[1,2,5]thiadiazolo[3,4-f][4,7]phenanthroline 2,2-dioxide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [1,2,5]thiadiazolo[3,4-f][4,7]phenanthroline 2,2-dioxide
• 英文别名: [1,2,5]Thiadiazolo[3,4-f][4,7]phenanthroline 2,2-dioxide
• 化学式: C₁₂H₆N₄O₂S
• 分子量: 270.271
• InChiKey: GQDDDHLKKJDKCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [1,2,5]thiadiazolo[3,4-f][4,7]phenanthroline 2,2-dioxide 以 neat (no solvent, solid phase) 为溶剂， 285.0 ℃ 、1.0 kPa 条件下， 反应 15.0h， 生成 [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline
  参考文献：
  名称：

  New Thiadiazole Dioxide Bridging Ligand with a Stable Radical Form for the Construction of Magnetic Coordination Chains

  摘要：

  A new thiadiazole dioxide-type bridging ligand with the ability to form stable anionic radicals and the ability to chelate two metal centers in a symmetric fashion has been designed, synthesized, and fully characterized. Its paramagnetic potassium salt and an example of a Cu-II coordination chain were also obtained.

  DOI：

  10.1021/cg500906w
• 作为产物：
  描述：

  泛喹酮 在 磺酰胺 作用下， 以 乙醇 为溶剂， 生成 [1,2,5]thiadiazolo[3,4-f][4,7]phenanthroline 2,2-dioxide
  参考文献：
  名称：

  New Thiadiazole Dioxide Bridging Ligand with a Stable Radical Form for the Construction of Magnetic Coordination Chains

  摘要：

  A new thiadiazole dioxide-type bridging ligand with the ability to form stable anionic radicals and the ability to chelate two metal centers in a symmetric fashion has been designed, synthesized, and fully characterized. Its paramagnetic potassium salt and an example of a Cu-II coordination chain were also obtained.

  DOI：

  10.1021/cg500906w