N-甲基-2,4,6-三硝基苯胺 | 1022-07-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-甲基-2,4,6-三硝基苯胺
• 英文名称: N-methylpicramide
• 英文别名: N-Methyl-2,4,6-trinitro-anilin；N-Methyl-pikramid；N-Methylpicramid；2,4,6-Trinitro-N-methyl-anilin；N-methyl-2',4',6'-trinitroaniline；N-Methyl-2,4,6-trinitroaniline
• CAS: 1022-07-7
• 化学式: C₇H₆N₄O₆
• 分子量: 242.148
• InChiKey: CFYAUGJHWXGWHI-UHFFFAOYSA-N

物化性质

• 熔点：
  114.8 °C(Solv: ethanol (64-17-5))
• 沸点：
  390.1±42.0 °C(Predicted)
• 密度：
  1.676±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  150
• 氢给体数：
  1
• 氢受体数：
  7

安全信息

• 海关编码：
  2921430090

反应信息

• 作为反应物：
  描述：

  N-甲基-2,4,6-三硝基苯胺 在 乙醇 、 亚硝酸 、 溶剂黄146 作用下， 生成 2,4,6-三硝基二苯基胺
  参考文献：
  名称：

  Seats That May Not Matter: Testing for Racial Polarization in U.S. City Councils

  摘要：

  DOI：

  10.3162/036298002x200693
• 作为产物：
  描述：

  1-甲基-1-苯基脲 在 四氯化碳 、 硝酸 作用下， 生成 N-甲基-2,4,6-三硝基苯胺
  参考文献：
  名称：

  Ryan; Sweeney, Scientific Proceedings of the Royal Dublin Society, 1922, vol. 17, p. 159,160

  摘要：

  DOI：

文献信息

• Aromatic nucleophilic substitution reactions of 1-dialkylamino-substituted activated benzenes with various amines in dimethyl sulfoxide
  作者：Shizen Sekiguchi、Hiromi Ishikura、Yukitoshi Hirosawa、Nobuyuki Ono

  DOI：10.1016/s0040-4020(01)87755-3

  日期：1990.1

  In the reactions of 1-d1a1kylamino-2,4,6-trinitro- and 1-dialkylam1no-2, 4-dinitrobenzenes with various amines in dimethyl sulfoxide, 1-dialkylamino group is easily replaced with primary n-alkylamines at room temperature, and in a low yield with pyrrolidine only among secondary amines.

  在二甲基亚砜中1-d1a1kylamino-2,4,6-三硝基和1-dialkam1no-2、4-二硝基苯与各种胺的反应中，1-二烷基氨基很容易在室温下被伯正烷基胺取代，并且仅仲胺中吡咯烷的收率低。
• Evidence of the presence of minor tautomeric forms in selected nitroanilines
  作者：Diego D. Colasurdo、Matías N. Pila、Sergio L. Laurella、Patricia E. Allegretti、Danila L. Ruiz

  DOI：10.1002/rcm.9000

  日期：2021.2.15

  Nitroanilines can exist in several tautomeric forms: nitro‐amino, nitro‐imino, and aci‐imino. The importance of evaluating minor tautomeric species comes from the fact that even less abundant tautomers have been proved to play important roles in reaction mechanisms.

  硝基苯胺可以几种互变异构形式存在：硝基氨基，硝基亚氨基和氨基亚氨基。评估少数互变异构物种的重要性来自以下事实：事实证明，甚至更少量的互变异构体在反应机理中也起着重要作用。
• Controlled Odor Mimic Permeation System
  申请人：Furton Kenneth G.

  公开号：US20080295783A1

  公开（公告）日：2008-12-04

  The primary aspect of the Controlled Odor Mimic Permeation System (COMPS) is that it provides a field deployable instant and reproducible source of known amounts of target odors. This technology consists of a permeable polymer container (chosen to suit target odor and release rate required), stored inside a non-permeable package. The design allows for the pre-equilibration of the target odors such that the outer surface of the inner package can saturate with odor during storage. Removal of the inner item then provides an instant and reproducible source of known target vapor flux. We have successfully demonstrated this technology by placing the target odor chemicals within permeable membranes such as low density polyethylene which are then sealed within a non-permeable membranes such as metallized polyester. This design has multiple advantages including preventing cross contamination when storing multiple odor targets (5-10 targets are commonly employed) as well as being light-weight disposable, low unit cost potential, no external power/operating unit/machinery/hardware, simple to use and providing a known reproducible concentration of the target odors to the detector in the field. The applications of these COMPS include the whole range of biological (e.g. detector dog) and electronic (e.g. field sensors) detectors with examples such as explosives (e.g. 2-ethyl-1-hexanol simulating plasticized explosives), drugs (e.g. 3,4-methylenedioxybenzaldehyde simulating ecstasy), human remains (including dimethyl disulfide and pentanoic acid) and live human scent (including 5-heptene-2-one and nonanol).

  受控气味模拟渗透系统（COMPS）的主要方面是，它提供了一个现场可部署的即时和可重复的目标气味已知量源。该技术由一个渗透性聚合物容器（选择适合目标气味和所需释放速率的容器）组成，存放在一个非渗透性包装内。该设计允许目标气味预平衡，使内包装的外表面在存储期间饱和。然后，移除内部物品即可提供已知目标蒸汽通量的即时和可重复的源。我们已经成功地通过将目标气味化学品放置在渗透膜内（例如低密度聚乙烯），然后密封在非渗透膜内（例如金属化聚酯），展示了这项技术。这种设计具有多个优点，包括在存储多个气味目标（通常使用5-10个目标）时防止交叉污染，轻量级一次性，低单位成本潜力，无需外部电源/操作单元/机械/硬件，易于使用并在现场为检测器提供已知可重复的目标气味浓度。这些COMPS的应用包括整个生物（例如检测犬）和电子（例如现场传感器）检测器的范围，例如爆炸物（例如模拟塑化炸药的2-乙基-1-己醇），毒品（例如模拟迷幻药的3,4-亚甲二氧基苯甲醛），人体遗骸（包括二甲基二硫化物和戊酸）和活体人体气味（包括5-庚烯-2-酮和辛醇）。
• ENERGETIC COCRYSTALS FOR TREATMENT OF A SUBTERRANEAN FORMATION
  申请人：HALLIBURTON ENERGY SERVICES, INC.

  公开号：US20160177698A1

  公开（公告）日：2016-06-23

  The present invention relates to energetic cocrystals, and to methods for using the same for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation, the method including obtaining or providing a composition including energetic cocrystals. Each energetic cocrystal independently includes an energetic compound and a secondary material. The method also includes placing the composition in a subterranean formation.

  本发明涉及具有能量共晶体的相关技术，以及使用这些技术治疗地下地层的方法。在各种实施例中，本发明提供了一种治疗地下地层的方法，该方法包括获得或提供包括能量共晶体的组合物。每个能量共晶体独立地包括一个能量化合物和一个辅助材料。该方法还包括将该组合物放置在地下地层中。
• THERMALLY STABLE BOOSTER EXPLOSIVE AND PROCESS FOR MANUFACTURE
  申请人：Quinlin T. William

  公开号：US20060025603A1

  公开（公告）日：2006-02-02

  A thermally stable booster explosive and process for the manufacture of the explosive. The product explosive is 2,4,7,9-tetranitro-10H-benzo[4,5]furo[3,2-b]indole (TNBFI). A reactant/solvent such as n-methylpyrrolidone (NMP) or dimethyl formamide (DMF) is made slightly basic. The solution is heated to reduce the water content. The solution is cooled and hexanitrostilbene is added. The solution is heated to a predetermined temperature for a specific time period, cooled, and the product is collected by filtration.

  一种热稳定助推炸药及其制造过程。产品炸药为2,4,7,9-四硝基-10H-苯并[4,5]呋喃[3,2-b]吲哚（TNBFI）。将反应剂/溶剂（如N-甲基吡咯烷酮（NMP）或二甲基甲酰胺（DMF））稍微碱性化，加热溶液以减少水分含量。将溶液冷却后加入六硝基苯基乙烯。将溶液加热到预定温度并保持一定时间，冷却后通过过滤收集产物。

表征谱图