2,6,14-trimethyl-10-methylene-9-(3-methylenepent-4-enyl)pentadec-6-ene

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,6,14-trimethyl-10-methylene-9-(3-methylenepent-4-enyl)pentadec-6-ene
• 英文别名: 2,6,14-Trimethyl-10-methylene-9-(3-methylene-pent-4-enyl)-pentadec-6-ene；(E)-2,6,14-trimethyl-10-methylidene-9-(3-methylidenepent-4-enyl)pentadec-6-ene
• 化学式: C₂₅H₄₄
• 分子量: 344.624
• InChiKey: FAPXABWJTYQDGU-HAVVHWLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  25
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,6,14-trimethyl-10-methylene-9-(3-methylenepent-4-enyl)pentadec-6-ene 在 platinum(IV) oxide 氢气 作用下， 以 乙腈 为溶剂， 生成 2,6,10,14-tetramethyl-7-(3-methylpentyl)pentadecane
  参考文献：
  名称：

  Tetra-unsaturated sesterterpenoids (Haslenes) from Haslea ostrearia and related species

  摘要：

  The structures and distributions of C25 highly branched isoprenoid (HBI) alkenes (Haslenes) have been determined following isolation from cultures of the diatoms Haslea ostrearia, Haslea crucigera, Haslea pseudostrearia and Haslea saltstonica. The distributions of the HBIs change between Haslea species and also between different cultures of the same species. Large scale culturing of H. ostrearia and H. pseudostrearia has enabled the structures of three new tetra-unsaturated alkenes to be determined by NMR spectroscopy. The structural relationships between different Haslenes together with the potential significance of the biosynthesis of HBIs by the Haslea genus is discussed.

  DOI：

  10.1016/s0031-9422(00)00429-5

文献信息

• Tetra-unsaturated sesterterpenoids (Haslenes) from Haslea ostrearia and related species
  作者：W Guy Allard、Simon T Belt、Guillaume Massé、Raoul Naumann、Jean-Michel Robert、Steven Rowland

  DOI：10.1016/s0031-9422(00)00429-5

  日期：2001.4

  The structures and distributions of C25 highly branched isoprenoid (HBI) alkenes (Haslenes) have been determined following isolation from cultures of the diatoms Haslea ostrearia, Haslea crucigera, Haslea pseudostrearia and Haslea saltstonica. The distributions of the HBIs change between Haslea species and also between different cultures of the same species. Large scale culturing of H. ostrearia and H. pseudostrearia has enabled the structures of three new tetra-unsaturated alkenes to be determined by NMR spectroscopy. The structural relationships between different Haslenes together with the potential significance of the biosynthesis of HBIs by the Haslea genus is discussed.