三苯基碘锡 | 894-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯基碘锡
• 英文名称: iodotriphenylstannane
• 英文别名: Triphenyl-zinniodid；triphenylstannanylium;iodide
• CAS: 894-09-7
• 化学式: C₁₈H₁₅ISn
• 分子量: 476.932
• InChiKey: KJSACGHPPNXZFT-UHFFFAOYSA-M

物化性质

• 熔点：
  117-121°C
• 沸点：
  250-253°C / 13

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• TSCA：
  No
• 危险类别码：
  R20/21/22
• 海关编码：
  2931900090

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : IODOTRIPHENYLTIN
CAS-No. : 894-09-7
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Label elements
This substance is not classified as dangerous according to Directive 67/548/EEC.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C18H15ISn
Molecular Weight : 476,92 g/mol

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Section 4. FIRST AID MEASURES
Description of first aid measures
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen iodide, Tin/tin oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapors, mist or gas.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: WH8582000

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available

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Section 16. OTHER INFORMATION
Further information
Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  三苯基碘锡 在 Br₂ 、 HCl 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 生成 三苯基氯化锡
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.15.6, page 401 - 408

  摘要：

  DOI：
• 作为产物：
  描述：

  三苯基氢化锡 在 iodo naphthalene 作用下， 以 not given 为溶剂， 生成 三苯基碘锡
  参考文献：
  名称：

  Hydrogenolyses of Aromatic Halides with Triaryltin Hydrides¹

  摘要：

  DOI：

  10.1021/jo01044a042
• 作为试剂：
  描述：

  lead(IV) tetraacetate 、 ethyl triphenylstannylacetate 在 三苯基碘锡 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 0.33h， 以94%的产率得到乙酰基乙醇酸乙酯
  参考文献：
  名称：

  Reactions of stannylacetic acid derivatives with lead tetraacetate

  摘要：

  DOI：

  10.1007/bf00954394

文献信息

• Oxidative addition of triorganotin halides to platinum(0) complexes
  作者：Colin Eaborn、Alan Pidcock、Barry R. Steele

  DOI：10.1039/dt9760000767

  日期：——

  Triorganotin chlorides react with complexes of Pt0 to give products of insertion into the Sn–C rather than the Sn–Cl bond as reported previously. Products of the type cis-[PtR(PPh3)2(SnR′2X)](R = Ph, R′2X = Ph2Cl, MePhCl, Me2Cl, BrPh2, Ph2I, Ph2(OH), Ph2(ONO2), or Ph3) have been obtained from [Pt(C2H4)(PPh3)2] and SnPhR′2X, cis-[PtMe(PPh3)2(SnMe2Cl)] from [Pt(C2H4)(PPh3)2] and SnMe3Cl, and cis-[PtMe(PEt3)2(SnMe3)]

  三有机锡氯化物与Pt 0的配合物反应，生成插入到Sn–C中的产物，而不是先前报道的Sn–Cl键。类型的产品顺- [PTR（PPH 3）2（SNR' 2 X）]（R =苯基，R' 2 X =苯基2氯，MePhCl中，Me 2氯，BrPh 2中，Ph 2我中，Ph 2（ OH）中，Ph 2（ONO 2），或PH 3）已经从[PT（C获得的2 ħ 4）（PPH 3）2 ]和SnPhR' 2 X，顺-[ Pt（C 2 H 4）（PPh 3）2 ]和SnMe 3 Cl的-[PtMe（PPh 3）2（SnMe 2 Cl）]]和顺式-[PtMe（PEt 3）2（SnMe 3）] [Pt（PEt 3）4 ]和SnMe 4。已经重新研究了报道的给出具有Cl和SnR 3配体的配合物的各种反应，并显示了给出具有R和SnR 2的Cl配体的配合物或衍生自它们的配合物。已报道SnPh 3配体转变为Ph配体和Snph2
• Kinetics and mechanisms of cleavage of allylic derivatives of group IVA elements by mercuric salts
  作者：R.M.G Roberts

  DOI：10.1016/s0022-328x(00)85399-1

  日期：1969.8

  The cleavage of allylic derivatives of trialkyl-and triphenyltin compounds by mercuric salts in solvent ethanol has been examined using spectrophotometric and chromatographic techniques.

  已使用分光光度法和色谱技术检查了汞盐在溶剂乙醇中对三烷基锡和三苯基锡化合物的烯丙基衍生物的裂解。
• Metal-halogen bonding studies with group IV A trialkylmetal halides
  作者：Edwin C. Friedrich、Charles B. Abma、Paul F. Vartanian

  DOI：10.1016/s0022-328x(00)81789-1

  日期：1980.3

  Halogen redistribution reactions have been found to take place between benzyl bromide or benzyl iodide and the Group IVA silicon, germanium, tin, and lead containing triakylmetal chlorides. However, for the reactions of the Si, Ge and Sn compounds, a quaternary ammonium halide catalyst was necessary to enable the equilibria to be established at reasonably rapid rates. The equilibrium constants at 50°C

  已经发现卤素重新分布反应发生在苄基溴或苄基碘与IVA族硅，锗，锡和含铅的三烷基金属氯化物之间。但是，对于Si，Ge和Sn化合物的反应，季铵卤化物催化剂对于使平衡能够以合理的快速速率建立是必不可少的。在这些卤素的重新分布下，已分别测量了在50°C时的平衡常数。已发现它们在IV A组中从硅到铅下降时逐渐增加，对于R 3 MCl + BzBr和R 3而言，在硅中小于1，而在铅中大于1。 MCl + BzI反应。该Δ ģ°，这些均衡值已被计算出，并建议他们的差异可能在的相对重要性来解释p π d在各种IV族甲trialkylmetal卤化物系统的卤素-金属粘合π贡献。
• Synthesis of triphenylphosphonopropionbetainetriorganotin(IV) salts [(C6H5)3P(CH2)2CO2SnR3]+X−, by nucleophilic displacement of anions from triorganotins
  作者：S.-W. Ng、J.J. Zuckerman

  DOI：10.1016/0022-328x(82)80002-8

  日期：1982.8

  phosphobetaine and triphenyltin(IV) isocyanate and methyldiphenyltin(IV) chloride. The phosphonium chloride double salt could be converted to the thiophosphonium derivative by heating with elemental sulfur in ethanol. The products of these novel nucleophilic displacement reactions are high melting solids. Tin-119m Mössbauer data are consistent with five-coordinated, triorganotin(IV) formulations with the exception

  三甲基和三苯基锡（IV）氢氧化物作用于由3-氯丙酸和三苯基膦制成的三苯基（2-羧乙基）-hydro盐酸盐，在二甲基甲酰胺（DMF）作为催化剂存在下释放出水。将水共沸蒸馏以推动反应向前进行，并以高收率产生三苯基膦酰基丙氨酸甜菜碱三甲基和三苯基锡（IV）氯化物。后者的产物还由磷酸甜菜碱（C 6 H 5）3 P（CH 2）2 CO 2取代，由氯化三苯锡（IV）氯化物所制得，该化合物是通过用碳酸氢盐处理氯化，而制得的，以及这些化合物[（C 6 H 5）3 P（CH 2）2 CO 2的Sn（C 6 H ^ 5）3 ] + X - ，其中X =氯，溴，I，N 3，NCS，NO 3，B（C 6 H ^ 5）4和Co（ CO）4的制作方法相同。乙酸盐是由氯化物和乙酸铅（II）的复分解产生的。一种复盐，[（C 6 H 5）3 P（CH 2）2 CO 2 SnR 3 ] + [R 3通过向已形成的单盐中添加额外的（C
• Sulphur-substituted organometallic compounds. Part IV. Reactions of p-tolylthiomethyltriphenyltin with electrophilic reagents and oxidants. Comparison of reactions of the oxygen, selenium, and germanium analogues
  作者：Robin D. Taylor、James L. Wardell

  DOI：10.1039/dt9760001345

  日期：——

  and (iv) all reactions of HgCl2 give only Sn–Ph bond cleavage. In contrast, the reactionsof SnPh3(CH2SC6H4Me-p) with Etl and Na[IO4] each lead to SnPh3(CH2I). While attempts to prepare the tin sulphoxlde, Ph3SnCH2S(o)C6H4Me-p, have failed, the germanium analogue has been prepared using Br2, in aqueous methanol as the oxidant. The effect on the halogen reactions of changing the aryl groups (R) in SnR3(CH2SR)

  SnPh的反应3（CH 2 ZC 6 ħ 4 ME- p）（Z = O，S和Se）被Br 2，我2，的HgCl 2，和通常PhSCl给SnPh和Sn-CH 2键断裂。得出以下结论：（i）SnPh 3（CH 2 OC 6 H 4 Me- p）的所有反应仅导致Sn-Ph裂解：（ii）PhSCl反应中未发生Sn-Ph键裂解；（iii）卤素在与硫和硒化合物反应时会同时发生两种裂解：和（iv）HgCl 2的所有反应仅给出Sn-Ph键的裂解。与此相反，reactionsof SnPh 3（CH 2 SC 6 H ^ 4 ME- p）与ETL和Na [IO 4 ]分别通往SnPh 3（CH 2 I）。而尝试制备锡sulphoxlde中，Ph 3 SNCH 2 S（O）C 6 H ^ 4 ME- p，都失败了，锗类似物已使用溴制备2，在甲醇水溶液作为氧化剂。改变SnR 3（CH 2SR）已经简要的研究，作为具有GePh的反应3-