4-Hydroxybutyl Adipate | 86923-79-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-Hydroxybutyl Adipate
• 英文别名: Hexanedioic acid, ester with 1,4-butanediol；6-(4-hydroxybutoxy)-6-oxohexanoic acid
• CAS: 86923-79-7
• 化学式: C₁₀H₁₈O₅
• 分子量: 218.25
• InChiKey: ZSYUYBMMNNGZIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  6-羟基己酸甲酯 在 吡啶 、 咪唑 、 chromium(VI) oxide 、 草酰氯 、 硫酸 、 四丁基氟化铵 、 sodium hydride 、 N,N-二甲基甲酰胺 、 lithium iodide 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 、 丙酮 为溶剂， 反应 130.67h， 生成 4-Hydroxybutyl Adipate
  参考文献：
  名称：

  Binns, Falmai; Roberts, Stanley M.; Taylor, Alan, Journal of the Chemical Society. Perkin transactions I, 1993, # 8, p. 899 - 904

  摘要：

  DOI：

文献信息

• NOVEL POLYMERIC PHOTOINITIATORS AND PHOTOINITIATOR MONOMERS
  申请人：Coloplast A/S

  公开号：US20150148441A1

  公开（公告）日：2015-05-28

  The present invention provides polymeric photoinitiators being co-polymers of photoinitiator monomers and at least one further monomer, as well as photoinitiator monomers being intermediates in the preparation of such polymeric photoinitiators. Additionally, there is provided polyacrylate obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of such polymeric photoinitiators. In the photoinitiator monomers and polymeric photoinitiators, a photoinitiator moiety, a hydrolytic stable linker and two polymerisable functional groups are incorporated into the photoinitiator structure.

  本发明提供了聚合物光引发剂，其为光引发剂单体与至少一种进一步单体的共聚物，以及作为这种聚合物光引发剂制备过程中的中间体的光引发剂单体。此外，还提供了通过在存在这种聚合物光引发剂的情况下，通过至少一种丙烯酸酯单体（Ac）的自由基聚合得到的聚丙烯酸酯。在光引发剂单体和聚合物光引发剂中，光引发剂基团、水解稳定连接物和两个可聚合功能基团被结合到光引发剂结构中。
• NOVEL POLYMERIC PHOTOINITIATORS
  申请人：Madsen Niels Joergen

  公开号：US20130289155A1

  公开（公告）日：2013-10-31

  A polymeric photoinitiator, most suitably a polyurethane photoinitiator, is obtained by step-growth co-polymerization of at least one monomer (A) with at least one monomer (B). Monomer (A) includes a photoinitiator moiety, while monomer (B) is a monomer reactive with monomer (A) to form a polymer. A method produces the polymeric photoinitiator, a method cross-links the polymeric photoinitiator, and the polymeric photoinitiator is used as a photoinitiator of radical polymerization.

  一种聚合物光引发剂，最适宜的是聚氨酯光引发剂，通过至少一种单体（A）与至少一种单体（B）的步骤生长共聚反应获得。单体（A）包括光引发剂基团，而单体（B）是与单体（A）反应形成聚合物的单体。一种方法用于生产聚合物光引发剂，一种方法用于交联聚合物光引发剂，并且聚合物光引发剂用作自由基聚合的光引发剂。
• ROUTES TO POLYACRYLATES
  申请人：Madsen Niels Jørgen

  公开号：US20130296454A1

  公开（公告）日：2013-11-07

  A polyacrylate is obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of a polymeric photoinitiator. The polymeric photoinitiator is a co-polymer of at least one photoinitiator monomer (A) with at least one monomer (B), and optional additional monomers (C). Rapid polymerization of the acrylate monomer is provided. A method produces a polyacrylate using the polymeric photoinitiator as described, and a polymeric photoinitiator is used as the photoinitiator of radical polymerization of acrylate monomers.

  通过在聚合物光引发剂的存在下，通过自由基聚合至少一种丙烯酸酯单体（Ac）获得聚丙烯酸酯。聚合物光引发剂是由至少一种光引发剂单体（A）与至少一种单体（B）以及可选的其他单体（C）共聚而成的共聚物。提供了丙烯酸酯单体的快速聚合。一种方法使用上述聚合物光引发剂制备聚丙烯酸酯，以及使用聚合物光引发剂作为丙烯酸酯单体的自由基聚合的光引发剂。
• Polymers Comprising Photoinitiator Moieties and Dye Moieties
  申请人：Lambson Limited

  公开号：US20140316060A1

  公开（公告）日：2014-10-23

  The invention relates to a polymer (P) comprising at least one photoinitiator moiety (PI) and at least one dye moiety (DYE), wherein said at least one photoinitiator moiety (PI) and at least one dye moiety (DYE) are covalently linked to said polymer (P). Additionally, the invention relates to said polymer (P) being end-functionalized with optionally substituted acryloyi groups. The fact that both of these moieties are tightly bonded within the polymer, and the cross-linked polymer, means that the opportunities for leaching/migration of these components is reduced or even eliminated. Inks comprising at least one of said polymers are also provided. Methods for the manufacture of the polymers, and for printing are provided.

  本发明涉及一种聚合物（P），其包括至少一个光引发剂基团（PI）和至少一个染料基团（DYE），其中所述至少一个光引发剂基团（PI）和至少一个染料基团（DYE）与所述聚合物（P）共价连接。此外，本发明涉及所述聚合物（P）末端官能化，其具有可选的取代丙烯酰基团。这些基团都被紧密结合在聚合物中，交联的聚合物意味着这些组分的渗出/迁移机会减少甚至消除。本发明还提供了包含至少一种所述聚合物的油墨。提供了制造聚合物和印刷的方法。
• Method for protecting selected areas of circuitboards; protected circuitboards and boards bearing components
  申请人：DIAMOND SHAMROCK UK LIMITED

  公开号：EP0009967A2

  公开（公告）日：1980-04-16

  A photopolymerisable composition particularly useful as a solder resist composition able to withstand molten solder without loss of adhesion, pitmarks or shrinkage and for forming durable coatings on substrates generally is obtained by a combination of a photoinitiator, a polythiol acting as a chain modifier, and a polymer having hydroxy terminated chains capped by acrylate groups connected to the chains via the residue of a polyisocyanate.

  一种可光聚合的组合物，特别适用于阻焊组合物，它能够承受熔融焊料而不会失去附着力、坑痕或收缩，一般用于在基材上形成耐久涂层，这种组合物是由一种光引发剂、一种作为链改性剂的聚硫醇和一种具有羟基末端链的聚合物组合而成，羟基末端链由丙烯酸酯基团封端，丙烯酸酯基团通过多异氰酸酯的残留物连接到链上。