(Z)-2-decene oxide | 61140-88-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: (Z)-2-decene oxide
• 英文别名: cis-2,3-Epoxydecan；(2S,3R)-2-Heptyl-3-methyloxirane；(2S,3R)-2-heptyl-3-methyloxirane
• CAS: 61140-88-3
• 化学式: C₁₀H₂₀O
• 分子量: 156.268
• InChiKey: GSTZVCRHAKCHCF-ZJUUUORDSA-N

物化性质

• 沸点：
  194.8±8.0 °C(Predicted)
• 密度：
  0.847±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (Z)-2-decene oxide 在 二氯二茂钛 、 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 生成 顺-2-癸烯 、 癸烯
  参考文献：
  名称：

  Schobert, Rainer, Angewandte Chemie, 1988, vol. 100, # 6, p. 869 - 871

  摘要：

  DOI：
• 作为产物：
  描述：

  顺-2-癸烯 在 Mo₁₂O₄₀P^(3-)*3H⁽¹⁺⁾*3H₃N fluorapatite 、 过氧化脲素 作用下， 反应 24.0h， 生成 (Z)-2-decene oxide 、 2,3-decanediol
  参考文献：
  名称：

  Keggin-type polyacid clusters on apatite: characteristic catalytic activities in solvent-free oxidation

  摘要：

  We found that Keggin-type phosphometalates are effective catalysts for solvent-free oxidation With urea-H2O2 by dispersing on fluorapatite solid phase. In the solid phase system the phosphomolybdate (NH4)(3)PMo12O40 was more effective than the phosphotungstate (NH4)(3)PW12O40, whereas the latter was much superior to the former in the liquid-phase reaction with aqueous H2O2. In situ formation of novel peroxo-type species from (NH4)(3)PMo12O40/FAp and urea-H2O2 which may lead to the high catalytic activity in the solid phase system, was observed by P-31 solid-state NMR. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(02)02033-6

文献信息

• A highly stereoselective synthesis of transepoxides via arsonium ylides
  作者：W. Clark Still、Vance J. Novack

  DOI：10.1021/ja00395a078

  日期：1981.3
• Schobert, Rainer, Angewandte Chemie, 1988, vol. 100, # 6, p. 869 - 871
  作者：Schobert, Rainer

  DOI：——

  日期：——
• Keggin-type polyacid clusters on apatite: characteristic catalytic activities in solvent-free oxidation
  作者：Junko Ichihara、Shunro Yamaguchi、Takuya Nomoto、Hirokazu Nakayama、Katsuma Iteya、Nozomu Naitoh、Yoh Sasaki

  DOI：10.1016/s0040-4039(02)02033-6

  日期：2002.11

  We found that Keggin-type phosphometalates are effective catalysts for solvent-free oxidation With urea-H2O2 by dispersing on fluorapatite solid phase. In the solid phase system the phosphomolybdate (NH4)(3)PMo12O40 was more effective than the phosphotungstate (NH4)(3)PW12O40, whereas the latter was much superior to the former in the liquid-phase reaction with aqueous H2O2. In situ formation of novel peroxo-type species from (NH4)(3)PMo12O40/FAp and urea-H2O2 which may lead to the high catalytic activity in the solid phase system, was observed by P-31 solid-state NMR. (C) 2002 Published by Elsevier Science Ltd.