pentadeca-1,14-diene-8-one

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: pentadeca-1,14-diene-8-one
• 英文别名: pentadeca-1,14-dien-8-one
• 化学式: C₁₅H₂₆O
• 分子量: 222.371
• InChiKey: PKBFMMPUTWEGQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-己烯-1-醇 、 丙酮 在 [Cp*₂Ir₂(μ-N,N′-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)oxalamidato)Cl₂] 、 calcium hydroxide 作用下， 120.0 ℃ 、300.01 kPa 条件下， 反应 15.0h， 以79%的产率得到8-壬烯-2-酮
  参考文献：
  名称：

  Ir-oxalamidato /固体碱催化剂体系介导的醇与酮的高效α-烷基化

  摘要：

  Ir-草胺酰胺配合物与固体碱（例如，铝硅酸镁/ Ca（OH）2）结合可显着提高甲基酮与伯醇的α-烷基化反应的催化剂生产率。通过系统改变草酰胺的配体而进行的优化导致实际营业额（TON）为10,000至40,000。

  DOI：

  10.1021/acs.oprd.0c00362

文献信息

• Process for producing a copolymer of a non-polar olefin and a polar olefin and the copolymer obtained thereby
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1170308A2

  公开（公告）日：2002-01-09

  A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M' is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is -O-, -Si-, -Se-, -N(R6)-, n is a number satisfying a valence of M', R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

  一种生产极性烯烃共聚物的工艺，包括在选自元素周期表第 4、5、6 和 11 族的过渡金属化合物存在下，使非极性烯烃和极性烯烃共聚，该过渡金属化合物由下式(IV)表示： 其中 M' 是选自元素周期表第 4、5、6 和 11 族的过渡金属原子，m 是 1 至 6 的整数，A 是-O-、-Si-、-Se-、-N(R6)-，n 是满足 M' 的价数，R1 至 R4 和 R6 各为氢原子、卤素原子、烃基等、X 是卤素原子、氧原子、烃基等，以及至少一种选自有机金属化合物（B-1）、有机铝氧 化物（B-2）和离子电离化合物（B-3）的化合物（B）。因此，该工艺能够在温和的聚合条件下获得性能优异的极性烯烃共聚物。
• Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
  申请人：——

  公开号：US20020099155A1

  公开（公告）日：2002-07-25

  A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): 1 wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R 6 )—, n is a number satisfying a valence of M′, R 1 to R 4 and R 6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

  一种生产极性烯烃共聚物的工艺，包括在选自元素周期表第 4、5、6 和 11 族的过渡金属化合物存在下，使非极性烯烃和极性烯烃共聚，过渡金属化合物用下式（IV）表示： 1 其中 M′为选自元素周期表第 4、5、6 和 11 族的过渡金属原子，m 为 1 至 6 的整数，A 为-O-、-Si-、-Se-、-N(R 6 )-，n 是满足 M′化合价的数字，R 1 至 R 4 和 R 6 各为氢原子、卤素原子、烃基等，X 为卤素原子、氧原子、烃基等，以及至少一种选自有机金属化合物 (B-1)、有机铝氧化合物 (B-2) 和离子离子化合物 (B-3) 组的化合物 (B)。因此，该工艺能够在温和的聚合条件下获得性能优异的极性烯烃共聚物。
• Process for producing a copolymer of a non-polar olefin and a polar olefin
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1170308B1

  公开（公告）日：2015-05-06
• BLOOD SIMULANT FOR SIMULATOIN-BASED MEDICAL TRAUMA TRAINING
  申请人：Grinevich Oleg

  公开号：US20150140537A1

  公开（公告）日：2015-05-21

  A non-biological simulant liquid that includes about 30 to about 95 parts by weight of a polymer dispersion or a wax emulsion or dispersion, about 5 to about 70 parts by weight of a rheology modifying agent, and a pigment or a pigment combination. The non-biological simulant has a viscosity that is shear-dependent, such that the viscosity is from about 30 cP to about 300 cP at a shear rate from 0 s −1 to about 10 s −1 , and such that the viscosity decreases when the shear rate increases. The pigment or pigment combination imbues the non-biological simulant with a color that approximates that of human or animal arterial or venous blood.
• US3932573A
  申请人：——

  公开号：US3932573A

  公开（公告）日：1976-01-13