1,1,2,2-四氢全氟壬基碘化物 | 2043-52-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 中文名称: 1,1,2,2-四氢全氟壬基碘化物
• 英文名称: 1.1.1.2.2.3.3.4.4.5.5.6.6.7.7-Pentadecafluor-9-iod-nonan
• 英文别名: 1,1,2,2-Tetrahydro-1-iodperfluornonan；1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentadecafluoro-9-iodononane；1,1,2,2-tetrahydroperfluorononyl iodide
• CAS: 2043-52-9
• 化学式: C₉H₄F₁₅I
• 分子量: 524.011
• InChiKey: QVTHRDRXTVTNEK-UHFFFAOYSA-N

物化性质

• 熔点：
  42-44 °C
• 沸点：
  73 °C(Press: 8 Torr)
• 密度：
  1.885±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  15

安全信息

• 危险品标志：
  Xi
• 海关编码：
  2903799090

反应信息

• 作为反应物：
  描述：

  1,1,2,2-四氢全氟壬基碘化物 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成 3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-十五氟-1-壬烯
  参考文献：
  名称：

  Effect of a perfluoroalkyl group on the elimination and substitution reactions of two homologous series of perfluoroalkyl-substituted iodoalkanes

  摘要：

  DOI：

  10.1021/jo00187a012

文献信息

• Radical Addition of Perfluoroalkyl Iodides to Alkenes and Alkynes Initiated by Sodium Dithionite in an Aqueous Solution in the Presence of a Novel Fluorosurfactant
  作者：Zhiwei Xiao、Huawei Hu、Jiaoli Ma、Qingyun Chen、Yong Guo

  DOI：10.1002/cjoc.201300433

  日期：2013.7

  fluoroalkylation to occur in the water without adding organic solvent. The addition of perfluoroalkyl iodides with olefins and alkynes under the initiation of Na2S2O4 in water in the presence of the fluorosurfactant gave the corresponding adducts in good to excellent yields. The fluorosurfactant was suitable for a radical addition process.

  制备并表征了一种新型的氟化阴离子表面活性剂Cl（CF 2）6 O（CF 2）2 SO 3 N（C 2 H 5）4。含氟表面活性剂的应用使氟烷基化在水中发生而无需添加有机溶剂。在含氟表面活性剂的存在下，在水中在Na 2 S 2 O 4的引发下，将全氟烷基碘化物与烯烃和炔烃加成，得到相应的加合物，收率良好或优异。含氟表面活性剂适用于自由基加成过程。
• Perfluorinated esters of fumaric acid and certain other ethylenically
  申请人：Geigy Chemical Corporation

  公开号：US04075237A1

  公开（公告）日：1978-02-21

  Monomeric esters of fumaric, maleic, citraconic, mesaconic, itaconic, aconitic, or methylene malonic acid and alcohols of the formula C.sub.m F2.sub.m+1 C.sub.n H2.sub.n OH and mercaptans of the formula C.sub.m F2.sub.m+1 C.sub.n H2.sub.n SH form homopolymers and form copolymers with other ethylenically unsaturated comonomers. The polymers obtained have valuable soil repellent properties and are especially useful in textile finishes. Preferred compounds are bis (1,1,2,2-tetrahydroperfluorononyl) fumarate and bis (1,1-dihydroperfluorooctyl) fumarate.

  富马酸单体酯，马来酸单体酯，柠檬酸单体酯，美沙酸单体酯，顺丁烯二酸单体酯，顶酸单体酯，或甲基丙烯二酸单体酯与C.sub.m F2.sub.m+1 C.sub.n H2.sub.n OH的醇或C.sub.m F2.sub.m+1 C.sub.n H2.sub.n SH的巯基形成同聚物，并与其他乙烯基不饱和共聚单体形成共聚物。所得到的聚合物具有有价值的防污性能，在纺织品整理中特别有用。首选化合物为双(1,1,2,2-四氢过氟壬酰基)富马酸酯和双(1,1-二氢过氟辛酰基)富马酸酯。
• Perfluoroalkyl alcohols
  申请人：Ciba-Geigy Corporation

  公开号：US03965148A1

  公开（公告）日：1976-06-22

  Perfluoroalkyl group containing alcohols are disclosed with utility as intermediates for the synthesis of oil and water repellent fluorochemicals. The alcohols are obtained by the addition of mercaptoalcohols to perfluoroalkyl group containing esters of fumaric, maleic, citraconic, mesaconic, itaconic, methylene malonic or aconitic acids.

  公开了含有全氟烷基的醇，其作为合成油和水疏水氟化化学品的中间体具有实用性。这些醇是通过将巯基醇加入富马酸、马来酸、柠檬酸、梅萨康酸、顺丁烯二酸、甲基丙烯酸甲酯基丙酸或顺柿酸酯的全氟烷基中获得的。
• Process for preparing fluorine-containing carboxylic acid ester
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0252736B1

  公开（公告）日：1991-07-24
• BRACE, N. O.;MARSHALL, L. W.;PINSON, C. J.;VAN, WINGERDEN, G., J. ORG. CHEM., 1984, 49, N 13, 2361-2368
  作者：BRACE, N. O.、MARSHALL, L. W.、PINSON, C. J.、VAN, WINGERDEN, G.

  DOI：——

  日期：——