1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二甲桥萘-2-甲醇 | 7329-04-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二甲桥萘-2-甲醇
• 英文名称: 2-Hydroxymethyl-1,2,3,4,4a,5,8,8a-octahydro-1,4,5,8-dimethano-naphthalin
• 英文别名: 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene-2-methanol；octahydrodimethanonaphtalenemethanol；1,4:5,8-Dimethanonaphthalene-2-methanol, 1,2,3,4,4a,5,8,8a-octahydro-；4-tetracyclo[6.2.1.13,6.02,7]dodec-9-enylmethanol
• CAS: 7329-04-6
• 化学式: C₁₃H₁₈O
• 分子量: 190.285
• InChiKey: LLPLOWFYJGZIBV-UHFFFAOYSA-N

物化性质

• 沸点：
  110-122 °C(Press: 0.12 Torr)
• 密度：
  1.0935 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二甲桥萘-2-甲醇 、 烯丙醇 生成 5-降冰片烯-2-甲醇
  参考文献：
  名称：

  SMAGIN, V. M.;STRELCHIK, B. S.;KAMNEVA, S. A., OSN. ORGAN. SINTEZ I NEFTEXIMIYA,(1989) N5, S. 57-61

  摘要：

  DOI：
• 作为产物：
  描述：

  5-降冰片烯-2-甲醇 以35%的产率得到
  参考文献：
  名称：

  SMAGIN, V. M.;STRELCHIK, B. S.;KAMNEVA, S. A., OSN. ORGAN. SINTEZ I NEFTEXIMIYA,(1989) N5, S. 57-61

  摘要：

  DOI：

文献信息

• [EN] PROCESS FOR THE PREPARATION OF HIGH PURITY NORBORNENE ALKANOLS AND DERIVATIVES THEREOF<br/>[FR] PROCÉDÉ POUR LA PRÉPARATION D'ALCANOLS DE NORBORNÈNE DE PURETÉ ÉLEVÉE ET LEURS DÉRIVÉS
  申请人：PROMERUS LLC

  公开号：WO2014099546A1

  公开（公告）日：2014-06-26

  A process for the preparation of a variety of high purity norbornene alkanol monomers and their derivatives is disclosed and claimed. Specifically, a process for the preparation of industrial scale high purity norbornene methanol and its silyl ether derivative is disclosed and claimed. The high purity monomers prepared in accordance with the process of this invention are useful in a variety of applications including but not limited to the preparation of high quality and high purity polynorbornenes having utility in a variety of electronic applications, among various other applications.

  揭示和声明了一种制备各种高纯度的去甲基去氢莰烯烷醇单体及其衍生物的方法。具体地，揭示和声明了一种制备工业规模高纯度的去甲基去氢莰烯甲醇及其硅醚衍生物的方法。根据本发明的工艺制备的高纯度单体可用于各种应用，包括但不限于制备高质量和高纯度的聚去氢莰烯，在各种电子应用以及其他各种应用中具有实用性。
• CYCLIC OLEFIN POLYMER, OPTICAL MATERIAL, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：WATANABE Saisuke

  公开号：US20080299329A1

  公开（公告）日：2008-12-04

  A cyclic olefin polymer is provided and includes a repeating unit represented by formula (1A) and a repeating unit represented by the formula (1B): R 1 and R 3 each independently represents a substituent, L 1 and L 2 each independently represents a single bond or a divalent linking group, m and p each independently represents an integer of 0 or 1, and n and q each independently represents an integer of 1 to 4; and A represents COOR 2 or OCOR 2 , and R 2 represents a linear alkyl group having a carbon number of 1 to 10. The cyclic olefin polymer has a copolymerization ratio of x and y satisfying 0.03≦y/(x+y)≦0.50, a number average molecular weight of from 70,000 to 300,000, and a weight average molecular weight of from 200,000 to 700,000.

  提供了一种环状烯烃聚合物，包括由公式（1A）表示的重复单元和由公式（1B）表示的重复单元：R1和R3各自独立地表示取代基，L1和L2各自独立地表示单键或二价连接基，m和p各自独立地表示0或1的整数，n和q各自独立地表示1到4的整数；A表示COOR2或OCOR2，R2表示具有1到10个碳原子的线性烷基。该环状烯烃聚合物具有x和y的共聚比满足0.03≦y/(x+y)≦0.50，数量平均分子量为70,000至300,000，重量平均分子量为200,000至700,000。
• PROCESS FOR THE PREPARATION OF HIGH PURITY NORBORNENE ALKANOLS AND DERIVATIVES THEREOF
  申请人：PROMERUS, LLC

  公开号：US20160264498A1

  公开（公告）日：2016-09-15

  A process for the preparation of a variety of high purity norbornene alkanol monomers and their derivatives is disclosed and claimed. Specifically, a process for the preparation of industrial scale high purity norbornene methanol and its silyl ether derivative is disclosed and claimed. The high purity monomers prepared in accordance with the process of this invention are useful in a variety of applications including but not limited to the preparation of high quality and high purity polynorbornenes having utility in a variety of electronic applications, among various other applications.

  本发明揭示和声明了一种制备各种高纯度脱环戊二烯烷基醇单体及其衍生物的工艺。具体而言，本发明揭示和声明了一种制备工业规模高纯度脱环戊二烯甲醇及其硅醚衍生物的工艺。根据本发明工艺制备的高纯度单体可用于各种应用，包括但不限于制备在各种电子应用中有用的高质量和高纯度聚脱环戊二烯，以及其他各种应用。
• Process for producing norbornene derivatives
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP1757580B1

  公开（公告）日：2008-06-11
• SMAGIN, V. M.;STRELCHIK, B. S.;KAMNEVA, S. A., OSN. ORGAN. SINTEZ I NEFTEXIMIYA,(1989) N5, S. 57-61
  作者：SMAGIN, V. M.、STRELCHIK, B. S.、KAMNEVA, S. A.

  DOI：——

  日期：——