2-碘-2,4-二甲基戊烷 | 24556-57-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 中文名称: 2-碘-2,4-二甲基戊烷
• 英文名称: 2-iodo-2,4-dimethylpentane
• 英文别名: 2-Jod-2,4-dimethyl-pentan
• CAS: 24556-57-8
• 化学式: C₇H₁₅I
• 分子量: 226.101
• InChiKey: ORUTVFMMZAPOIX-UHFFFAOYSA-N

物化性质

• 沸点：
  140-142 °C(Press: 756 Torr)
• 密度：
  1.384±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-碘-2,4-二甲基戊烷 在 氢碘酸 作用下， 生成 2,4-二甲基戊烷
  参考文献：
  名称：

  Chonin, Chemisches Zentralblatt, 1905, vol. 76, # II, p. 813

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢碘酸 作用下， 生成 2-碘-2,4-二甲基戊烷
  参考文献：
  名称：

  Chonin, Chemisches Zentralblatt, 1905, vol. 76, # II, p. 813

  摘要：

  DOI：

文献信息

• CATALYST FOR LIVING RADICAL POLYMERIZATION
  申请人：Goto Atsushi

  公开号：US20110275775A1

  公开（公告）日：2011-11-10

  Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like.

  提供的是用于活性自由基聚合方法的催化剂，其包含由碳组成的中心元素，并且至少有一个卤素原子与中心元素结合。此外，碳氢化合物可以用作催化剂前体。在催化剂存在的情况下，将具有自由基反应不饱和键的单体进行自由基聚合反应，因此可以获得具有窄分子量分布的聚合物，从而可以显着降低活性自由基聚合的成本。由于催化剂毒性低、使用量少、催化剂溶解性高、反应条件温和、成品无色无味（无需对成型物进行任何后处理）等优点，本发明比传统的活性自由基聚合方法在环保和经济方面更加优越。
• Radical Yields in the Radiolysis of Branched Hydrocarbons:  Tertiary C−H Bond Rupture in 2,3-Dimethylbutane, 2,4-Dimethylpentane, and 3-Ethylpentane
  作者：Robert H. Schuler、Laszlo Wojnarovits

  DOI：10.1021/jp030658+

  日期：2003.10.1

  Gel permeation chromatography has been applied to iodine scavenging studies of the distribution of radicals produced in the radiolysis of symmetrically branched hydrocarbons 2,3-dimethylbutane, 2,4-dimethylpentane, and 3-ethylpentane. The principal iodides observed are those expected as a result of simple bond rupture. In the case of 2,3-dimethylbutane all five expected iodides are readily resolvable

  凝胶渗透色谱法已应用于碘清除研究，研究对称支链烃 2,3-二甲基丁烷、2,4-二甲基戊烷和 3-乙基戊烷辐解过程中产生的自由基分布。观察到的主要碘化物是由于简单的键断裂而预期的那些。在 2,3-二甲基丁烷的情况下，所有五种预期的碘化物都很容易解析，并且表明 H 从三级位置的损失比从一级位置的损失高约 10 倍。对于 2,4-二甲基戊烷也观察到类似的比率。对于 3-乙基戊烷观察到的 15 的较高比率表明依赖于烷烃上的叔位点的数量。从 2 损失二级和一级 H 原子的相对产率约为 3.3，4-二甲基戊烷和3-乙基戊烷与正构烷烃相似，表明相邻叔碳的影响可以忽略不计。在所有三种情况下，末端 C−C 键的断裂相对较少，CC 断裂...
• NOVEL LIVING RADICAL POLYMERIZATION METHOD USING PHOSPHORUS COMPOUND OR NITROGEN COMPOUND AS CATALYST
  申请人：Kyoto University

  公开号：EP2147936A1

  公开（公告）日：2010-01-27

  A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from nitrogen and phosphorus, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as lowtoxicityof the catalyst, a small amount of the catalyst being required, high solubility of the catalyst in the polymerization media, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than other living radical polymerization methods.

  提供了一种用于活自由基聚合的高活性环保型催化剂。本发明提供了一种用于活自由基聚合方法的催化剂。催化剂包括一个中心元素（选自氮和磷）和至少一个与中心元素结合的卤素原子。具有自由基反应性不饱和键的单体在催化剂存在下进行自由基聚合反应，从而可以获得分子量分布较窄的聚合物。本发明具有催化剂毒性低、催化剂用量少、催化剂在聚合介质中的溶解度高、反应条件温和、无色、无味（无需对成型产品进行后处理）等优点。与其他活自由基聚合方法相比，本发明的方法更环保、更经济。
• CATALYST FOR LIVING RADICAL POLYMERIZATION AND POLYMERIZATION METHOD
  申请人：Kyoto University

  公开号：EP2463312A1

  公开（公告）日：2012-06-13

  Provided is a low-cost, highly active, environmentally friendly living radical polymerization catalyst which does not require a radical initiator. An organic compound having an oxidation-reduction capability is used as a catalyst. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. It is made possible to prevent adverse effects of using a radical initiator. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), etc.

  本发明提供了一种无需自由基引发剂的低成本、高活性、环保型活自由基聚合催化剂。催化剂使用一种具有氧化还原能力的有机化合物。即使不使用自由基引发剂，也可以对单体进行自由基聚合，从而获得分子量分布较窄的聚合物。活自由基聚合的成本可显著降低。还可以避免使用自由基引发剂带来的不利影响。由于催化剂具有毒性低、催化剂用量少、催化剂溶解度高、反应条件温和、无着色/无气味（无需对模塑制品进行后处理）等优点，本发明比传统的活自由基聚合方法更环保、更经济。
• LIVING RADICAL POLYMERIZATION CATALYST AND POLYMERIZATION METHOD
  申请人：Kyoto University

  公开号：EP2749577A1

  公开（公告）日：2014-07-02

  A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.

  一种与卤化离子具有离子键的非金属化合物被用作活自由基聚合的催化剂。即使不使用自由基引发剂，也可以对单体进行自由基聚合，从而获得分子量分布较窄的聚合物。活自由基聚合的成本可以大大降低，而且可以避免使用自由基引发剂的不良影响（如副反应）。本发明具有催化剂毒性低、催化剂用量少、催化剂溶解度高、反应条件温和、无着色/无气味等优点，与传统活自由基聚合方法相比，具有明显的环境友好性和经济性。该催化剂可用于各种单体，并能合成高分子量聚合物。