3-(2-methylaziridin-1-yl)-propionic acid 2-[4-(2-hydroxy-2-methyl-propionyl)phenoxy]ethyl ester | 1228009-89-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(2-methylaziridin-1-yl)-propionic acid 2-[4-(2-hydroxy-2-methyl-propionyl)phenoxy]ethyl ester
• 英文别名: 2-[4-(2-Hydroxy-2-methylpropanoyl)phenoxy]ethyl 3-(2-methylaziridin-1-yl)propanoate
• CAS: 1228009-89-9
• 化学式: C₁₈H₂₅NO₅
• 分子量: 335.4
• InChiKey: LUBLVMHOFSZERO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  75.8
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-(4-(2-hydroxy-2-methylpropanoyl)phenoxy)ethyl acrylate 、 2-甲基氮丙啶 以 二氯甲烷 为溶剂， 生成 3-(2-methylaziridin-1-yl)-propionic acid 2-[4-(2-hydroxy-2-methyl-propionyl)phenoxy]ethyl ester
  参考文献：
  名称：

  [EN] AZIRIDINE-FUNCTIONAL PHOTOACTIVE CROSSLINKING COMPOUNDS
  [FR] COMPOSÉS DE RÉTICULATION PHOTOACTIFS À FONCTION AZIRIDINE

  摘要：

  描述了一种光活性化合物，它是氮杂环丙烷化合物和光引发剂官能基（甲基）丙烯酸酯的迈克尔加成反应产物。该化合物可通过氢抽取或α-裂解机制用于交联（甲基）丙烯酸聚合物。

  公开号：

  WO2010065355A1

文献信息

• AZIRIDINE-FUNCTIONAL PHOTOACTIVE CROSSLINKING COMPOUNDS
  申请人：Zhu Peiwang

  公开号：US20100137469A1

  公开（公告）日：2010-06-03

  A photoactive compound that is the Michael addition reaction product of an aziridine compound and a photoinitiator-functional (meth)acrylate is described. The compound can be used to crosslink (meth)acrylic polymers via a hydrogen abstracting or an alpha-cleavage mechanism.

  描述了一种光活性化合物，它是氮杂环丙烷化合物和光引发剂官能基（甲基）丙烯酸酯的迈克尔加成反应产物。该化合物可通过氢抽取或α-裂解机制用于交联（甲基）丙烯酸聚合物。
• Syrup polymer compositions and adhesives therefrom
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10093753B2

  公开（公告）日：2018-10-09

  Acrylic syrup polymer composition are provided by partially polymerizing a (meth)acrylic monomer mixture in the presence of a thiol chain transfer agent to produce a first syrup polymer composition comprising a low molecular weight solute (meth)acrylic copolymer and solvent monomers, quenching the chain transfer agent, further polymerizing the first syrup polymer composition to produce a second syrup polymer composition comprising the low molecular weight solute acrylic copolymer, a high molecular weight solute acrylic copolymer and optionally unreacted solvent monomers, optionally adding a crosslinker and photoinitiator; and further photopolymerizing the syrup polymer composition to produce a pressure-sensitive adhesive.

  丙烯酸糖浆聚合物组合物的制备方法是：在硫醇链转移剂存在下，部分聚合（甲基）丙烯酸单体混合物，生成包含低分子量溶质（甲基）丙烯酸共聚物和溶剂单体的第一糖浆聚合物组合物；淬灭链转移剂；进一步聚合第一糖浆聚合物组合物，生成包含低分子量溶质丙烯酸共聚物、高分子量溶质丙烯酸共聚物和任选未反应溶剂单体的第二糖浆聚合物组合物；任选添加交联剂和光引发剂；进一步光聚合糖浆聚合物组合物，生产压敏胶。
• SYRUP POLYMER COMPOSITIONS AND ADHESIVES THEREFROM
  申请人：3M Innovative Properties Company

  公开号：EP3227347A1

  公开（公告）日：2017-10-11
• US7838110B2
  申请人：——

  公开号：US7838110B2

  公开（公告）日：2010-11-23
• [EN] SYRUP POLYMER COMPOSITIONS AND ADHESIVES THEREFROM<br/>[FR] COMPOSITIONS DE SIROPS DE POLYMÈRES ET ADHÉSIFS CORRESPONDANTS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2016089805A1

  公开（公告）日：2016-06-09

  Acrylic syrup polymer composition are provided by partially polymerizing a (meth)acrylic monomer mixture in the presence of a thiol chain transfer agent to produce a first syrup polymer composition comprising a low molecular weight solute (meth)acrylic copolymer and solvent monomers, quenching the chain transfer agent, further polymerizing the first syrup polymer composition to produce a second syrup polymer composition comprising the low molecular weight solute acrylic copolymer, a high molecular weight solute acrylic copolymer and optionally unreacted solvent monomers, optionally adding a crosslinker and photoinitiator; and further photopolymerizing the syrup polymer composition to produce a pressure-sensitive adhesive.