1-(异丁氧基甲氧基)-2-甲基丙烷 | 2568-91-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(异丁氧基甲氧基)-2-甲基丙烷
• 英文名称: diisobutoxymethane
• 英文别名: di-iso-butyloxymethane；di-iso-butoxy methane；diisobutyl formal；diisobutylformal；formaldehyde diisobutylacetal；Formaldehyd-diisobutylacetal；Methane, diisobutoxy-；2-methyl-1-(2-methylpropoxymethoxy)propane
• CAS: 2568-91-4
• 化学式: C₉H₂₀O₂
• 分子量: 160.257
• InChiKey: LVRIOILOUAJGGN-UHFFFAOYSA-N

物化性质

• 沸点：
  226.18°C (rough estimate)
• 密度：
  0.8268
• 保留指数：
  930;944

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(异丁氧基甲氧基)-2-甲基丙烷 、 乳腈 在 硫酸 作用下， 生成 2-isobutyloxymethoxy-propionitrile
  参考文献：
  名称：

  US2398757

  摘要：

  公开号：
• 作为产物：
  描述：

  异丁醇 、 二甲基亚砜 在 溴 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 以88%的产率得到1-(异丁氧基甲氧基)-2-甲基丙烷
  参考文献：
  名称：

  Conversion of alcohols to methylene acetals by reaction with dimethyl sulfoxide-bromine

  摘要：

  DOI：

  10.1021/jo01304a039

文献信息

• Oxidation of ethers with dimethyldioxirane
  作者：S. A. Grabovskiy、Q. K. Timerghazin、N. N. Kabal’nova

  DOI：10.1007/s11172-006-0127-0

  日期：2005.10

  Oxidation of a series of tert-butyl ethers ButOR (R = Me, Et, CH2CH2Cl, Pri, Bui), diethyl ether, diisopropyl ether, 1,2-dimethoxyethane, diisobutoxymethane, 1,4-dioxane, and tetrahydrofuran with dimethyldioxirane (DMDO) was studied. The reaction kinetics obeys the second-order equation w = k[DMDO][ether]. The rate constants in a range of 5–50 °C and the activation parameters of the reaction were determined

  使用二甲基二环氧乙烷 (DMDO) 氧化一系列叔丁基醚 ButOR（R = Me、Et、CH2CH2Cl、Pri、Bui）、乙醚、二异丙醚、1,2-二甲氧基乙烷、二异丁氧基甲烷、1,4-二恶烷和四氢呋喃) 进行了研究。反应动力学服从二阶方程 w = k[DMDO][ether]。确定了 5-50°C 范围内的速率常数和反应的活化参数。研究了溶剂对氧化速率的影响。氧化产物是相应的醇和羰基化合物。讨论了反应的非自由基（氧插入）和自由基机制之间的竞争。通过密度泛函理论 (DFT) 研究了母体二环氧乙烷和 DMDO 与一系列甲基醚 MeOr' (r' = Me, Et, CH2CH2F, Pri) 的反应。(U)B3LYP-6-311G(d, p) 方法用于计算反应物和过渡态的几何形状和能量。获得的数据表明通过自由基途径氧化的可能性可能增加，并且含有吸电子取代基的底物的活化势垒增加。
• METHOD FOR MANUFACTURING NITROGEN-CONTAINING CARBON ALLOY, NITROGEN-CONTAINING CARBON ALLOY, AND FUEL CELL CATALYST
  申请人：FUJIFILM Corporation

  公开号：US20150376218A1

  公开（公告）日：2015-12-31

  Provided is a method for manufacturing a nitrogen-containing carbon alloy having a sufficiently high oxygen reduction reaction activity, a nitrogen-containing carbon alloy, and a fuel cell catalyst. The method for manufacturing a nitrogen-containing carbon alloy comprises sintering a precursor which contains a nitrogen-containing compound and an inorganic metal salt, the nitrogen-containing compound having at least one heteroaromatic ring and a conjugated heterocycle, and the conjugated heterocycle having 12 or larger number of ring-forming atoms.

  提供了一种制造具有足够高氧还原反应活性的含氮碳合金的方法，一种含氮碳合金和燃料电池催化剂。制造含氮碳合金的方法包括烧结含有含氮化合物和无机金属盐的前体，其中含氮化合物至少含有一个杂芳环和一个共轭杂环，共轭杂环具有12个或更多个环形原子。
• An Efficient and Convenient Method for the Synthesis of Dialkoxymethanes Using Kaolinite as a Catalyst
  作者：Devendra D. Pathak、J. Joe Gerald

  DOI：10.1081/scc-120018774

  日期：2003.1.5

  Abstract A one pot synthesis of dialkoxymethanes (2a–h) is described from the reaction of alcohols (la–h) with paraformaldehyde under reflux in the presence of catalytic amount of kaolinite.

  摘要描述了在催化量的高岭石存在下，醇 (la-h) 与多聚甲醛在回流下反应的二烷氧基甲烷 (2a-h) 的一锅法合成。
• METHOD OF OBTAINING POLYOXYGENATED ORGANIC COMPOUNDS
  申请人：CONSEJO SUPERIOR DE INVESTIGACIONES CIENT FICAS

  公开号：EP1767515A1

  公开（公告）日：2007-03-28

  The invention relates to a method of obtaining polyoxygenated organic compounds. The inventive method is characterized in that it comprises the oxidation reaction of a diether, preferably an acetal, with an oxygen source, in the presence of: one or more radical initiating agents, one or more additives that generate a basic reaction medium, and one or more catalysts.

  本发明涉及一种获取多氧化有机化合物的方法。该方法的特点在于，它包括在一个或多个引发自由基反应的剂、一个或多个生成碱性反应介质的添加剂和一个或多个催化剂的存在下，将二元醚，优选为缩醛醚，与氧源进行氧化反应。
• Morphological variation, photobiont association and ITS phylogeny of Chaenotheca phaeocephala and C. subroscida (Coniocybaceae, lichenized ascomycetes)
  作者：Leif Tibell、Andreas Beck

  DOI：10.1111/j.1756-1051.2001.tb00824.x

  日期：2001.12

  Chaenotheca phaeocephala and C. subroscida have been characterized by differences in their morphology and ecology. They are, however, morphologically plastic and sometimes seem to intergrade. It has been suspected that the differences in morphology between these two taxa could possibly be phenotypic and caused by their occurrence in different habitats and/or by the association with different photobionts. To test if there is a genetic difference between the species ITS1–5.8S‐ITS2 rDNA sequences of six specimens of the mycobiont of C. phaeocephala and five of C. subroscida were compared. Further the ITS1–5.8S‐ITS2 rDNA sequences of the photobiont of one specimens of C. phaeocephala and six of C. subroscida were compared to each other and to other species of Trebouxia. The mycobiont sequences of both C. phaeocephala and C. subroscida were monophyletic, substantially different and the groups had strong supports. They also proved to be associated with different Trebouxia species, C. phaeocephala with T. arboricola and Chaenotheca subroscida with T. jamesii. The morphologically based concepts of C. phaeocephala and C. subroscida thus not merely represent phenotypic variation but also are associated with considerable genetic differences in the extremes of the ITS1–5.8S‐ITS2 rDNA region.

  _Chaenotheca phaeocephala_ 和 _C. subroscida_ 在形态学和生态学特征上存在差异。然而，它们在形态上具有一定的可塑性，有时似乎会出现过渡现象。人们怀疑这两个分类单元之间的形态差异可能是表型上的，这可能与其栖息地的不同以及与不同光合共生生物的关联有关。为了验证这两个物种之间是否存在遗传差异，我们比较了 _C. phaeocephala_ 真菌共生体的六个样本和 _C. subroscida_ 的五个样本的 ITS1–5.8S‐ITS2 rDNA 序列。此外，我们还比较了 _C. phaeocephala_ 一个样本和 _C. subroscida_ 六个样本的光合共生体的 ITS1–5.8S‐ITS2 rDNA 序列，并与其他 _Trebouxia_ 种类进行了比较。结果发现，无论是 _C. phaeocephala_ 还是 _C. subroscida_，它们的真菌共生体序列均具有单系性且差异显著，支持度较高。同时，它们分别与不同的 _Trebouxia_ 种类相关联，_C. phaeocephala_ 与 _T. arboricola_ 关联，而 _C. subroscida_ 与 _T. jamesii_ 关联。因此，基于形态学的 _C. phaeocephala_ 和 _C. subroscida_ 的概念不仅仅是表型变异的体现，还伴随着 ITS1–5.8S‐ITS2 rDNA 区域在遗传上的显著差异。

表征谱图