dimethyl (E,E)-dipiperonylidenesuccinate | 14833-90-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: dimethyl (E,E)-dipiperonylidenesuccinate
• 英文别名: gossypidiene；(E,E)-dipiperonylidene-succinic acid dimethyl ester；(E,E)-Dipiperonyliden-bernsteinsaeure-dimethylester；α,β-Dipiperonyliden-bernsteinsaeure-dimethylester；Dimethyl-α,α'-dipiperonyliden-succinat；dimethyl (2E,3E)-2,3-bis(1,3-benzodioxol-5-ylmethylidene)butanedioate
• CAS: 14833-90-0
• 化学式: C₂₂H₁₈O₈
• 分子量: 410.38
• InChiKey: DUGIKHHFHOYBJI-BGPOSVGRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  dimethyl (E,E)-dipiperonylidenesuccinate 在 2,3-二氯碘苯 、 sodium acetate 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 以93%的产率得到dimethyl (E,E)-di-(6-chloropiperonylidene) succinate
  参考文献：
  名称：

  Anjaneyulu, A.S.R.; Umasundari, P.; Sastry, Ch.V.M., Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989, vol. 28, p. 214 - 218

  摘要：

  DOI：
• 作为产物：
  描述：

  丁二酸二甲酯 在 sodium methylate 作用下， 以 甲醇 、 乙醚 为溶剂， 反应 26.0h， 生成 dimethyl (E,E)-dipiperonylidenesuccinate
  参考文献：
  名称：

  Gossypidien, a lignan from stems of Jatrophagossypifolliafn1fn1Part 29 in the series Studies onPhytochemicals. For Part 28 see Das, B., and Venkataiah,B. (1998). Biochem. Syst. Ecol., in press. iictCommunication No. 4148.

  摘要：

  A new lignan, gossypidien, has been isolated from the stems of Jatropha gossypifolia. The structure of the compound was deduced from its spectral data, as well as from its synthesis. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(98)00727-4

文献信息

• Freudenberg; Kempermann, Justus Liebigs Annalen der Chemie, 1957, vol. 602, p. 184,198
  作者：Freudenberg、Kempermann

  DOI：——

  日期：——
• Preparation of Some Substituted α,β-Diphenylacrylic Acids and Related Derivatives
  作者：B. H. ALEXANDER、W. F. BARTHEL

  DOI：10.1021/jo01097a015

  日期：1958.3
• ANJANEYULU, A. S. R.;UMASUNDARI, P.;SASTRY, CH. V. M.;SATYANARAYANA, P., INDIAN J. CHEM. B , 28,(1989) N, C. 214-218
  作者：ANJANEYULU, A. S. R.、UMASUNDARI, P.、SASTRY, CH. V. M.、SATYANARAYANA, P.

  DOI：——

  日期：——
• Gossypidien, a lignan from stems of Jatrophagossypifolliafn1fn1Part 29 in the series Studies onPhytochemicals. For Part 28 see Das, B., and Venkataiah,B. (1998). Biochem. Syst. Ecol., in press. iictCommunication No. 4148.
  作者：Biswanath Das、G Anjani

  DOI：10.1016/s0031-9422(98)00727-4

  日期：1999.5

  A new lignan, gossypidien, has been isolated from the stems of Jatropha gossypifolia. The structure of the compound was deduced from its spectral data, as well as from its synthesis. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Anjaneyulu, A.S.R.; Umasundari, P.; Sastry, Ch.V.M., Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989, vol. 28, p. 214 - 218
  作者：Anjaneyulu, A.S.R.、Umasundari, P.、Sastry, Ch.V.M.、Satyanarayana, P.

  DOI：——

  日期：——