1H,1H,2H,2H-全氟-9-甲基癸醇 | 31200-98-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1H,1H,2H,2H-全氟-9-甲基癸醇
• 中文别名: 1H,1H,2H,2H-全氟-9-甲基-1-癸醇
• 英文名称: 1H,1H,2H,2H-perfluoro-9-methyldecan-1-ol
• 英文别名: 2-(perfluoro-7-methyloctyl)ethanol；3,3,4,4,5,5,6,6,7,7,8,8,9,10,10,10-hexadecafluoro-9-(trifluoromethyl)decan-1-ol
• CAS: 31200-98-3
• 化学式: C₁₁H₅F₁₉O
• 分子量: 514.13
• InChiKey: RRPJMPARBFYNMD-UHFFFAOYSA-N

物化性质

• 沸点：
  100°C 7mm
• 稳定性/保质期：
  如果按照规定使用和储存，则不会发生分解，目前没有已知的危险反应。

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  20

安全信息

• 危险品标志：
  F

反应信息

• 作为反应物：
  描述：

  1H,1H,2H,2H-全氟-9-甲基癸醇 在 dichloro( 1,5-cyclooctadiene)platinum(ll) 、 sodium hydroxide 、 四丁基硫酸氢铵 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 40.0h， 生成 3-(propoxy-1H,1H,2H,2H-perfluoro-9-methyldecyl)-1,1,1,3,5,5,5-heptamethyltrisiloxane
  参考文献：
  名称：

  Synthesis of model organosiloxanes containing perfluoroether side-chains

  摘要：

  一系列有机三硅氧烷[(Me3SiO)2MeSi(CH2)nO(CH2)mRf]，其中（n = 3，m = 1，Rf = CF3；n = 3，m = 2，Rf = C4F9，C6F13，C8F17，C10F21，C7F15；n = 5，m = 1，Rf = CF3；n = 10，m = 0，Rf = C3HF6；n = 10，m = 1，Rf = CF3）已经通过[Pt(环辛二烯)Cl2]催化的氢硅化反应制备，反应物为七甲基三硅氧烷和CH2CH(CH2)n−2O(CH2)mRf。产率取决于烯链长度和Rf基团的支化程度。在涉及CH2CHCH2OCH2CF3的反应中，检测到了异构体产物[(Me3SiO)2MeSi(CH2)3OCH2CF3]和[(Me3SiO)2MeSiCH(Me)CH2OCH2CF3]。

  DOI：

  10.1039/b001376p

文献信息

• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• Fluorine-containing diols and use thereof
  申请人：DAINICHISEIKA COLOR & CHEMICALS MFG. CO. LTD.

  公开号：EP1132378A2

  公开（公告）日：2001-09-12

  Fluorine-containing diols represented by the following formula (I) are provided: wherein Rf represents a perfluoroalkyl or perfluoroalkenyl group having 1 to 20 carbon atoms; X represents a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenylene group represented by -CH=CH-(CH2)n- in which n stands for an integer of from 1 to 10, or in which n stands for an integer of from 0 to 6; Y represents a direct bond, -O-, -NH-, or -R0-NH- in which R0 is an alkylene group having 1 to 6 carbon atoms; Z represents a direct bond or -N(R')R- in which R is an alkylene group having 1 to 20 carbon atoms and R' is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R1 and R2 each independently represent a divalent organic group; and R3 represents a residual group of an aliphatic, alicyclic or aromatic diisocyanate. These fluorine-containing diols are useful for the production of polyurethanes.

  提供了下式(I)所代表的含氟二元醇： 其中 Rf 代表具有 1 至 20 个碳原子的全氟烷基或全氟烯基； X 代表具有 1 至 10 个碳原子的取代或未取代的亚烷基、由 -CH=CH-(CH2)n- 代表的取代或未取代的烯基，其中 n 代表 1 至 10 的整数，或 其中 n 代表 0 至 6 的整数； Y 代表直接键、-O-、-NH- 或-R0-NH-，其中 R0 是具有 1 至 6 个碳原子的亚 烷基；Z 代表直接键或-N(R')R-，其中 R 是具有 1 至 20 个碳原子的亚烷基，R'是氢原子或具有 1 至 6 个碳原子的烷基；R1 和 R2 各自独立地代表二价有机基团；R3 代表脂肪族、脂环族或芳香族二异氰酸酯的残基。这些含氟二元醇可用于生产聚氨酯。
• Artificial leather
  申请人：DAINICHISEIKA COLOR & CHEMICALS MFG. CO. LTD.

  公开号：EP1143063A2

  公开（公告）日：2001-10-10

  Artificial leather has a base sheet and a resin layer arranged on at least one side of the base sheet. The resin layer comprises a polyurethane having side chains derived from a fluorine-containing diol represented by the following formula ( I ) : wherein Rf represents a perfluoroalkyl or perfluoroalkenyl group having 1 to 20 carbon atoms; X represents a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenylene group represented by -CH=CH-(CH2)n- in which n stands for an integer of from 1 to 10, or in which n stands for an integer of from 0 to 6; Y represents a direct bond, -O-, -NH-, or -R0-NH- in which R0 is an alkylene group having 1 to 6 carbon atoms; Z represents a direct bond or -N(R')R- in which R is an alkylene group having 1 to 20 carbon atoms and R' is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R1 and R2 each independently represent a divalent organic group; and R3 represents a residual group of an aliphatic, alicyclic or aromatic diisocyanate.

  人造革有一个基片和一个至少位于基片一侧的树脂层。树脂层包括一种聚氨酯，其侧链由下式 ( I ) 所代表的含氟二元醇衍生而来： 其中 Rf 代表具有 1 至 20 个碳原子的全氟烷基或全氟烯基； X 代表具有 1 至 10 个碳原子的取代或未取代的亚烷基、由 -CH=CH-(CH2)n- 代表的取代或未取代的烯基，其中 n 代表 1 至 10 的整数，或 其中 n 代表 0 至 6 的整数； Y 代表直接键、-O-、-NH- 或-R0-NH-，其中 R0 是具有 1 至 6 个碳原子的亚 烷基；Z 代表直接键或-N(R')R-，其中 R 是具有 1 至 20 个碳原子的亚烷基，R'是氢原子或具有 1 至 6 个碳原子的烷基；R1 和 R2 各自独立地代表二价有机基团；R3 代表脂肪族、脂环族或芳香族二异氰酸酯的残基。
• Dye-donor element for thermal transfer recording
  申请人：DAINICHISEIKA COLOR & CHEMICALS MFG. CO. LTD.

  公开号：EP1136278A1

  公开（公告）日：2001-09-26

  A thermal recording media has a base sheet, a thermal recording layer arranged on one side of the base sheet, and a back layer arranged on an opposite side of the base sheet. The back layer comprises a polyurethane having side chains derived from a fluorine-containing diol represented by the following formula ( I ) : wherein Rf represents a perfluoroalkyl or perfluoroalkenyl group having 1 to 20 carbon atoms; X represents a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenylene group represented by -CH=CH-(CH2)n- in which n stands for an integer of from 1 to 10, or in which n stands for an integer of from 0 to 6; Y represents a direct bond, -O-, -NH-, or -R0-NH- in which R0 is an alkylene group having 1 to 6 carbon atoms; Z represents a direct bond or -N(R')R- in which R is an alkylene group having 1 to 20 carbon atoms and R' is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R1 and R2 each independently represent a divalent organic group; and R3 represents a residual group of an aliphatic, alicyclic or aromatic diisocyanate.

  一种热敏记录介质具有基片、位于基片一侧的热敏记录层和位于基片另一侧的背层。背层包括聚氨酯，其侧链由下式 ( I ) 所代表的含氟二元醇衍生而来： 其中 Rf 代表具有 1 至 20 个碳原子的全氟烷基或全氟烯基； X 代表具有 1 至 10 个碳原子的取代或未取代的亚烷基、由 -CH=CH-(CH2)n- 代表的取代或未取代的烯基，其中 n 代表 1 至 10 的整数，或 其中 n 代表 0 至 6 的整数； Y 代表直接键、-O-、-NH- 或-R0-NH-，其中 R0 是具有 1 至 6 个碳原子的亚 烷基；Z 代表直接键或-N(R')R-，其中 R 是具有 1 至 20 个碳原子的亚烷基，R'是氢原子或具有 1 至 6 个碳原子的烷基；R1 和 R2 各自独立地代表二价有机基团；R3 代表脂肪族、脂环族或芳香族二异氰酸酯的残基。
• Thermal recording media
  申请人：Dainichiseika Color & Chemicals Mfg. Co.

  公开号：US20010034301A1

  公开（公告）日：2001-10-25

  A thermal recording media has a base sheet, a thermal recording layer arranged on one side of the base sheet, and a back layer arranged on an opposite side of the base sheet. The back layer comprises a polyurethane having side chains derived from a fluorine-containing diol represented by the following formula (I): 1 wherein R f represents a perfluoroalkyl or perfluoroalkenyl group having 1 to 20 carbon atoms; X represents a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenylene group represented by —CH═CH—(CH 2 ) n — in which n stands for an integer of from 1 to 10, or 2 in which n stands for an integer of from 0 to 6; Y represents a direct bond, —O—, —NH—, or —R 0 —NH— in which R 0 is an alkylene group having 1 to 6 carbon atoms; Z represents a direct bond or —N(R′)R— in which R is an alkylene group having 1 to 20 carbon atoms and R′ is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 1 and R 2 each independently represent a divalent organic group; and R 3 represents a residual group of an aliphatic, alicyclic or aromatic diisocyanate.

  一种热敏记录介质具有基片、位于基片一侧的热敏记录层和位于基片另一侧的背层。背层由聚氨酯组成，其侧链由下式（I）表示的含氟二元醇衍生而来： 1 其中 R f 代表具有 1 至 20 个碳原子的全氟烷基或全氟烯基； X 代表具有 1 至 10 个碳原子的取代或未取代的亚烷基、由-CH═CH-(CH) 2 ) n - 其中 n 代表 1 至 10 的整数，或 2 其中 n 代表 0 至 6 的整数；Y 代表直接键、-O-、-NH- 或 -R 0 -NH-，其中 R 0 是具有 1 至 6 个碳原子的亚烷基；Z 代表直接键或 -N(R′)R-，其中 R 是具有 1 至 20 个碳原子的亚烷基，R′是氢原子或具有 1 至 6 个碳原子的烷基；R 1 和 R 2 各自独立地代表二价有机基团；以及 R 3 代表脂肪族、脂环族或芳香族二异氰酸酯的残基。