2-丙烯酸-2-[(3A,4,5,6,7,7A-六氢-4,7-亚甲基-1H-茚-5基)氧]乙酯 | 79638-11-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 2-丙烯酸-2-[(3A,4,5,6,7,7A-六氢-4,7-亚甲基-1H-茚-5基)氧]乙酯
• 英文名称: 2-Propenoic acid, 2-((3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-5-yl)oxy)ethyl ester
• 英文别名: 2-(8-tricyclo[5.2.1.02,6]dec-4-enyloxy)ethyl prop-2-enoate
• CAS: 79638-11-2
• 化学式: C₁₅H₂₀O₃
• 分子量: 248.32
• InChiKey: XIPXCVZIOAPJIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Ethanol, 2-[(3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-5-yl)oxy]- 、 丙烯酸 生成 2-丙烯酸-2-[(3A,4,5,6,7,7A-六氢-4,7-亚甲基-1H-茚-5基)氧]乙酯
  参考文献：
  名称：

  OKAMOTO, YASUXIRO

  摘要：

  DOI：

文献信息

• Ink composition, injet recording method, printed material, and process for producing lithographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP1975213A1

  公开（公告）日：2008-10-01

  An ink composition is provided that includes (A) an N-vinyllactam, (B) a monomer represented by Formula (I), and (C) a radical polymerization initiator, or includes (A) an N-vinyllactam, (B) a monomer represented by Formula (II), (C) a radical polymerization initiator, and phenoxyethyl acrylate. (In Formula (I) and Formula (II), R1 denotes a hydrogen atom, a halogen atom, or an alkyl group having 1 to 4 carbons, X1 denotes a divalent linking group, R2 and R3 independently denote a substituent, k denotes an integer of 1 to 6, q and r independently denote an integer of 0 to 5, n denotes a cyclic hydrocarbon structure, the cyclic hydrocarbon structure may comprise in addition to hydrocarbon bonds a carbonyl bond (-C(O)-) and/or an ester bond (-C(O)O-), and the k R1s, the k X1s, the q R2s, and the r R3s may each be identical to or different from each other; furthermore, one carbon atom in the adamantane framework in Formula (I) may be replaced by a carbonyl bond (-C(O)-) and/or an ester bond (-C(O)O-), and one carbon atom in the norbornene framework in Formula (II) may be replaced by an ether bond (-O-) and/or an ester bond (-C(O)O-).) There are also provided an inkjet recording method, a printed material, and a process for producing a lithographic printing plate that employ the ink composition.

  提供了一种油墨组合物，它包括 (A)一种 N-乙烯内酰胺、(B) 一种由式 (I) 代表的单体和 (C) 一种自由基聚合引发剂，或包括 (A)一种 N-乙烯内酰胺、(B) 一种由式 (II) 代表的单体、(C) 一种自由基聚合引发剂和丙烯酸苯氧乙酯。 (在式 (I) 和式 (II) 中，R1 表示氢原子、卤素原子或具有 1 至 4 个碳原子的烷基，X1 表示二价连接基团，R2 和 R3 独立地表示取代基，k 表示 1 至 6 的整数，q 和 r 独立地表示 0 至 5 的整数、n 表示环状烃结构，环状烃结构除烃键外，还可包括羰基键 (-C(O)-) 和/或酯键 (-C(O)O-)，且 k R1、k X1、q R2 和 r R3 可彼此相同或不同；此外，式(I)中金刚烷框架中的一个碳原子可被羰基键(-C(O)-)和/或酯键(-C(O)O-)取代，式(II)中降冰片烯框架中的一个碳原子可被醚键(-O-)和/或酯键(-C(O)O-)取代。)此外，还提供了采用该油墨组合物的喷墨记录方法、印刷材料和平版印刷板的生产工艺。
• Ink composition, inkjet recording method, and printed material
  申请人：FUJIFILM Corporation

  公开号：EP2042568A1

  公开（公告）日：2009-04-01

  An ink composition is provided that includes (A) at least one polymerizable compound selected from the group consisting of a monofunctional radically polymerizable monomer having an aliphatic cyclic structure, an N-vinyllactam, and an aromatic monofunctional radically polymerizable monomer, (B) a radical polymerization initiator, (C) a pigment, and (D) a graft copolymer having a repeating unit represented by the Formula below in a graft chain. (In the Formula, R denotes a hydrogen atom or a methyl group, X denotes a single bond, - O-, -CO-, -COO-, -CONR1-, -OCO-, or a phenylene group, R1 denotes a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, L denotes a single bond or a divalent linking group, Z denotes -NR2R3, R2 and R3 independently denote a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, and R2 and R3 may be bonded to each other to form a ring.) There are also provided an inkjet recording method that includes a step of discharging the ink composition above onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, and a printed material recorded by the inkjet recording method.

  本发明提供了一种油墨组合物，其中包括：(A) 至少一种可聚合化合物，该化合物选自由脂肪族环状结构的单官能团可辐射聚合单体、N-乙烯内酰胺和芳香族单官能团可辐射聚合单体组成的组；(B) 自由基聚合引发剂；(C) 颜料；(D) 接枝共聚物，该接枝共聚物的接枝链中具有下式所代表的重复单元。 (式中，R 表示氢原子或甲基，X 表示单键、-O-、-CO-、-COO-、-CONR1-、-OCO-或亚苯基，R1 表示氢原子、烷基、芳基或芳烷基、L 表示单键或二价连接基团，Z 表示-NR2R3，R2 和 R3 独立地表示氢原子、烷基、芳基或芳烷基，R2 和 R3 可相互键合形成环。)还提供了一种喷墨记录方法，该方法包括将上述墨水组合物排放到记录介质上的步骤和通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤，以及用该喷墨记录方法记录的印刷材料。
• Photocurable composition, photocurable ink composition, process for producing photocured material, and inkjet recording method
  申请人：FUJIFILM Corporation

  公开号：EP2085439A1

  公开（公告）日：2009-08-05

  A photocurable composition is provided that includes a polymerizable compound, a photopolymerization initiator, a compound represented by Formula (I) below, and an amine compound, the photopolymerization initiator comprising an acylphosphine oxide compound and/or an α-aminoacetophenone compound in Formula (I) above, X denotes O, S, or NR, n denotes 0 or 1, R denotes a hydrogen atom, an alkyl group, or an acyl group, R1, R2, R3, R4, R5, R6, R7, and R8 independently denote a hydrogen atom or a monovalent substituent, and two of R1, R2, R3, and R4 that are adjacent may be bonded to each other to form a ring. There are also provided a photocurable ink composition that includes the photocurable composition and a colorant, an ink composition for photocuring inkjet recording that includes the photocurable ink composition, a process for producing a photocured material that includes preparing the photocurable composition and irradiating the photocurable composition with light having a light emission peak in the range of at least 340 nm but no greater than 400 nm, and an inkjet recording method that includes discharging the ink composition onto a recording medium and irradiating the ink composition with actinic radiation.

  提供了一种光固化组合物，该组合物包括可聚合化合物、光聚合引发剂、下式 (I) 所代表的化合物和胺化合物，其中光聚合引发剂包括酰基氧化膦化合物和/或 α-氨基苯乙酮化合物 在上式（I）中，X 表示 O、S 或 NR，n 表示 0 或 1，R 表示氢原子、烷基或酰基，R1、R2、R3、R4、R5、R6、R7 和 R8 独立地表示氢原子或一价取代基，相邻的两个 R1、R2、R3 和 R4 可以相互键合形成环。还提供了一种光固化墨水组合物，它包括该光固化组合物和着色剂；一种用于光固化喷墨记录的墨水组合物，它包括该光固化墨水组合物；一种用于生产光固化材料的工艺，它包括制备该光固化组合物，并用在至少340纳米但不大于400纳米范围内具有光发射峰的光照射该光固化组合物；以及一种喷墨记录方法，它包括将墨水组合物排放到记录介质上，并用阳极辐射照射该墨水组合物。
• Inkjet ink composition, and inkjet recording method and printed material employing same
  申请人：FUJIFILM Corporation

  公开号：EP2093265A1

  公开（公告）日：2009-08-26

  An inkjet ink composition is provided that includes at least one type of organic pigment exhibiting an orange, violet, or green color, at least one type selected from the group consisting of polymer compounds derived from a monomer represented by specific Formulae and a polymer represented by a specific Formula, and an actinic radiation-curable compound.

  提供了一种喷墨墨水组合物，其中包括至少一种呈现橙色、紫色或绿色的有机颜料、至少一种选自由特定式子代表的单体和特定式子代表的聚合物衍生的高分子化合物以及一种光辐射固化化合物组成的组。
• Ink-jet ink composition, and ink-jet recording method
  申请人：Fujifilm Corporation

  公开号：EP2154213A1

  公开（公告）日：2010-02-17

  An ink-jet ink composition containing the following components of (a), (b), and (c), and having a viscosity at 25°C in the range of from 5 mPa·s to 100 mPa·s, (a) a polymerizable compound, (b) a photopolymerization initiator, and (c) a sensitizer represented by the following formula (i): in the Formula (i), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; each of R1, R2, R3, R4, R5, R6, R7 and R8 independently represents a hydrogen atom or a monovalent substituent, provided that any neighboring two of R1, R2, R3 and R4 may be bonded to each other to form a ring, and R5 and R7 or R8, or R6 and R7 or R8, may be bonded to each other to form an aliphatic ring but do not form an aromatic ring.

  一种喷墨墨水组合物，含有(a)、(b)和(c)中的下列成分，在 25℃时的粘度在 5 mPa-s 至 100 mPa-s 之间、 (a) 可聚合化合物、 (b) 光聚合引发剂，和 (c) 下式(i)所代表的敏化剂： 式（i）中，X 代表 O、S 或 NR；n 代表 0 或 1 的整数；R 代表氢原子、烷基或酰基；R1、R2、R3、R4、R5、R6、R7 和 R8 中的每一个独立地代表一个氢原子或一个一价取代基，但 R1、R2、R3 和 R4 中的任意相邻两个可相互键合形成一个环，R5 和 R7 或 R8 或 R6 和 R7 或 R8 可相互键合形成一个脂肪族环，但不形成一个芳香族环。