bicyclo<2.2.1>heptane-2,3-dione | 6236-71-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: bicyclo<2.2.1>heptane-2,3-dione
• 英文别名: 2,3-norbornenedione；norbornane-2,3-dione；Norbornan-2,3-dion；Bicyclo<2.2.1>heptan-2,3-dion；Bicyclo<2.2.1>hept-2,3-dion；Norcampherchinon；Bicyclo[2.2.1]heptane-2,3-dione
• CAS: 6236-71-1
• 化学式: C₇H₈O₂
• 分子量: 124.139
• InChiKey: DTKVZNFHNGLJBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bicyclo<2.2.1>heptane-2,3-dione 在 双氧水 、 溶剂黄146 作用下， 生成 (1S,3R)-环戊烷-1,3-二甲酸
  参考文献：
  名称：

  Alder et al., Justus Liebigs Annalen der Chemie, 1955, vol. 593, p. 1,17

  摘要：

  DOI：
• 作为产物：
  描述：

  3,3-Dihydroxy-bicyclo[2.2.1]heptan-2-one 以 水 为溶剂， 生成 bicyclo<2.2.1>heptane-2,3-dione
  参考文献：
  名称：

  Structural effects affecting hydration of 1,2-diones studied by linear-sweep voltammetry

  摘要：

  DOI：

  10.1021/jo00376a062

文献信息

• Metal Complexes
  申请人：Merck Patent GmbH

  公开号：US20150171348A1

  公开（公告）日：2015-06-18

  The present invention relates to metal complexes and to electronic devices, in particular organic electroluminescent devices, comprising these metal complexes.

  这项发明涉及金属配合物以及包括这些金属配合物的电子设备，特别是有机电致发光器件。
• [EN] LIGAND-ENABLED META-C-H ACTIVATION USING A TRANSIENT MEDIATOR<br/>[FR] ACTIVATION DE MÉTA-C-H PERMISE PAR UN LIGAND UTILISANT UN MÉDIATEUR TRANSITOIRE
  申请人：SCRIPPS RESEARCH INST

  公开号：WO2016123361A1

  公开（公告）日：2016-08-04

  An alternative approach to formation of a C-C bond at a meta-position of an aromatic compound is disclosed that employs an ethylenically unsaturated bicyclic compound as a transient mediator to achieve meta-selective C-H activation with a simple and common ortho-directing group. The use of a pyridine-based ligand assists in relaying the palladium catalyst to the meta-position by the unsaturated bicyclic compound following initial ortho-C-H activation.

  披露了一种在芳香化合物的间位形成C-C键的替代方法，该方法利用乙烯不饱和的双环化合物作为瞬时介质，通过简单常见的邻向导向基团实现间选择性C-H活化。使用以吡啶为基础的配体有助于通过不饱和的双环化合物将钯催化剂传递到间位，从而实现最初的邻位C-H活化。
• Alkyl-pyridazine derivatives as 11b-HSD1 inhibitors
  申请人：Amrein Kurt

  公开号：US20080009499A1

  公开（公告）日：2008-01-10

  Compounds of formula (I): as well as pharmaceutically acceptable salts and esters thereof for use as pharmaceutical compositions.

  化合物的化学式（I）：以及其药用可接受的盐和酯，用作药物组合物。
• New pyridazines as 11B-HSD1 inhibitors
  申请人：Amrein Kurt

  公开号：US20070010519A1

  公开（公告）日：2007-01-11

  Compounds of formula as well as pharmaceutically acceptable salts and esters thereof, wherein R 1 to R 4 have the significance given in claim 1 can be used in the form of pharmaceutical compositions.

  公式化合物及其药用可接受的盐和酯，其中R1至R4具有权利要求1中所给出的意义，可以用于制备药物组成物。
• Camphorquinone Derivative Having Acylphosphine Oxide Group, Photopolymerization Catalyst And Photo/Chemical Polymerization Catalyst Containing The Same And Hardenable Composition Contaning The Same
  申请人：Ikemura Kunio

  公开号：US20090105361A1

  公开（公告）日：2009-04-23

  A compound that exhibits excellent color tone stability and physical properties as well as excellent photopolymerization activity over a wide region from near-ultraviolet to visible region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry; and a relevant photopolymerization initiator and hardenable composition. In particular, there is provided a novel camphorquinone derivative having an acylphosphine oxide group [—(C═O)—(P═O)<] in each molecule. Further, there is provided a photopolymerization initiator comprising the camphorquinone derivative having an acrylphosphine oxide group [—(C═O)—(P═O)<] in each molecule as an indispensable component, loaded with at least one member selected from among a polymerization accelerator, a photoacid generator, a photosensitizer and a (bis)acylphosphine oxide, and provided a hardenable composition comprising the initiator. The thus provided photopolymerization initiator and hardenable composition exhibit excellent color tone stability and physical properties as well as excellent photopolymeritzaion activity over an ultraviolet and visible wide wavelength region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry.

  提供了一种化合物，其具有出色的色调稳定性和物理性能，以及在近紫外到可见光区域内具有优异的光聚合活性，使得在环境光线下可以放松操作，因此在牙科领域和光聚合工业中可以找到广泛的应用；以及相关的光聚合引发剂和可硬化组合物。特别地，提供了一种新型的萜烯酮衍生物，其每个分子中都具有一个酰基膦氧化物基团[—(C═O)—(P═O)<]。此外，还提供了一种光聚合引发剂，其中包含具有丙烯酰膦氧化物基团[—(C═O)—(P═O)<]的萜烯酮衍生物作为不可或缺的组分，装载有至少一种从聚合促进剂、光酸发生剂、光敏剂和(双)酰基膦氧化物中选择的成员，并提供了一种包含引发剂的可硬化组合物。因此，所提供的光聚合引发剂和可硬化组合物在紫外和可见光宽波长区域内表现出优异的色调稳定性和物理性能，以及优异的光聚合活性，使得在环境光线下可以放松操作，因此在牙科领域和光聚合工业中可以找到广泛的应用。