Ph3SnSPh | 1441-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ph3SnSPh
• 英文别名: Benzenethiolate;triphenylstannanylium
• CAS: 1441-22-1
• 化学式: C₂₄H₂₀SSn
• 分子量: 459.199
• InChiKey: LRKGFRRKAOVBFF-UHFFFAOYSA-M

物化性质

• 熔点：
  102-103 °C
• 沸点：
  508.2±33.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Ph3SnSPh 在 四丁基氟化铵 作用下， 以 二氯甲烷 为溶剂， 以97%的产率得到二苯二硫醚
  参考文献：
  名称：

  Electrogeneration of Triphenyltin Radical, Anion, and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions

  摘要：

  In our research of precursors of tin radicals able to initiate radical chain reactions under mild conditions, a series of triphenyltin derivatives Ph(3)SnY (Y = H, I, Cl, OTf, OCHO, SnPh(3), SPh) is investigated by cyclic voltammetry. The results show that the tin radical Ph(3)Sn(.) is only produced from two compounds: by a one-electron oxidation of Ph(3)SnH or by a one-electron reduction of Ph(3)SnI. Therefore electrooxidation of Ph(3)SnH generates Ph(3)Sn(.) which is able to initiate cyclization of haloalkynes. Reduction or oxidation of the other derivatives affords respectively the anion Ph(3)Sn(-) or the cation Ph(3)Sn(+) because they are generated at potentials where the radical Ph(3)Sn(.) is either reduced or oxidized.

  DOI：

  10.1021/jo960741b
• 作为产物：
  描述：

  lithium triphenylstannide 以 正己烷 为溶剂， 生成 Ph3SnSPh
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.15.4, page 386 - 396

  摘要：

  DOI：

文献信息

• Ruthenium and osmium carbonyl clusters incorporating stannylene and stannyl ligands
  作者：Shariff E. Kabir、Arun K. Raha、Mohammad R. Hassan、Brian K. Nicholson、Edward Rosenberg、Ayesha Sharmin、Luca Salassa

  DOI：10.1039/b805024d

  日期：——

  bimetallic Ru–Sn compound [Ru3(CO)8(μ-SPh)2(μ3-SnPh2)(SnPh3)2] 1 which consists of a SnPh2 stannylene bonded to three Ru atoms to give a planar tetra-metal core, with two peripheral SnPh3 ligands. The stannylene ligand forms a very short bond to one Ru atom [Sn–Ru 2.538(1) Å] and very long bonds to the other two [Sn–Ru 3.074(1) Å]. The germanium compound [Ru3(CO)8(μ-SPh)2(μ3-GePh2)(GePh3)2] 2 was obtained

  [的反应Ru 3（CO）12] 和 Ph 3 SnSPh 在回流中 苯 提供了双金属Ru-Sn化合物[茹3（CO）8（μ-SPH）2（μ 3 -SnPh 2）（SnPh 3）2] 1，其中包含一个锡磷2 亚锡 绑定到三个 茹 原子产生平面四金属核，两个外围 锡磷3配体。这亚锡 配体与一个很短的键 茹原子[Sn–Ru 2.538（1）Å]和与其他两个[Sn–Ru 3.074（1）Å]的很长键。这锗 化合物 [茹3（CO）8（μ-SPH）2（μ 3 -GePh 2）（GePh 3）2从[的反应中得到] 2Ru 3（CO）12] 和 Ph 3 GeSPh并具有与1相似的结构，这由光谱数据证明。[操作系统3（CO）10（MeCN）2] 和 Ph 3 SnSPh 在回流中 苯产生双金属OS-Sn化合物[O的3（CO）9（μ-SPH）（μ 3 -SnPh 2）（乙腈）（η 1 -C 6 ħ 5）] 3。簇
• Novel room light-induced disproportionation reaction of organo-ditin and -dilead compounds with organic dichalcogenides: an efficient salt-free route to organo-tin and -lead chalcogenides
  作者：Farzad Mirzaei、Li-Biao Han、Masato Tanaka

  DOI：10.1039/b000309n

  日期：——

  Disproportionation of organo-ditin and -dilead compounds (R3M)2 (M = Sn, Pb) with organic dichalcogenides (R′Z)2 (Z = S, Se, Te) is efficiently promoted by room light to produce the corresponding organo-tin and -lead chalcogenides R3MZR′ quantitatively.

  有机二锡和二铅化合物 (R3M)2 (M = Sn, Pb) 与有机二硫代元素 (R′Z)2 (Z = S, Se, Te) 的不成比例反应在室光下高效促进，定量生成相应的有机锡和铅硫化物 R3MZR′。
• Functionally substituted organotin compounds I. Addition of thiols to alkenyltin compounds
  作者：G. Ayrey、R.D. Brasington、R.C. Poller

  DOI：10.1016/s0022-328x(00)86887-4

  日期：1972.2

  3-(Trialkylstannyl)propyl aryl sulphides (R3SnCH2CH2CH2SR′; R = Me, Et, Bu; R′ = Ph, p-tolyl) were prepared by the addition of arenethiols to allyltrialkyltin compounds. Preferential cleavage of the allyl group by the reaction R3SnCH2CHCH2+R′SH→R3SnSR′+CH3CHCH2 occurred when R = R′ = Bu and R = R′ = Ph. Diallyltin dibromide and benzenethiol gave stannous bromide. Mössbauer parameters of the products

  通过将芳硫醇加入烯丙基三烷基锡化合物中来制备3-（三烷基锡烷基）丙基芳基硫化物（R 3 SnCH 2 CH 2 CH 2 SR'； R = Me，Et，Bu; R'= Ph，对甲苯基）。烯丙基的优先裂解由反应r 3 SNCH 2 CHCH 2 + R'SH→R 3 SNSR'+ CH 3 CHCH 2发生时R = R'= Bu和R = R'=苯基。Diallyltin二溴化物和苯硫醇制得溴化亚锡。记录产品的Mössbauer参数。
• Lucas, C. Robert, Canadian Journal of Chemistry, 1986, vol. 64, p. 1758 - 1763
  作者：Lucas, C. Robert

  DOI：——

  日期：——
• Dean, Philip A. W.; Vittal, Jagadese J., Canadian Journal of Chemistry, 1988, vol. 66, p. 2443 - 2451
  作者：Dean, Philip A. W.、Vittal, Jagadese J.

  DOI：——

  日期：——