5-benzylthio-2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-2H-benzotriazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 5-benzylthio-2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-2H-benzotriazole
• 英文别名: 2-(5-Benzylsulfanylbenzotriazol-2-yl)-6-tert-butyl-4-methylphenol
• 化学式: C₂₄H₂₅N₃OS
• 分子量: 403.548
• InChiKey: AWKFDQSUGHKZHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  76.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苄硫醇 、 紫外线吸收剂 UV-326 在 potassium carbonate 、 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 9.0h， 生成 5-benzylthio-2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-2H-benzotriazole
  参考文献：
  名称：

  PLASTIC LENS

  摘要：

  提供一种塑料镜片，可以高效吸收波长为400至420纳米的光线，但在吸收波长约为420纳米或更长的光线时减少吸收，对有害光线的影响较小，抑制黄色变色，从而具有出色的外观，随着时间的推移抑制黄色变色，并具有出色的耐热性、耐光性以及光学性能，特别是出色的阿贝数。该塑料镜片的特征在于含有以下式(I)所代表的紫外线吸收剂：（在公式中，R1至R8分别表示氢原子等单价基团，R9表示由以下式(i)所代表的含硫单价基团：（在公式中，R10表示含有1至20个碳原子的二价碳氢基团或类似基团；R11表示含有1至20个碳原子的二价碳氢基团或类似基团；R12表示含有1至20个碳原子的单价碳氢基团；R10、R11和R12的碳原子总数不超过30；m表示0或1的整数；n表示0至3的整数）），以及树脂材料。

  公开号：

  US20180134872A1

文献信息

• ADDITIVE FOR IMPARTING ULTRAVIOLET ABSORBENCY AND/OR HIGH REFRACTIVE INDEX TO MATRIX, AND RESIN MEMBER USING SAME
  申请人：Miyoshi Oil & Fat Co., Ltd.

  公开号：US20170217937A1

  公开（公告）日：2017-08-03

  Provided is an additive for imparting ultraviolet absorbency, or an additive for imparting a high refractive index, which has satisfactory compatibility with a resin serving as a matrix and can maintain high transparency even if added in high concentrations. Also provided is an additive with which the function of imparting both ultraviolet absorbency and a high refractive index can be realized by means of one kind of additive. This additive is represented by the following Formula (I): wherein at least one of R 1a to R 9a is a monovalent sulfur-containing group represented by the following Formula (i-1) or Formula (i-2): wherein R 10a to R 12a each represent a divalent hydrocarbon group or the like; and R 13a represents a monovalent hydrocarbon group or the like.

  提供了一种用于赋予紫外线吸收性能的添加剂，或者用于赋予高折射率的添加剂，该添加剂与作为基体的树脂具有良好的相容性，并且即使在高浓度下添加也能保持高透明度。还提供了一种通过一种添加剂实现赋予紫外线吸收性能和高折射率功能的添加剂。该添加剂由以下式（I）表示：其中R1至R9中至少有一个是由以下式（i-1）或式（i-2）表示的一价含硫基团：其中R10至R12分别表示二价碳氢基团或类似物；R13表示一价碳氢基团或类似物。
• ADDITIVE FOR IMPARTING ULTRAVIOLET ABSORPTIVITY AND/OR HIGH REFRACTIVE INDEX TO MATRIX, AND RESIN MEMBER USING SAME
  申请人：Miyoshi Oil & Fat Co., Ltd.

  公开号：EP3178898A1

  公开（公告）日：2017-06-14

  Provided is an additive for imparting ultraviolet absorbency, or an additive for imparting a high refractive index, which has satisfactory compatibility with a resin serving as a matrix and can maintain high transparency even if added in high concentrations. Also provided is an additive with which the function of imparting both ultraviolet absorbency and a high refractive index can be realized by means of one kind of additive. This additive is represented by the following Formula (I): wherein at least one of R1a to R9a is a monovalent sulfur-containing group represented by the following Formula (i-1) or Formula (i-2): wherein R10a to R12a each represent a divalent hydrocarbon group or the like; and R13a represents a monovalent hydrocarbon group or the like.

  本发明提供了一种用于赋予紫外线吸收性的添加剂或用于赋予高折射率的添加剂，它与作为基体的树脂具有令人满意的相容性，即使添加浓度较高，也能保持高透明度。我们还提供了一种添加剂，它可以通过一种添加剂同时实现紫外线吸收能力和高折射率的功能。这种添加剂由下式（I）表示： 其中 R1a 至 R9a 中至少有一个是由下式（i-1）或下式（i-2）表示的单价含硫基团： 其中 R10a 至 R12a 分别代表二价烃基或类似物；R13a 代表一价烃基或类似物。
• LIGHT-RESISTANT, HEAT-RESISTANT, AND DURABLE UV ABSORBENT
  申请人：Miyoshi Oil & Fat Co., Ltd.

  公开号：EP3904443A1

  公开（公告）日：2021-11-03

  Provided is an ultraviolet absorber capable of efficiently absorbing harmful lights in a wavelength region of 380 to 400 nm; and suppressing the absorption of lights having a wavelength of not shorter than 400 nm, which constitutes the cause of yellowing at early stages. The ultraviolet absorber can thus be used to produce a member superior in appearance as being less affected by harmful lights, and has an excellent light resistance, heat resistance and durability accordingly. The highly light-resistant ultraviolet absorber of the present invention is comprised of a 2-phenylbenzotriazole derivative that contains a thioaryl ring group or the like and is represented by, for example, the following formula (1):         PhBzT1a-S-X1a-(R1a)     (1) wherein PhBzT1a represents a substituted or unsubstituted 2-phenylbenzotriazole skeleton bonded to a thioaryl ring group (-S-X1a-...), X1a represents a residue of a phenyl ring or the like, each of 1R1as independently represents, for example, a hydrocarbon group having 1 to 18 carbon atoms, 1 represents an integer of 0 to 5.

  本发明提供了一种紫外线吸收剂，它能够有效吸收波长在 380 至 400 纳米之间的有害光，并抑制对波长不短于 400 纳米的光的吸收，而这些光是导致早期黄变的原因。因此，紫外线吸收剂可用于生产受有害光影响较小的外观优异的构件，并相应地具有出色的耐光性、耐热性和耐用性。本发明的高耐光性紫外线吸收剂由 2-苯基苯并三唑衍生物组成，该衍生物含有硫代芳基环基或类似基团，例如由下式（1）表示： PhBzT1a-S-X1a-(R1a) (1) 其中 PhBzT1a 代表与硫代芳基环基（-S-X1a-......）键合的取代或未取代的 2-苯基苯并三唑骨架，X1a 代表苯基环或类似物的残基，1R1as 各自独立地代表例如具有 1 至 18 个碳原子的烃基，1 代表 0 至 5 的整数。
• RESIN MOLDING MATERIAL, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING RESIN MEMBER OR THE LIKE
  申请人：Miyoshi Oil & Fat Co., Ltd.

  公开号：EP3932976A1

  公开（公告）日：2022-01-05

  Provided are a resin molding material, a method for producing same, and a method for producing resin member or the like, said resin molding material being a resin molding material which is capable of reducing a loss of ultraviolet absorber, resulting in less contamination in facilities, minimizing the impact of harmful lights by efficiently absorbing harmful lights in the wavelength region of 380 to 400 nm (to 420 nm), and suppressing the absorption of lights having a wavelength of not shorter than 400 nm (420 nm) which is a primary cause of early-stage yellowing to thereby produce a member having a superior appearance since the ultraviolet absorber is less prone to be sublimed during hot-melt compounding (first/second processing) that requires a high-temperature processing, or during other heat processing. The resin molding material is used in heat processing and comprises a resin and a 2-phenylbenzotriazole derivative that contains a thioether-containing group.

  本发明提供了一种树脂成型材料、其生产方法以及树脂构件或类似材料的生产方法，所述树脂成型材料是一种树脂成型材料，能够减少紫外线吸收剂的损失，从而减少对设施的污染，通过有效吸收波长为 380 至 400 nm（至 420 nm）的有害光，将有害光的影响降至最低、由于紫外线吸收剂在需要高温处理的热熔复合（第一/第二处理）或其他热处理过程中不易升华，因此可抑制对波长不短于 400 纳米（420 纳米）的光的吸收，从而生产出具有出色外观的构件。热加工中使用的树脂成型材料包括树脂和含有硫醚基团的 2-苯基苯并三唑衍生物。
• Additive for imparting ultraviolet absorbency and/or high refractive index to matrix, and resin member using same
  申请人：Miyoshi Oil & Fat Co., Ltd.

  公开号：US10316024B2

  公开（公告）日：2019-06-11

  Provided is an additive for imparting ultraviolet absorbency, or an additive for imparting a high refractive index, which has satisfactory compatibility with a resin serving as a matrix and can maintain high transparency even if added in high concentrations. Also provided is an additive with which the function of imparting both ultraviolet absorbency and a high refractive index can be realized by means of one kind of additive. This additive is represented by the following Formula (I): wherein at least one of R1a to R9a is a monovalent sulfur-containing group represented by the following Formula (i-1) or Formula (i-2): wherein R10a to R12a each represent a divalent hydrocarbon group or the like; and R13a represents a monovalent hydrocarbon group or the like.

  本发明提供了一种用于赋予紫外线吸收性的添加剂或用于赋予高折射率的添加剂，它与作为基体的树脂具有令人满意的相容性，即使添加浓度较高，也能保持高透明度。我们还提供了一种添加剂，它可以通过一种添加剂同时实现紫外线吸收能力和高折射率的功能。这种添加剂由下式（I）表示： 其中 R1a 至 R9a 中至少有一个是由下式（i-1）或式（i-2）代表的一价含硫基团： 其中 R10a 至 R12a 分别代表二价烃基或类似物；R13a 代表一价烃基或类似物。