3,4-bis(decyloxy)thiophene | 156112-75-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,4-bis(decyloxy)thiophene
• 英文别名: 3,4-didecyloxythiophene；3,4-didecoxythiophene
• CAS: 156112-75-3
• 化学式: C₂₄H₄₄O₂S
• 分子量: 396.678
• InChiKey: CFCYZQALCKXBOZ-UHFFFAOYSA-N

物化性质

• 沸点：
  473.7±25.0 °C(Predicted)
• 密度：
  0.935±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  27
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  46.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,4-bis(decyloxy)thiophene 在 N-氯代丁二酰亚胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以55%的产率得到2-chloro-3,4-bis(decyloxy)thiophene
  参考文献：
  名称：

  Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids

  摘要：

  Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent conversion. The "living" character of this process was used to prepare new block copolymers.

  DOI：

  10.1021/ja308498h
• 作为产物：
  描述：

  3,4-Bis-decyloxy-thiophene-2,5-dicarboxylic acid 以88%的产率得到3,4-bis(decyloxy)thiophene
  参考文献：
  名称：

  A Facile Synthesis of 3,4-Dialkoxythiophenes

  摘要：

  Dialkylation of diethyl 3,4-dihydroxythiophenedicarboxylate followed by ester hydrolysis and acid decarboxylation provides a general route to 3,4-dialkoxythiophenes.

  DOI：

  10.1080/00397919608003580

文献信息

• Electro-active monomers comprised of aniline-thiophene units
  申请人：The United States of America as represented by the Secretary of the Air

  公开号：US06130339A1

  公开（公告）日：2000-10-10

  Provided are novel, electropolymerizable monomers of the formulae: ##STR1##

  提供的是化学式为：##STR1## 的新型可电聚合单体。
• Method of crosslinking intrinsically conductive polymers or intrinsically conductive polymer precursors and the articles obtained therefrom
  申请人：——

  公开号：US20040242792A1

  公开（公告）日：2004-12-02

  A method of manufacturing an intrinsically conductive polymer crosslinking at least a portion of an intrinsically conductive polymer precursor in the solid state, the swollen state, or combinations comprising at least one of the foregoing states, wherein the swollen state is characterized as being one wherein the intrinsically conductive polymer precursor increases in volume upon exposure to a solvent without completely dissolving in the solvent. In another embodiment, a method of manufacturing a pattern comprises casting a film of an intrinsically conductive polymer precursor on a substrate; and crosslinking at least a portion of the film by oxidation, wherein the crosslinking occurs in the solid state, the swollen state or combinations comprising at least one of the foregoing states.

  一种制造固态、膨胀态或包括上述状态中至少一种状态的本质导电聚合物交联的方法，其中膨胀态被表征为在暴露于溶剂时，本质导电聚合物前体体积增大而不完全溶解于溶剂中。在另一实施例中，一种制造图案的方法包括在基板上铸造本质导电聚合物前体的薄膜；通过氧化交联至少部分薄膜，其中交联发生在固态、膨胀态或包括上述状态中至少一种状态中。
• CONDUCTIVE COMPOSITION, CONDUCTIVE COATING MATERIAL, CONDUCTIVE RESIN, CAPACITOR, PHOTO-ELECTRIC CONVERTING ELEMENT, AND PROCESS FOR PRODUCING THE SAME
  申请人：SHIN-ETSU POLYMER CO., LTD.

  公开号：EP1634922A1

  公开（公告）日：2006-03-15

  The present invention provides a conductive composition comprising (i) a cyano group-containing polymer compound which is a copolymer of a cyano group-containing monomer and a vinyl group-containing monomer, and Π-conjugated conductive polymer.

  本发明提供了一种导电组合物，该组合物包含(i)含氰基的聚合物化合物，它是含氰基单体和含乙烯基单体的共聚物，以及Π-共轭导电聚合物。
• CONDUCTIVE COMPOSITION AND PROCESS FOR PRODUCING THE SAME, ANTISTATIC PAINT, ANTISTATIC COATING AND ANTISTATIC FILM, OPTICAL FILTER, OPTICAL INFORMATION RECORDING MEDIUM, AND CAPACITOR AND PROCESS FOR PRODUCING THE SAME
  申请人：SHIN-ETSU POLYMER CO., LTD.

  公开号：EP1798259A1

  公开（公告）日：2007-06-20

  A conductive composition comprises a π conjugated conductive polymer, a polyanion, and a hydroxy group-containing aromatic compound containing two or more hydroxy groups. An antistatic coating material comprises the conductive composition and a solvent. An antistatic coating is produced by applying the antistatic coating material. A capacitor comprises an anode composed of a porous valve metal body; a dielectric layer formed by oxidizing a surface of the anode; and a cathode formed on the dielectric layer, wherein the cathode has a solid electrolyte layer comprising the conductive composition.

  导电组合物由 π 共轭导电聚合物、聚阴离子和含有两个或两个以上羟基的含羟基芳香族化合物组成。抗静电涂层材料由导电组合物和溶剂组成。通过使用抗静电涂层材料可制成抗静电涂层。电容器包括由多孔阀金属体组成的阳极；通过氧化阳极表面形成的介电层；以及在介电层上形成的阴极，其中阴极具有由导电组合物组成的固体电解质层。
• CONDUCTIVE-POLYMER SOLUTION, ANTISTATIC COATING MATERIAL, ANTISTATIC HARD COATING LAYER, OPTICAL FILTER, CONDUCTIVE COATING FILM, ANTISTATIC PRESSURE-SENSITIVE ADHESIVE, ANTISTATIC PRESSURE-SENSITIVE ADHESIVE LAYER, PROTECTIVE MATERIAL, AND PROCESS FOR PRODUCING THE SAME
  申请人：Shin-Etsu Polymer Co. Ltd.

  公开号：EP1857504A1

  公开（公告）日：2007-11-21

  The conductive polymer solution of the present invention contains a π-conjugated conductive polymer, a solubilizable polymer, a phase transfer catalyst, and an organic solvent. The method for preparing a conductive polymer solution of the present invention comprises adding a phase transfer catalyst adding an organic solvent to an aqueous polymer solution prepared by dissolving the π-conjugated conductive polymer and a solubilizable polymer in water. Alternatively, the method for preparing a conductive polymer solution of the present invention comprises the steps of adding a phase transfer catalyst to an aqueous polymer solution prepared by dissolving a π-conjugated conductive polymer and a solubilizable polymer in water thereby to precipitate a mixture containing the π-conjugated conductive polymer, the solubilizable polymer and the phase transfer catalyst, and adding an organic solvent to the mixture.

  本发明的导电聚合物溶液含有π-共轭导电聚合物、可溶解聚合物、相转移催化剂和有机溶剂。本发明的导电聚合物溶液的制备方法包括向通过将π-共轭导电聚合物和可溶解聚合物溶解在水中制备的聚合物水溶液中加入相转移催化剂和有机溶剂。或者，本发明制备导电聚合物溶液的方法包括以下步骤：向通过将π-共轭导电聚合物和可溶解聚合物溶于水而制备的聚合物水溶液中加入相转移催化剂，从而析出含有π-共轭导电聚合物、可溶解聚合物和相转移催化剂的混合物，并向该混合物中加入有机溶剂。