3-(2-hydroxy-2-methylpropyl)cyclohex-2-enone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(2-hydroxy-2-methylpropyl)cyclohex-2-enone
• 英文别名: 3-(2-Hydroxy-2-methyl-propyl)-cyclohex-2-enone；3-(2-hydroxy-2-methylpropyl)cyclohex-2-en-1-one
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: SRBQVOCXOKYAKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  环丙沙星 在 dipotassium peroxodisulfate 、 硫酸 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 0.33h， 生成 油酸 、 三十烷 、 2,3-二氢-1,1,3-三甲基-3-苯基-1H-茚 、 heptyl octyl phthalate 、 3-methyl-2-propionylbenzoic acid 、 3-(2-hydroxy-2-methylpropyl)cyclohex-2-enone 、 N,N-二甲基甲酰胺 、 氯苯
  参考文献：
  名称：

  Photocatalytic degradation of ciprofloxacin by synthesized TiO2 nanoparticles on montmorillonite: Effect of operation parameters and artificial neural network modeling

  摘要：

  TiO2/MMT nanocomposite was synthesized and characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Energy-dispersive Xray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray fluorescence (XRF) and Brunauer-Emmett-Teller (BET) techniques. The average size of TiO2 nanoparticles was decreased from 60-80 nm to 40-60nm through the immobilization on MMT. The main influential factors such as the TiO2/MMT dose, ciprofloxacin (CIP) concentration, pH of the solution, UV light regions, reusability of the catalyst and electrical energy determination were studied. The addition of radical scavengers (e.g. chloride, iodide, sulfate and bicarbonate) and enhancers (e.g. hydrogen peroxide, potassium iodate and peroxydisulfate) on the degradation efficiency was studied. The predicted data from the designed artificial neural network model were found to be in a good agreement with the experimental data (R-2=0.9864). The main intermediates of CIP degradation were determined by GC-Mass spectrometry. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2015.08.020

文献信息

• Photocatalytic degradation of ciprofloxacin by synthesized TiO2 nanoparticles on montmorillonite: Effect of operation parameters and artificial neural network modeling
  作者：Aydin Hassani、Alireza Khataee、Semra Karaca

  DOI：10.1016/j.molcata.2015.08.020

  日期：2015.12

  TiO2/MMT nanocomposite was synthesized and characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Energy-dispersive Xray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray fluorescence (XRF) and Brunauer-Emmett-Teller (BET) techniques. The average size of TiO2 nanoparticles was decreased from 60-80 nm to 40-60nm through the immobilization on MMT. The main influential factors such as the TiO2/MMT dose, ciprofloxacin (CIP) concentration, pH of the solution, UV light regions, reusability of the catalyst and electrical energy determination were studied. The addition of radical scavengers (e.g. chloride, iodide, sulfate and bicarbonate) and enhancers (e.g. hydrogen peroxide, potassium iodate and peroxydisulfate) on the degradation efficiency was studied. The predicted data from the designed artificial neural network model were found to be in a good agreement with the experimental data (R-2=0.9864). The main intermediates of CIP degradation were determined by GC-Mass spectrometry. (C) 2015 Elsevier B.V. All rights reserved.