Bis(3,7-dimethyloct-6-enylsulfanyl)methanethione | 1021376-54-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Bis(3,7-dimethyloct-6-enylsulfanyl)methanethione
• CAS: 1021376-54-4
• 化学式: C₂₁H₃₈S₃
• 分子量: 386.731
• InChiKey: MIJAQNZYPOROTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  24
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二硫化碳 、 (+/-)-citronellyl tosylate 在 aluminum oxide 作用下， 反应 15.0h， 以88%的产率得到Bis(3,7-dimethyloct-6-enylsulfanyl)methanethione
  参考文献：
  名称：

  Basic Al₂O₃ as an Efficient Heterogeneous Reagent for the Synthesis of Symmerical Dialkyl Trithiocarbonates

  摘要：

  This work deals with reaction of alkyl halides with carbon disulfide in the presence of basic alumina as heterogeneous and reusable reagent. It afforded symmetrical dialkyl trithiocarbonate in moderate to excellent isolated yields. Reaction of 1,2-dichloro ethane with carbon disulfide also proceeded in a similar manner to give a five-membered cyclic trithiocarbonate without formation of any polymeric by-product.

  DOI：

  10.1080/00397910701861198

文献信息

• Basic Al₂O₃ as an Efficient Heterogeneous Reagent for the Synthesis of Symmerical Dialkyl Trithiocarbonates
  作者：Ali Reza Kiasat、Foad Kazemi、Ali Savari

  DOI：10.1080/00397910701861198

  日期：2008.3.1

  This work deals with reaction of alkyl halides with carbon disulfide in the presence of basic alumina as heterogeneous and reusable reagent. It afforded symmetrical dialkyl trithiocarbonate in moderate to excellent isolated yields. Reaction of 1,2-dichloro ethane with carbon disulfide also proceeded in a similar manner to give a five-membered cyclic trithiocarbonate without formation of any polymeric by-product.