1,1-Dimesitylethylene | 38575-31-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,1-Dimesitylethylene
• 英文别名: 1,1-dimethylethylene；1,1-Dimesitylethene；1,1-dimesityl-ethene；1,1-Dimesityl-aethen；Benzene, 1,1'-ethenylidenebis[2,4,6-trimethyl-；1,3,5-trimethyl-2-[1-(2,4,6-trimethylphenyl)ethenyl]benzene
• CAS: 38575-31-4
• 化学式: C₂₀H₂₄
• 分子量: 264.411
• InChiKey: ZXLMOUVEHHFJDE-UHFFFAOYSA-N

物化性质

• 沸点：
  366.4±37.0 °C(Predicted)
• 密度：
  0.946±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1-Dimesitylethylene 在 乙醇 、 镍 作用下， 200.0 ℃ 、13.73 MPa 条件下， 生成 1,1-dimesityl-ethane
  参考文献：
  名称：

  Polyphosphoric Acid as a Dehydrating Agent. III. Identification of the Hydrocarbons from Mesitylene and Aliphatic Acids¹

  摘要：

  DOI：

  10.1021/ja01143a004
• 作为产物：
  描述：

  2′,4′,6′-三甲基苯乙酮 在 PPA 作用下， 生成 1,1-Dimesitylethylene
  参考文献：
  名称：

  Polyphosphoric Acid as a Dehydrating Agent. III. Identification of the Hydrocarbons from Mesitylene and Aliphatic Acids¹

  摘要：

  DOI：

  10.1021/ja01143a004

文献信息

• An Efficient Bismuth(III) Chloride-Catalyzed Synthesis of 1,1-Diarylalkenesvia Friedel–Crafts Reaction of Acyl Chloride or Vinyl Chloride with Arenes
  作者：Hongbin Sun、Ruimao Hua、Songjie Chen、Yingwu Yin

  DOI：10.1002/adsc.200606157

  日期：2006.9

  In the presence of catalytic amount of bismuth(III) chloride, the reactions of acyl chlorides or vinyl chlorides with arenes afforded 1,1-diarylalkenes in 25–82 % isolated yield. In the case of the reaction of acyl chlorides with arenes, the procedure includes an initial Friedel–Crafts acylation, subsequent formation of vinyl chlorides and final Friedel–Crafts-type vinylation of another arene molecule

  在催化量的氯化铋（III）的存在下，酰氯或氯乙烯与芳烃的反应可提供1,1-二芳基烯烃，分离产率为25-82％。在酰氯与芳烃反应的情况下，该程序包括最初的Friedel-Crafts酰化反应，随后形成的氯乙烯和最终的另一个芳烃分子与氯乙烯的Friedel-Crafts型乙烯基化反应。本文报道了路易斯酸催化的氯乙烯CCl键的首次裂解及其在多取代烯烃合成中的应用。
• A novel Friedel-Crafts reaction of hindered ketones
  作者：Royston M. Roberts、Ahmed M. El-Khawaga、Sophon Roengsumran

  DOI：10.1021/jo00191a026

  日期：1984.8
• Synthesis of sterically hindered aromatic dialdehydes
  作者：A. P. Yakubov、D. V. Tsyganov、L. I. Belen'kii、M. M. Krayushkin

  DOI：10.1007/bf00961271

  日期：1991.7

  A study was carried out on the formylation of a series of aromatic compounds containing two mesitylene or durene residues [dimesityl (I), dimesitylmethane (II), 1,2-dimesitylethane (III), 1,6-dimesitylhexane (IV), dimesityl sulfide (V), 1,1-dimesitylethylene (VI), 1,1-dimesityl-1-butene (VII), and didurylmethane (VIII)) by the action of dichloromethyl methyl ether (DCM) in the presence of AlCl3 and TiCl4. The corresponding dialdehydes are the major products. The formylation products when the reaction is carried out in the presence of AlCl3 in the case of (I) and (V) contain significant amounts of monoaldehydes, while partial cleavage of the substrates with the formation of products containing only one benzene ring is observed in the case of (II) and (VIII) in addition to formylation.
• Ortho Methyl Group Effects in Cumyl Systems
  作者：Jack W. Timberlake、Dawei Pan、Jane Murray、Branko S. Jursic、Tonghua Chen

  DOI：10.1021/jo00121a057

  日期：1995.8

  In an attempt to evaluate the steric effect of ortho methyl groups on the stability of the cumyl radical, 2,2',4,4',6,6'-hexamethylazocumene (6) was synthesized and its rate of decomposition was measured. The fact that 6 decomposes 40 times faster than azocumene is attributed to a ground state steric effect. Calculations on the mesitylcumyl radical 1 and cation 2 show both systems to be substantially nonplanar with dihedral angles of 48 degrees and 35 degrees, respectively. Calculated charge distributions for cation 2 corroborate previously obtained NMR results which showed substantial loss of charge delocalization.(1)
• YAKUBOV, A. P.;TSYGANOV, D. V.;BELENKIJ, L. I.;KRAYUSHKIN, M. M., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1700-1703
  作者：YAKUBOV, A. P.、TSYGANOV, D. V.、BELENKIJ, L. I.、KRAYUSHKIN, M. M.

  DOI：——

  日期：——