过氧化氢对薄荷烷 | 80-47-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 过氧化氢对薄荷烷
• 中文别名: 过氧化氢对孟烷；對過氧化蓋烷；对孟烷-8-过氧化氢；萜烷过氧化氢；PMPH
• 英文名称: p-Menthan-hydroperoxid
• 英文别名: p-Menthane hydroperoxide；1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane
• CAS: 80-47-7
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: XSZYESUNPWGWFQ-UHFFFAOYSA-N

物化性质

• 沸点：
  242.6°C (rough estimate)
• 密度：
  0.9224 (rough estimate)
• 物理描述：
  P-menthane hydroperoxide is a clear pale yellow viscous liquid. (NTP, 1992)
• 闪点：
  127 °F (NTP, 1992)
• 溶解度：
  less than 0.1 mg/mL at 63° F (NTP, 1992)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 危险等级：
  5.2
• 危险类别码：
  R7
• 包装等级：
  II
• 危险类别：
  5.2

制备方法与用途

类别：氧化剂

爆炸物危险特性

• 与还原剂、硫、磷等混合可引发爆炸；
• 干燥或受热时易爆，撞击也会导致爆炸。

可燃性危险特性

• 易燃；
• 遇到还原剂、铵盐、有机物、酸类或易燃物质时混合易燃。

储运特性

• 应存放在通风良好且低温干燥的库房中；
• 与有机物、还原物、易燃物及强酸等分开存放，以确保安全。

灭火剂

• 可使用雾状水、砂土或二氧化碳进行扑灭。

文献信息

• Method of stabilizing trichloroethane during production
  申请人：——

  公开号：US20040030203A1

  公开（公告）日：2004-02-12

  Trichloroethane, e.g., 1,1,1-trichloroethane, is stabilized during processing at temperatures at which it is susceptible to thermal decomposition by conducting such processing in the presence of a stabilizing amount of a stable free radical stabilizer, e.g., a material having a 2,2,6,6-tetra(lower alkyl)-1-piperidinyloxy-yl free radical group such as 2,2,6,6-tetramethyl-4-hydroxy-1-piperidinyloxy.

  三氯乙烷，例如1,1,1-三氯乙烷，在加工过程中稳定在容易热分解的温度下，通过在存在稳定自由基稳定剂的情况下进行处理来实现稳定，例如，具有2,2,6,6-四(较低烷基)-1-哌啶氧自由基团的材料，如2,2,6,6-四甲基-4-羟基-1-哌啶氧自由基。
• Method for recovering trans-1,2-dichloroethene
  申请人：Graybill S. Clark

  公开号：US20050245775A1

  公开（公告）日：2005-11-03

  Describes a method for recovering trans-1,2-dichloroethene from a liquid feed composition comprising both the cis- and trans-isomers of 1,2-dichloroethene and contaminating amounts of other chlorinated hydrocarbons, e.g., lower alkyl chlorinated hydrocarbons, such as C 1- C 2 chlorinated hydrocarbons. In one of the described methods, the liquid feed composition is introduced into a first distillation column 10 wherein the stereoisomers and chlorinated hydrocarbons more volatile than the stereoisomers are removed as overhead 12 and charged to a second distillation column 20 . In column 20 , the stereoisomers are separated from the more volatile chlorinated hydrocarbons, and a bottoms fraction 24 comprising the stereoisomers are charged to a reaction distillation column 30 wherein the cis-isomer, is isomerized to the trans-isomer in the liquid phase and in the presence of an organic free-radical initiator, e.g., an azonitrile initiator. Substantially pure trans-1;2-dichloroethene is recovered as overhead 32 from reaction distillation column 30.

  描述了一种从液体进料中回收trans-1,2-二氯乙烯的方法，该液体进料包括1,2-二氯乙烯的顺反异构体和其他氯化碳氢化合物的污染物，例如低碳烷基氯化碳氢化合物，如C1-C2氯化碳氢化合物。在其中一种描述的方法中，将液体进料引入第一蒸馏柱10中，其中立体异构体和比立体异构体更挥发的氯化碳氢化合物作为顶部12去除并充入第二蒸馏柱20中。在柱20中，立体异构体与更挥发的氯化碳氢化合物分离，底部馏分24包括立体异构体，被充入反应蒸馏柱30中，在液相和有机自由基引发剂的存在下，例如偶氮腈引发剂中，顺异构体异构为反异构体。从反应蒸馏柱30中以过头气体32的形式回收基本纯的trans-1,2-二氯乙烯。
• Improved polymer composition and process for the preparation thereof
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1388547A1

  公开（公告）日：2004-02-11

  An aqueous composition including a polymer having polymerized ethylenically unsaturated acid monomer is disclosed. The aqueous composition is prepared in the presence of select organic compounds. As provided is a process to prepare the aqueous composition. The aqueous composition is useful as a dispersant for inorganic particles, a thickener or rheology modifiers for various aqueous formulations, and as a dispersing resin.

  本发明公开了一种水性组合物，其中包括具有聚合乙烯基不饱和酸单体的聚合物。这种水性组合物是在有选择的有机化合物存在的情况下制备的。本发明还提供了一种制备水性组合物的工艺。该水性组合物可用作无机颗粒的分散剂、各种水性配方的增稠剂或流变修饰剂以及分散树脂。
• Aqueous polymer composition and coating produced therefrom
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1473311A1

  公开（公告）日：2004-11-03

  An aqueous polymer composition including a plurality of comb copolymer particles is disclosed. The comb copolymer particles contain comb copolymer having a polymer backbone with at least one attached graft segment. The polymer backbone and the at least one graft segment have select compositional ranges and select glass transition temperature ranges. Further, the comb copolymer contains as a polymerized unit at least one select monomer such as, aldehyde reactive group-containing monomer or certain styrenic monomers. The aqueous polymer composition of the present invention is useful for preparing coatings having one or more improved properties such as dirt pickup resistance, gloss, gloss retention, alkyd adhesion, and tint retention. A method for forming a coated substrate from the aqueous polymer composition of this invention is also provided.

  本发明公开了一种含水聚合物组合物，其中包括多个梳状共聚物颗粒。梳状共聚物颗粒含有梳状共聚物，梳状共聚物具有聚合物骨架和至少一个连接接枝段。聚合物骨架和至少一个接枝段具有选定的组成范围和选定的玻璃化转变温度范围。此外，梳状共聚物含有至少一种选择性单体作为聚合单元，例如含醛活性基团的单体或某些苯乙烯类单体。本发明的含水聚合物组合物可用于制备具有一种或多种改良特性的涂料，例如耐污性、光泽度、光泽保持力、醇酸树脂附着力和色调保持力。此外，还提供了一种用本发明的水性聚合物组合物形成涂层基材的方法。
• FILM, MULTILAYER BODY, SEMICONDUCTOR WAFER WITH FILM LAYER, SUBSTRATE FOR MOUNTING SEMICONDUCTOR WITH FILM LAYER, AND SEMICONDUCTOR DEVICE
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP3991969A1

  公开（公告）日：2022-05-04

  The present invention provides a film containing: a compound (A) containing at least one selected from the group consisting of a maleimide compound and a citraconimide compound; an organic peroxide (B) containing at least one selected from the group consisting of organic peroxides represented by specific formulae; and an imidazole compound (C) represented by a specific formula.

  本发明提供了一种薄膜，其中含有：至少一种选自由马来酰亚胺化合物和柠康酰亚胺化合物组成的组的化合物（A）；至少一种选自由以特定公式表示的有机过氧化物组成的组的有机过氧化物（B）；以及一种以特定公式表示的咪唑化合物（C）。