2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-3-butenoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-3-butenoate
• 英文别名: (5-Methyl-2-prop-1-en-2-ylhex-4-enyl) 3-methylbut-3-enoate；(5-methyl-2-prop-1-en-2-ylhex-4-enyl) 3-methylbut-3-enoate
• 化学式: C₁₅H₂₄O₂
• 分子量: 236.354
• InChiKey: WYWNGFBLJJWITG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-甲基巴豆酰氯 、 拉凡醇; 5-甲基-2-(1-甲基乙烯基)-4-己烯-1-醇 在 4-二甲氨基吡啶 作用下， 以 乙醚 为溶剂， 生成 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-3-butenoate
  参考文献：
  名称：

  Identification and synthesis of the sex pheromone of the vine mealybug, Planococcus ficus

  摘要：

  Sexually mature females of an important agricultural pest, the vine mealybug Planococcus ficus, produce the monoterpene (S)-lavandulol and the corresponding ester, (S)-(+)-lavandulyl senecioate. The racemic ester was highly attractive to mature male mealybugs, whereas lavandulol was not. The naturally produced 2:5 blend of lavandulol and the ester also was no more attractive than the ester alone. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)02347-9

文献信息

• METHOD FOR PRODUCING 2-ISOPROPENYL-5-METHYL-4-HEXEN-1-YL 3-METHYL-2-BUTENOATE
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20160152544A1

  公开（公告）日：2016-06-02

  Provided is a method for industrially producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate, which is, for example, a sex pheromone substance of vine mealybug. More specifically, there is provided a method for producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate, comprising a step of transesterifying 2-isopropenyl-5-methyl-4-hexen-1-ol represented by Formula (1) with alkyl senecioate represented by General Formula (2) in the presence of a catalyst, while distilling off an alcohol represented by General Formula (4) formed as a by-product, to obtain 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by Formula (3).

  提供了一种用于工业生产2-异丙烯基-5-甲基-4-己烯-1-基 3-甲基-2-丁烯酸酯的方法，该物质例如是葡萄藤粉虱的性信息素。更具体地，提供了一种生产2-异丙烯基-5-甲基-4-己烯-1-基 3-甲基-2-丁烯酸酯的方法，包括在催化剂存在下，通过将通式（1）表示的2-异丙烯基-5-甲基-4-己烯-1-醇与通式（2）表示的烷基塞内酸酯进行酯交换反应的步骤，同时蒸馏掉作为副产物形成的通式（4）表示的醇，以获得通式（3）表示的2-异丙烯基-5-甲基-4-己烯-1-基 3-甲基-2-丁烯酸酯。
• [EN] METHOD OF MONITORING AND/OR CONTROLLING THYSANOPTERA<br/>[FR] PROCÉDÉ DE SURVEILLANCE ET/OU DE LUTTE CONTRE LES THYSANOPTÈRES
  申请人：UNIV KEELE

  公开号：WO2014068303A1

  公开（公告）日：2014-05-08

  The present invention provides a method of monitoring or controlling Thysanoptera (hereafter thrips) using a behaviour-modifying compound of Formula (1), wherein Formula (1) is: where R1 is a C2-C8 straight or branched alkenyl group and the * denotes a stereocentre. Suitably, the method involves providing the behaviour-modifying compound at a pre- determined location. Typically the behaviour-modifying compound is released or broadcast within an area infested (or potentially infested) by thrips. This can be achieved by using a lure or other release device comprising a compound of Formula (1), for example to attract the thrips to a trap.

  本发明提供了一种使用具有公式（1）的行为改变化合物监测或控制刺管目昆虫（以下简称蓟马）的方法，其中公式（1）为：其中R1是C2-C8的直链或支链烯基基团，*表示立体中心。适当地，该方法涉及在预定位置提供行为改变化合物。通常，行为改变化合物在蓟马受到感染（或可能受到感染）的区域内释放或广播。这可以通过使用包含公式（1）化合物的诱饵或其他释放装置来实现，例如吸引蓟马到陷阱中。
• METHOD OF MONITORING AND/OR CONTROLLING THYSANOPTERA
  申请人：Keele University

  公开号：EP2914572A1

  公开（公告）日：2015-09-09
• US9738587B2
  申请人：——

  公开号：US9738587B2

  公开（公告）日：2017-08-22
• Identification and synthesis of the sex pheromone of the vine mealybug, Planococcus ficus
  作者：Diane M Hinkens、J.Steven McElfresh、Jocelyn G Millar

  DOI：10.1016/s0040-4039(00)02347-9

  日期：2001.2

  Sexually mature females of an important agricultural pest, the vine mealybug Planococcus ficus, produce the monoterpene (S)-lavandulol and the corresponding ester, (S)-(+)-lavandulyl senecioate. The racemic ester was highly attractive to mature male mealybugs, whereas lavandulol was not. The naturally produced 2:5 blend of lavandulol and the ester also was no more attractive than the ester alone. (C) 2001 Elsevier Science Ltd. All rights reserved.