1-[4-(1-甲基乙基)-1-环戊烯-1-基]-乙酮 | 73011-52-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 1-[4-(1-甲基乙基)-1-环戊烯-1-基]-乙酮
• 英文名称: 4-Isopropyl-1-acetyl-cyclopenten-(1)
• 英文别名: 1-[4-(Propan-2-yl)cyclopent-1-en-1-yl]ethanone；1-(4-propan-2-ylcyclopenten-1-yl)ethanone
• CAS: 73011-52-6
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: MLMAMBFDFHGWBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-[4-(1-甲基乙基)-1-环戊烯-1-基]-乙酮 生成 1-<3-Isopropylcyclopent-1-yl>-ethanol
  参考文献：
  名称：

  KULESZA J.; SIKORA M., 7 INT. CONGR. ESSENTIAL OILS, KYOTO, 1977, S. L., 1979, 272

  摘要：

  DOI：
• 作为产物：
  描述：

  p-menth-1-ene 生成 1-[4-(1-甲基乙基)-1-环戊烯-1-基]-乙酮
  参考文献：
  名称：

  Moulines,J.; Lalande,R., Bulletin de la Societe Chimique de France, 1963, p. 199

  摘要：

  DOI：

文献信息

• Stereoselective Multiple Functionalization of Pyrylium Salts by Domino Reactions with 2-Silyloxybuta-1,3-dienes
  作者：Uwe Beifuss、Kim Goldenstein、Frank Döring、Christopher Lehmann、Mathias Noltemeyer

  DOI：10.1002/1521-3773(20010202)40:3<568::aid-anie568>3.0.co;2-l

  日期：2001.2.2

  Six at a time! Up to six stereogenic centers can be diastereoselectively formed in one step in three-component domino reactions of 4-silyloxypyrylium triflates with 2-silyloxybuta-1,3-dienes. Annulated or bridged ring systems such as 1 and 2, respectively, can be formed with high selectivity. R1 =silyl group; R2 , R3 =organyl group.
• OZONOLYSIS REACTIONS IN LIQUID CO2 AND CO2-EXPANDED SOLVENTS
  申请人：Subramaniam Bala

  公开号：US20090118498A1

  公开（公告）日：2009-05-07

  A method for increasing ozone concentration in a liquid can include: providing a gas having ozone; introducing the ozone-containing gas into a liquid, wherein the liquid and ozone combination has a temperature between about 0.8 and about 1.5 times the critical temperature of ozone; and increasing isothermally, the pressure of the ozone-containing gas above the liquid to about 0.3 to about 5 times the critical pressure of ozone so as to increase the ozone concentration in the liquid. The temperature is expressed in absolute units (Kelvin or Rankin). The method can be used for removing ozone from a gas or for purifying ozone. The liquid having a high ozone concentration can be used for ozonolysis of a substrate.
• Ozonolysis Reactions in Liquid CO2 and CO2-Expanded Solvents
  申请人：UNIVERSITY OF KANSAS

  公开号：US20130240781A1

  公开（公告）日：2013-09-19

  A method for increasing ozone concentration in a liquid can include: providing a gas having ozone; introducing the ozone-containing gas into a liquid, wherein the liquid and ozone combination has a temperature between about 0.8 and about 1.5 times the critical temperature of ozone; and increasing isothermally, the pressure of the ozone-containing gas above the liquid to about 0.3 to about 5 times the critical pressure of ozone so as to increase the ozone concentration in the liquid. The temperature is expressed in absolute units (Kelvin or Rankin). The method can be used for removing ozone from a gas or for purifying ozone. The liquid having a high ozone concentration can be used for ozonolysis of a substrate.
• US8425784B2
  申请人：——

  公开号：US8425784B2

  公开（公告）日：2013-04-23
• US8801939B2
  申请人：——

  公开号：US8801939B2

  公开（公告）日：2014-08-12