1-癸基环己醇 | 104699-86-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-癸基环己醇
• 英文名称: 1-Decyl-cyclohexanol
• 英文别名: 1-Decylcyclohexan-1-ol
• CAS: 104699-86-7
• 化学式: C₁₆H₃₂O
• mdl: MFCD20966838
• 分子量: 240.429
• InChiKey: UKKARDXLNGYDQL-UHFFFAOYSA-N

物化性质

• 沸点：
  169 °C(Press: 5 Torr)
• 密度：
  0.885±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-癸基环己醇 在 chromium(VI) oxide 、 溶剂黄146 作用下， 生成 6-oxohexadecanoic acid
  参考文献：
  名称：

  Keskin, Istanbul Universitesi Fen Fakultesi Mecmuasi, Seri A: Matematik-Fizik-Kimya, 1952, vol. 17, p. 344,346

  摘要：

  DOI：
• 作为产物：
  描述：

  Decylmagnesium bromide 、 环己酮 以 四氢呋喃 为溶剂， 生成 1-癸基环己醇
  参考文献：
  名称：

  利用异羟肟酸作为有机催化剂，以过氧化氢为氧化剂进行烯烃环氧化反应

  摘要：

  提出了一种以异羟肟酸为催化剂、过氧化氢为绿色氧化剂的有机催化环氧化烯烃合成方法。通过直接输注 HRMS 进行的机理研究为各种中间体的形成提供了实验证据。

  DOI：

  10.1002/ejoc.202400082

文献信息

• <i>p</i>-Toluenesulfonic Acid Adsorbed on Silica Gel: An Efficient Dehydrating Agent of Alcohols
  作者：Franco D'Onofrio、Arrigo Scettri

  DOI：10.1055/s-1985-31463

  日期：——

  Secondary and tertiary alcohols are efficiently dehydrated by reaction with p-toluenesulfonic acid supported on silica gel. In particular, the procedure allows the direct conversion of 3-hydroxy-steroids into Δ2-olefins or Δ3,5-dienes, without passing through the mesylate or tosylate esters.

  二级和三级醇通过与负载在硅胶上的对甲苯磺酸反应有效脱水。特别是，该方法允许将3-羟基类固醇直接转化为Δ2-烯烃或Δ3,5-二烯，而无需经过美克酸酯或对甲苯磺酸酯。
• Method for the mechanical working of metals and lubricant concentrate
  申请人：BEROL KEMI AB

  公开号：EP0034132A2

  公开（公告）日：1981-08-19

  During mechanical working, an aqueous lubricant composition is used as a lubricating and cooling agent, which contains an ether phosphate as a lubricating agent. A concentrate suitable for use as a lubricant after dilution with water is also described.

  在机械加工过程中，一种水性润滑剂组合物被用作润滑和冷却剂，其中含有一种作为润滑剂的磷酸醚。此外，还介绍了一种适合用水稀释后用作润滑剂的浓缩物。
• A Transition from Heterogeneous to Homogeneous Nucleation in the Turbulent Mixing CNC
  作者：Rashid Mavliev、Philip K. Hopke、Hwa-Chi Wang、Doh-Won Lee

  DOI：10.1080/02786820119393

  日期：2001.1

  A new method for changing the supersaturation in the Turbulent Mixing CNC has been developed and used to examine the transition from heterogeneous nucleation of test particles to homogenous nucleation of working fluid: dibutylphthlate (DBP). Supersaturation was controlled by changing the DBP vapor pressure in the nozzle flow by saturating only a predetermined part of the flow, while the total flow and temperature remain constant. This approach allows for the changing of the initial DBP vapor pressure, while keeping the flow structure and temperature field unchanged. The DBP concentration in the outlet of the vapor generator was measured experimentally for different ratios of saturated and bypass flows and found to be close to estimated values. Experimental results for transitions from heterogeneous nucleation to homogeneous nucleation are presented for NaCl and WOx particles at various DBP vapor pressures. With an increasing of the DBP vapor pressure, the concentration of enlarged particles increases until it reaches a plateau. At higher initial values of DBP pressure, homogeneous nucleation prevails, and the number concentration of particles follows a curve typical for homogeneous nucleation recorded in the absence of nuclei. Nuclei with different mobility diameters were activated at different values of vapor pressure. There are significant differences in the slopes of particle activation curves for NaCl and WOx particles. The reasons for such differences are a subject for continuing research.
• SHONO, TATSUYA;KASHIMURA, SHIGENORI;MORI, YASUO;HAYASHI, TAKASHI;SOEJIMA,+, J. ORG. CHEM., 54,(1989) N6, C. 6001-6003
  作者：SHONO, TATSUYA、KASHIMURA, SHIGENORI、MORI, YASUO、HAYASHI, TAKASHI、SOEJIMA,+

  DOI：——

  日期：——
• US3954845A
  申请人：——

  公开号：US3954845A

  公开（公告）日：1976-05-04