1,6-dimethyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,6-dimethyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde
• 英文别名: 1,6-dimethyl-4-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde
• 化学式: C₁₅H₂₄O
• 分子量: 220.355
• InChiKey: INBWJYBPNUSPTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  ethylaluminium dichloride 、 反式-2-甲基-2-丁烯醛 、 月桂烯 以 水 、 苯 为溶剂， 生成 1,6-dimethyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde
  参考文献：
  名称：

  Bridged ketones and process for preparing same

  摘要：

  描述的是由通用结构涵盖的化合物；##STR1## 其中R.sub.1、R.sub.2和R.sub.3中的一个、两个或全部相同或不同，每个代表1至3个碳原子的氢或较低的烷基；使用具有通用结构的化合物制备同样的过程；##STR2## 其中虚线之一是碳-碳双键，另一条虚线代表碳-碳单键，以及其在香水、古龙水、香水制品（如阴离子、阳离子和非离子洗涤剂、化妆粉和添加到干衣机的织物柔顺剂制品中的有机感官用途，以及在吸烟烟草和吸烟烟草制品（例如吸烟烟草的主体、包装纸或其过滤器）中的应用。因此，我们的发明的三环酮化合物具有通用结构：##STR3## 在香水组合物、香水制品或古龙水中赋予、增强或增加低调的油腻、木质、琥珀、皮革、温暖的香料、土腥樟脑、廉价香树脂、绿色、豆蔻样、岩兰草样、甜木质或薄荷样的微妙气味。我们发明的三环酮进一步增强、增加或赋予甜美、花香、木质、辛辣、皮革和琥珀香气的气味特征于吸烟烟草在吸烟前以及在主流和副流中的天然烟草口味和香气。

  公开号：

  US04250338A1

文献信息

• Process for augmenting or enhancing the aroma or taste of smoking
  申请人：International Flavors & Fragrances Inc.

  公开号：US04909854A1

  公开（公告）日：1990-03-20

  Described for use in augmenting or enhancing the aroma or taste of smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor in a cigarette or cigar, or the whole cigarette or cigar itself are compounds defined according to the generic structure: ##STR1## wherein R.sub.1 represents hydrogen, methyl or acetyl and wherein R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent the same or different hydrogen, methyl or ethyl.

  该化合物用于增强或提高吸烟烟草和吸烟烟草制品的香味或口感，例如吸烟烟草的主体、香烟或雪茄的包装纸或过滤器，或整支香烟或雪茄本身。该化合物的通用结构如下：##STR1## 其中R.sub.1代表氢、甲基或乙酰基，R.sub.2、R.sub.3、R.sub.4和R.sub.5代表相同或不同的氢、甲基或乙基。
• Tricyclic alcohols, ethers and esters, process for preparing same and
  申请人：International Flavors & Fragrances Inc.

  公开号：US04439354A1

  公开（公告）日：1984-03-27

  Described are compounds having the generic structure: ##STR1## wherein R.sub.1 represents hydrogen, methyl or acetyl and wherein R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent the same or different hydrogen, methyl or ethyl; a process for preparing same using compounds designed according to the generic structure: ##STR2## and organoleptic uses thereof in perfumes, colognes and perfumed articles.

  描述了具有通用结构的化合物：##STR1##其中R.sub.1代表氢，甲基或乙酰基，R.sub.2，R.sub.3，R.sub.4和R.sub.5代表相同或不同的氢，甲基或乙基; 使用根据通用结构设计的化合物：##STR2##制备它们的过程以及它们在香水，古龙水和带香味的物品中的有机感官用途。
• Rubus plant named ‘BWPRASP01’
  申请人：Berryworld Plus Limited

  公开号：USPP032721P2

  公开（公告）日：2021-01-05

  A new cultivar of Rubus idaeus hybrid plant named ‘BWPRASP01’ that is characterized by its fruit production on primocanes, its consistently large fruit that are light red in color, its consistent fruit quality throughout the cropping season, its extended shelf life, its easy picking as there is low adherence to the plug and easily accessible through the canopy, its early fruit production, its firm fruit with low acidity, and its versatile cropping schedule as it can be established on different planting dates throughout summer to maintain cropping in autumn and winter in Spain.

  一种新的覆盆子杂交植物品种命名为“BWPRASP01”，其特点是在初生枝上结出果实，果实始终呈浅红色且大小一致，果实品质在整个采摘季节内保持一致，具有较长的货架寿命，易于采摘，因为果实与插头之间的附着力较低且易于通过树冠访问，果实早期产量高，果实坚实且酸度低，并且其多功能的采摘时间表，可在夏季的不同种植日期上建立，以在西班牙的秋季和冬季保持连续采摘。
• Process for using bridged ketones in augmenting or enhancing the
  申请人：International Flavors & Fragrances Inc.

  公开号：US04293453A1

  公开（公告）日：1981-10-06

  Described are compounds covered by the generic structure: ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure: ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.

  本文描述的是一类化合物，其通用结构为：##STR1## 其中R.sub.1，R.sub.2和R.sub.3中的一个，两个或全部相同或不同，每个表示1至3个碳原子的氢或低碳基；使用具有通用结构的化合物制备它们的过程为：##STR2## 其中虚线之一是碳-碳双键，另一条虚线表示碳-碳单键，并且它们在香水、古龙香水、香味物品（例如阴离子、阳离子和非离子洗涤剂、化妆品粉末和加入干衣机的柔软剂物品）以及吸烟烟草和吸烟烟草产品（例如吸烟烟草的主体、包装或过滤器）中具有感官用途。因此，本发明的三环酮化合物具有通用结构：##STR3## 在香水、香味物品或古龙香水中增强或增强了低调的油腻、木质、琥珀、皮革、温暖的香料、泥土松香、延胡索、香膏、绿色、豆蔻、香根草、甜木质或薄荷气息。本发明的三环酮进一步增强、增强或赋予吸烟烟草甜美、花香、木质、香辣、皮革和琥珀香气，在吸烟前呈现天然烟草味和香气，在主流和侧流中呈现甜美的香气和天然烟草味和香气的气息。
• Use of certain bridged ketones in augmenting or enhancing the
  申请人：International Flavors & Fragrances Inc.

  公开号：US04285349A1

  公开（公告）日：1981-08-25

  Described in a process for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of adding to a smoking tobacco an aroma or taste augmenting or enhancing quantity of at least one tricyclic ketone having the structure: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl.

  描述了一种增强或提高烟草香味或口感的过程，其中步骤包括向烟草中添加至少一种三环酮，其结构具有以下式子：##STR1## 其中R.sub.1，R.sub.2和R.sub.3相同或不同，每个代表氢或C.sub.1-C.sub.3低碳基。