S-methyl-O-<3-(3,7-dimethyl-1,6-octadienyl)>dithiocarbonate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: S-methyl-O-<3-(3,7-dimethyl-1,6-octadienyl)>dithiocarbonate
• 英文别名: O-(3,7-dimethylocta-1,6-dien-3-yl) methylsulfanylmethanethioate
• 化学式: C₁₂H₂₀OS₂
• 分子量: 244.422
• InChiKey: LSJUJCMJBMQDCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二硫化碳 、 芳樟醇 、 碘甲烷 在 aluminum oxide 、 potassium fluoride 作用下， 生成 S-methyl-O-<3-(3,7-dimethyl-1,6-octadienyl)>dithiocarbonate
  参考文献：
  名称：

  Potassium Fluoride on Alumina: One-Pot Synthesis of S-Allyl-S-Methyldithiocarbonates by Tandem Condensation-Alkylation-Sigmatropic Rearrangement

  摘要：

  Allyl alcohols adsorbed on Al2O3-KF at room temperature reacted with carbon disulfide and iodomethane and gave S-allyl-S-methyldithiocarbonate. Linalool did not give a rearrangement product. With chrysanthemyl alcohol, opening of the cyclopropane ring was observed.

  DOI：

  10.1080/00397919508011788

文献信息

• Potassium Fluoride on Alumina: One-Pot Synthesis of S-Allyl-S-Methyldithiocarbonates by Tandem Condensation-Alkylation-Sigmatropic Rearrangement
  作者：Didier Villemin、Messaoud Hachemi

  DOI：10.1080/00397919508011788

  日期：1995.8

  Allyl alcohols adsorbed on Al2O3-KF at room temperature reacted with carbon disulfide and iodomethane and gave S-allyl-S-methyldithiocarbonate. Linalool did not give a rearrangement product. With chrysanthemyl alcohol, opening of the cyclopropane ring was observed.