Acrylsaeure-((anthrachinon-2-yl)-methylester) | 93656-95-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: Acrylsaeure-((anthrachinon-2-yl)-methylester)
• 英文别名: acrylic acid 9,10-dioxo-9,10-dihydroanthracen-2-ylmethyl ester；(9,10-Dioxoanthracen-2-yl)methyl prop-2-enoate
• CAS: 93656-95-2
• 化学式: C₁₈H₁₂O₄
• 分子量: 292.291
• InChiKey: DHLPLORHQFEPCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  60.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Acrylsaeure-((anthrachinon-2-yl)-methylester) 、 2-甲基氮丙啶 以 二氯甲烷 为溶剂， 生成 3-(2-methylaziridin-1-yl)propionic acid 9,10-dioxo-9,10-dihydro-anthracen-2-ylmethyl ester
  参考文献：
  名称：

  [EN] AZIRIDINE-FUNCTIONAL PHOTOACTIVE CROSSLINKING COMPOUNDS
  [FR] COMPOSÉS DE RÉTICULATION PHOTOACTIFS À FONCTION AZIRIDINE

  摘要：

  描述了一种光活性化合物，它是氮杂环丙烷化合物和光引发剂官能基（甲基）丙烯酸酯的迈克尔加成反应产物。该化合物可通过氢抽取或α-裂解机制用于交联（甲基）丙烯酸聚合物。

  公开号：

  WO2010065355A1
• 作为产物：
  描述：

  2-羟甲基蒽醌 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 Acrylsaeure-((anthrachinon-2-yl)-methylester)
  参考文献：
  名称：

  [EN] AZIRIDINE-FUNCTIONAL PHOTOACTIVE CROSSLINKING COMPOUNDS
  [FR] COMPOSÉS DE RÉTICULATION PHOTOACTIFS À FONCTION AZIRIDINE

  摘要：

  描述了一种光活性化合物，它是氮杂环丙烷化合物和光引发剂官能基（甲基）丙烯酸酯的迈克尔加成反应产物。该化合物可通过氢抽取或α-裂解机制用于交联（甲基）丙烯酸聚合物。

  公开号：

  WO2010065355A1

文献信息

• CHANGING SURFACE PROPERTIES BY FUNCTIONALIZED NANOPARTICLES
  申请人：Giesenberg Thomas

  公开号：US20100178512A1

  公开（公告）日：2010-07-15

  A process for modifying the surface of an inorganic or organic substrate with strongly adherent nanoparticles is described, providing to the surface modified substrate durable effects like hydrophobicity, hydrophilicity, electrical conductivity, magnetic properties, flame retardance, color, adhesion, roughness, scratch resistance, UV-absorbance, antimicrobial properties, antifouling properties, antiprotein properties, antistatic properties, antifog properties, release properties. In this process, an optional first step a) a low-temperature plasma, ozonization, high energy irradiation, corona discharge or a flame is caused to act on the inorganic or organic substrate, and in a second step b) one or more defined nanoparticles or mixtures of defined nanoparticles with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied, preferably at normal pressure, to the inorganic or organic substrate. In a third step c) suitable methods are applied to dry or cure those afore-mentioned substances and, optionally, in a fourth step d) a further coating is applied on the substrate so pretreated.

  本文描述了一种用强附着力纳米颗粒改性无机或有机基底表面的方法，使表面改性后的基底具有耐久性效果，如疏水性、亲水性、电导性、磁性、防火性、颜色、附着力、粗糙度、抗刮擦性、UV吸收性、抗菌性、防污性、抗蛋白质性、抗静电性、防雾性和释放性。在此过程中，第一步（可选）是在无机或有机基底上施加低温等离子体、臭氧化、高能辐射、电晕放电或火焰，第二步（b）是将一个或多个定义的纳米颗粒或定义的纳米颗粒与至少一个乙烯基未饱和基团的单体，或上述物质的溶液、悬浮液或乳液，应用于无机或有机基底上，最好是在常压下进行。第三步（c）是应用适当的方法干燥或固化上述物质，可选地，在第四步（d）中在预处理的基底上施加进一步的涂层。
• Anti-fog coatings on thermoplastic substrates
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1498189A1

  公开（公告）日：2005-01-19

  The invention relates to a process for the production of strongly adhering anti-fogging coatings on thermoplastic substrates, wherein a low-temperature plasma treatment, a corona discharge treatment or a flame treatment is applied to the thermoplastic substrate. Subsequently the substrate is coated at normal pressure with a composition comprising one or more photoinitiators and at least one ethylenically unsaturated monomer or oligomer with one or more hydrophilic groups in the molecule, imparting anti-fogging properties. The coating is then cured by means of radiation. The invention relates also to the use of an unsaturated monomer or oligomer with one or more hydrophilic groups in the molecule as anti-fogging agent in such layers and to the strongly adherent coatings themselves.

  本发明涉及一种在热塑性基材上生产强附着性防雾涂层的工艺，其中对热塑性基材进行低温等离子处理、电晕放电处理或火焰处理。然后在常压下在基材上涂覆一种组合物，该组合物包括一种或多种光引发剂和至少一种乙烯不饱和单体或低聚物，其分子中含有一个或多个亲水基团，可赋予防雾特性。然后通过辐射固化涂层。本发明还涉及在此类涂层中使用分子中含有一个或多个亲水基团的不饱和单体或低聚物作为防雾剂，以及强附着涂层本身。
• Silicon coated release substrate
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1772479A1

  公开（公告）日：2007-04-11

  Subject of the invention is a process for the preparation of a silicon release-layer on an inorganic or organic substrate, wherein a pretreated substrate is first covered with an adhesion promoting composition and subsequently a silicon and/or fluorine containing composition is applied as the top layer.

  本发明的主题是在无机或有机基底上制备硅释放层的工艺，其中首先在预处理过的基底上覆盖一层增粘组合物，然后将含硅和/或氟的组合物作为面层使用。
• Process for the production of strongly adherent coatings
  申请人：Kunz Martin

  公开号：US20050147919A1

  公开（公告）日：2005-07-07

  The invention relates to a process and to the corresponding apparatus for the production of strongly adherent coatings on an inorganic or organic substrate, wherein in a first step: a) a low-temperature plasma, a corona discharge or a flame is caused to act on the inorganic or organic substrate, in a second step: b) one or more photoinitiators or mixtures of photoinitiators with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied at normal pressure to the inorganic or organic substrate, in a third step: c) using suitable methods those afore-mentioned substances are dried and/or irradiated with electromagnetic waves and, optionally, in a fourth step d) the substrate so pretreated is provided with a coating and the coating is cured or dried.

  本发明涉及一种在无机或有机基底上生产强附着力涂层的工艺和相应设备，其中第一步： a) 在无机或有机基底上产生低温等离子体、电晕放电或火焰，第二步： b) 在无机或有机基底上产生一种或多种光引发剂或光引发剂与单体的混合物（至少含有一个乙烯不饱和基），或上述单体的溶液、悬浮液或乳液：b) 将一种或多种光引发剂或光引发剂与单体的混合物（至少含有一个乙烯不饱和基团）或上述物质的溶液、悬浮液或乳液在常压下施加到无机或有机基材上，第三步： c) 使用适当的方法将上述物质干燥和/或用电磁波照射，第四步： d) 在经过预处理的基材上涂覆涂层，并将涂层固化或干燥。
• VERFAHREN ZUR HERSTELLUNG HAFTFESTER OBERFLÄCHENBESCHICHTUNGEN
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1135219B1

  公开（公告）日：2004-01-28