2-丙烯酸-2-(2,4,6-三溴苯氧基)乙酯 | 7347-19-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2-丙烯酸-2-(2,4,6-三溴苯氧基)乙酯
• 英文名称: 2-(2,4,6-Tribromophenoxy)ethyl acrylate
• 英文别名: 2-(2,4,6-tribromophenoxy)ethyl prop-2-enoate
• CAS: 7347-19-5
• 化学式: C₁₁H₉Br₃O₃
• 分子量: 428.9
• InChiKey: AMBJXYFIMKHOQE-UHFFFAOYSA-N

物化性质

• 沸点：
  423.9±45.0 °C(Predicted)
• 密度：
  1.892±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] DICARBOXYLIC ACID COMPOUNDS. INORGANIC PARTICLES TREATED WITH THE DICARBOXYLIC ACID COMPOUNDS, AND COMPOSITIONS THEREOF<br/>[FR] COMPOSÉS D'ACIDE DICARBOXYLIQUE, PARTICULES INORGANIQUES TRAITÉES PAR LES COMPOSÉS D'ACIDE DICARBOXYLIQUE ET COMPOSITIONS CORRESPONDANTES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2021064530A1

  公开（公告）日：2021-04-08

  Described herein is a dicarboxylic acid compound of formula (I): Wherein: R3 comprises an aryl group, R2 is an alkylene group comprising 1 to 6 carbon atoms, n is 0 or 1, R1 is H or CH3, and X is S or NZ, wherein Z is H, an alkyl group comprising 1 to 4 carbon atoms or a phenyl group. Such compounds can be used to modify the surface of inorganic particles. These modified inorganic particles may then be advantageously used in polymerizable resins to increase the refractive index of the resulting composite, while enabling good flow properties of the polymerizable composition

  本文介绍了一种二羧酸化合物，其化学式为（I）：其中：R3包括一个芳基基团，R2是含有1至6个碳原子的烷基基团，n为0或1，R1为H或CH3，X为S或NZ，其中Z为H，含有1至4个碳原子的烷基基团或苯基团。这些化合物可用于修改无机颗粒的表面。然后可以有利地将这些修改后的无机颗粒用于可聚合树脂中，以增加所得复合材料的折射率，同时使可聚合组分具有良好的流动性。
• High refractive index monomers, compositions and uses thereof
  申请人：Craciun Liliana

  公开号：US20080200582A1

  公开（公告）日：2008-08-21

  The invention relates to novel sulfur-containing (meth)acrylic monomers and compositions thereof characterized by a high refractive index, for optical and industrial applications. The invention also relates to a method for preparing high refractive index polymeric materials and more specifically to a method for formation of ultraviolet cast optical lenses and compositions thereof comprising the sulfur-containing (meth)acrylic monomers.

  本发明涉及一种新型含硫（甲基）丙烯酸单体及其组合物，其具有高折射率，适用于光学和工业应用。本发明还涉及一种制备高折射率聚合材料的方法，更具体地涉及一种形成紫外线铸造光学透镜的方法和组合物，其中包括含硫（甲基）丙烯酸单体。
• MICROSTRUCTURED OPTICAL FILMS COMPRISING BIPHENYL DIFUNCTIONAL MONOMERS
  申请人：Invie Judith M.

  公开号：US20080221291A1

  公开（公告）日：2008-09-11

  Optical films having a polymerized microstructured surface are described. The polymerized microstructured surface comprises the reaction product of a polymerizable resin composition comprising 10% to 100 wt-% of at least one biphenyl di(meth)acrylate monomer. The di(meth)acrylate monomer comprises a core biphenyl structure having two aromatic rings connected with a C—C bond. The biphenyl di(meth)acrylate monomer preferably comprises a sufficient amount of ortho and/or meta(meth)acrylate substituents such that the monomer is a liquid at 25° C.

  描述了具有聚合微结构表面的光学薄膜。聚合微结构表面包括聚合物化可树脂组合物的反应产物，该组合物包括10%至100重量％的至少一种联苯二（甲基）丙烯酸酯单体。二（甲基）丙烯酸酯单体包括一个核心联苯结构，其中两个芳香环通过C-C键连接。联苯二（甲基）丙烯酸酯单体优选包括足够量的邻位和/或间位（甲基）丙烯酸酯取代基，使单体在25°C时为液体。
• METHODS OF MAKING MICROSTRUCTURED OPTICAL FILMS COMPRISING BIPHENYL DIFUNCTIONAL MONOMERS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20130149495A1

  公开（公告）日：2013-06-13

  A method of making optical films having a polymerized microstructured surface are described. The polymerized microstructured surface comprises the reaction product of a polymerizable resin composition comprising 10% to 100 wt-% of at least one biphenyl di(meth)acrylate monomer. The di(meth)acrylate monomer comprises a core biphenyl structure having two aromatic rings connected with a C—C bond. The biphenyl di(meth)acrylate monomer preferably comprises a sufficient amount of ortho and/or meta(meth)acrylate substituents such that the monomer is a liquid at 25° C.

  本文描述了一种制备具有聚合微结构表面的光学膜的方法。聚合微结构表面由聚合树脂组成，包括至少10%至100重量％的联苯二（甲基）丙烯酸酯单体。二（甲基）丙烯酸酯单体包括一个核心联苯结构，其具有两个芳香环通过C—C键连接。联苯二（甲基）丙烯酸酯单体最好包括足够的邻位和/或间位（甲基）丙烯酸酯取代基，使得单体在25℃时为液态。
• Halogen-containing resin lens material
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0142921A1

  公开（公告）日：1985-05-29

  A halogen-containing resin lens material, having a refractive index of no = 1.55 or higher, an Abbe number of 27 or higher and good dyeable property and comprising a copolymer containing 10 to 90 wt. % of a monomer (I) represented by the formula (I) shown below: wherein: R1 represents hydrogen or CH3 group; X' a halogen atom except for fluorin; and p the number of substituted halogens which is an integer selected from 1 to 5, and n is an integer selected from 1 to 4, R1 existing in plural number and being either identical or different, X1 when existing in plural number being either identical or different and 10 to 70 wt. % of a crosslinking monomer having two or more polymerizable functional groups (the percentages being based on the copolymer weight).

  一种含卤素树脂镜片材料，其折射率为 no = 1.55 或更高，阿贝数为 27 或更高，并具有良好的可染性，其包含一种共聚物，该共聚物含有 10 至 90 wt.%由下式（I）表示的单体（I）：其中：R1 代表氢或 CH3 基团；X'为除氟以外的卤素原子；p 为取代卤素的数目，为 1 至 5 的整数，n 为 1 至 4 的整数，R1 为复数且相同或不同，X1 为复数时相同或不同，以及 10 至 70 wt.%具有两个或更多可聚合官能团的交联单体（百分比基于共聚物重量）。