N-(n-dodecyl)-4-methylquinolinium bromide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: N-(n-dodecyl)-4-methylquinolinium bromide
• 英文别名: 1-Dodecyl-4-methylquinolin-1-ium;bromide
• 化学式: Br*C₂₂H₃₄N
• 分子量: 392.423
• InChiKey: VWVPGNMREBDIBC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.36
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-[(3-(苯胺基亚甲基)-2-氯-1-环己烯-1-基)亚甲基]苯胺盐酸盐 、 N-(n-dodecyl)-4-methylquinolinium bromide 在 sodium acetate 作用下， 以 乙醇 为溶剂， 反应 12.0h， 以87%的产率得到
  参考文献：
  名称：

  一种喹啉七甲川菁染料的制备方法

  摘要：

  本发明涉及一种近红外喹啉类七甲川菁染料及其制备方法，属于化工有机染料合成领域。合成的近红外染料具有优良的光学性能，如处于近红外二区，化合物斯托克斯位移大，光稳定性强，合成步骤短，提纯方便等优点。该类染料最明显的特性是在近红外二区具有较强的吸收，对环境、生物组织均具有优良的穿透性，在有机溶剂如二氯甲烷中具有很高的量子产率。可用于生物分子标记，荧光成像等领域。该探针制备方法简单易行，成本低，经济效益好，适用于工业化生产。

  公开号：

  CN108410202A
• 作为产物：
  描述：

  4-甲基喹啉 、 溴代十二烷 以 乙腈 为溶剂， 反应 6.0h， 以95%的产率得到N-(n-dodecyl)-4-methylquinolinium bromide
  参考文献：
  名称：

  一种喹啉七甲川菁染料的制备方法

  摘要：

  本发明涉及一种近红外喹啉类七甲川菁染料及其制备方法，属于化工有机染料合成领域。合成的近红外染料具有优良的光学性能，如处于近红外二区，化合物斯托克斯位移大，光稳定性强，合成步骤短，提纯方便等优点。该类染料最明显的特性是在近红外二区具有较强的吸收，对环境、生物组织均具有优良的穿透性，在有机溶剂如二氯甲烷中具有很高的量子产率。可用于生物分子标记，荧光成像等领域。该探针制备方法简单易行，成本低，经济效益好，适用于工业化生产。

  公开号：

  CN108410202A

文献信息

• Synthesis and Surface and Antimicrobial Properties of Novel Cationic Surfactants
  作者：Guido Viscardi、Pierluigi Quagliotto、Claudia Barolo、Piero Savarino、Ermanno Barni、Emilia Fisicaro

  DOI：10.1021/jo0006425

  日期：2000.12.1

  A series of surfactants with tuned polarity were prepared, including a new class of compounds: gluco-pyridinium: surfactants. Pure anomers were obtained by chromatographic separation. The conductivity and surface tension of surfactant solutions in water were measured, and-provided interesting information regarding their aggregation behavior. Peculiarities were observed,in the premicellar range. Tensidic parameters correlated with antimicrobial activity. A few parameters, mainly the hydrophobicity of the headgroup, may play a role in finding more efficient antimicrobial structures.
• Controlling the structure of transparent Langmuir–Blodgett films for nonlinear optical applications
  作者：Geoffrey J. Ashwell、Paul D. Jackson、Gary Jefferies、Ian R. Gentle、Colin H. L. Kennard

  DOI：10.1039/jm9960600137

  日期：——

  Langmuir-Blodgett (LB) multilayers of (E)-N-alkyl-4-[2-(4-docosyloxyphenyl)ethenyl]pyridinium bromide, CBH2n+1-Py(+)-CH=CH-C6H4-O-C22H45Br- (dye I), are centrosymmetric (Y-type) for n less than or equal to 6 and non-centrosymmetric (Z-type) for 8 less than or equal to n less than or equal to 20. The areas obtained from grazing incidence synchrotron X-ray diffraction indicate that the molecules adopt a 'stretched' rather than a 'U-shaped' configuration and, unlike conventional amphiphilic materials, the long chain homologues do not invert during deposition. The second-harmonic intensity from films of the higher homologues (n greater than or equal to 10) increases quadratically with the number of LB layers (I-2 omega(N) = I-2 omega(1)N-2) whereas for the lower homologues (n less than or equal to 6) the intensity is negligible for even numbers of layers. The nonlinear optical properties of the sulfur (dye II), selenium (dye III) and quinolinium (dye TV) analogues are also reported and, in each case, quadratic enhancement of the second-harmonic intensity has been observed for suitable combinations of alkyl chain lengths. The second-order susceptibility, chi((2))(zzz), of a 100 layer LB film of (E)-N-dodecyl-4-[2-(4-docosyloxyphenyl)ethenyl] quinolinium bromide (dye IV) is 20 pm V-1.