Ethyltriphenylgerman | 2945-45-1

• 物质功能分类: 有机原料
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ethyltriphenylgerman
• 英文别名: Triphenylethylgermanium；ethyltriphenylgermane；Aethyl-triphenyl-germanium；Aethyl-triphenyl-german；Ethyl(triphenyl)germane
• CAS: 2945-45-1
• 化学式: C₂₀H₂₀Ge
• 分子量: 332.969
• InChiKey: GTCQONMCAAWWIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.18
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  生成 Ethyltriphenylgerman
  参考文献：
  名称：

  CORRIU, R. J. P.;OULD-KADA, S.;LANNEAU, G. F., J. ORGANOMET. CHEM., 1983, 248, N 1, 39-50

  摘要：

  DOI：

文献信息

• The chemical behaviour of cobalt-stabilized carbenes having a trisubstituted silyl or germyl ligand. Stereospecific formation of benzoylsilanes from the reaction of organosilyl-cobalt tetracarbonyl derivatives with phenyllithium
  作者：Geneviéve Cerveau、Ernesto Colomer、Robert J.P. Corriu、J.Colin Young

  DOI：10.1016/s0022-328x(00)82934-4

  日期：1981.1

  behavior of cobalt-stabilized carbenes, R3M(CO)3CoC(OEt)R′, and their parent anions, R3M(CO)3CoC(O−)R′, where M = Si or Ge. The anions where M = Si, R′ = Ph decompose thermally into the corresponding benzoylsilanes; when the silicon atom is chiral (R3 = MePh-1-Np) optically active R3SiCOPh is obtained with complete retention of configuration.

  我们报告钴稳定的卡宾的化学行为，R 3 M（CO）3 COC（OET）R'，和它们的母体的阴离子，R 3 M（CO）3大会（O -）R'，其中M = Si或哥 M = Si，R'= Ph的阴离子热分解成相应的苯甲酰基硅烷；当硅原子是手性的（R 3＝ MePh-1-Np）时，获得具有完全保留构型的光学活性R 3 SiCOPh。
• Preferential carbene insertion into Ge–H vs. other heavier group 14 hydrides via samarium carbenoids
  作者：Hitoshi Kondo、Yoshinori Yamanoi、Hiroshi Nishihara

  DOI：10.1039/c1cc11256b

  日期：——

  The relative reactivities of Zn, Al, and Sm carbenoids in the chemoselective carbene insertion reaction of heavier group 14 hydrides were studied. By variation of the reaction protocols using Sm carbenoids, insertion reaction can favour the Ge-H bonds to give Ge-alkylated derivatives in good to high yield.

  研究了较重的14族氢化物在化学选择性卡宾插入反应中Zn，Al和Sm类胡萝卜素的相对反应性。通过改变使用Sm类胡萝卜素的反应方案，插入反应可以促进Ge-H键，从而以良好或高收率得到Ge-烷基化衍生物。
• Preparation of ethylene-bridged Group 14 metal–zirconocene complexes
  作者：Yasuyuki Ura、Ryuichiro Hara、Tamotsu Takahashi

  DOI：10.1016/s0022-328x(00)00463-0

  日期：2000.10

  The reactions of the zirconocene-ethylene complex Cp2Zr(CH2=CH2)(PMe3) with Group 14 metal chlorides or alkoxides give ethylene-bridged group 14 metal-zirconocene complexes. A reaction mechanism via a five-membered intermediate which involves direct coupling of ethylene and single bonding is proposed. (C) 2000 Elsevier Science S.A. All rights reserved.
• Dennis, Zeitschrift fur Anorganische und Allgemeine Chemie, 1928, vol. 174, p. 136
  作者：Dennis

  DOI：——

  日期：——
• Orndorff; Tabern; Dennis, Journal of the American Chemical Society, 1927, vol. 49, p. 2516
  作者：Orndorff、Tabern、Dennis

  DOI：——

  日期：——