Stefano; Bacchi, Alessia, Inorganic Chemistry, 1996, vol. 35, # 21, p. 6245 - 6253
  作者：Albertin, Gabriele、Antoniutti, Stefano、Bacchi, Alessia、Bordignon, Emilio、Pelizzi, Giancarlo、Ugo, Paolo

  DOI：——

  日期：——
• Alexander, Bruce D.; Boyle, Paul D.; Johnson, Brian J., Inorganic Chemistry, 1987, vol. 26, # 15, p. 2547 - 2551
  作者：Alexander, Bruce D.、Boyle, Paul D.、Johnson, Brian J.、Casalnuovo, Joseph A.、Johnson, Steven M.、Mueting, Ann M.、Pignolet, Louis H.

  DOI：——

  日期：——